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MESITYL OXIDE

Description References
MESITYL OXIDE
MESITYL OXIDE
CAS No.
141-79-7
Chemical Name:
MESITYL OXIDE
Synonyms
mesityl;FEMA 3368;Mesityloxid;Mesityloxyde;Mesity oxide;MESITYL OXIDE;mesityl oxnide;femanumber3368;Mesityloxide 0;oxydedemesityle
CBNumber:
CB2139085
Molecular Formula:
C6H10O
Formula Weight:
98.14
MOL File:
141-79-7.mol

MESITYL OXIDE Properties

Melting point:
−53 °C(lit.)
Boiling point:
129 °C(lit.)
Density 
0.858 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.442(lit.)
FEMA 
3368 | 4-METHYL-3-PENTEN-2-ONE
Flash point:
87 °F
storage temp. 
Flammables area
solubility 
30g/l
form 
Liquid, Free Of Suspended Matter
color 
Clear
explosive limit
1.4-10.1%(V)
Water Solubility 
28 G/L (20 ºC)
Merck 
14,5908
BRN 
1361550
CAS DataBase Reference
141-79-7(CAS DataBase Reference)
NIST Chemistry Reference
3-Penten-2-one, 4-methyl-(141-79-7)
EPA Substance Registry System
3-Penten-2-one, 4-methyl-(141-79-7)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn
Risk Statements  10-20/21/22-36/37/38
Safety Statements  25
RIDADR  UN 1229 3/PG 3
WGK Germany  1
RTECS  SB4200000
TSCA  Yes
HazardClass  3
PackingGroup  III
Hazardous Substances Data 141-79-7(Hazardous Substances Data)
Toxicity LD50 in mice (mg/kg): 710 ±85 intragastric; LC50 in mice (2 hr), rats (4 hr) (mg/m3): 10000 ±270, 9000 ±600 (Ismerov)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning P280,P302+P352, P312, P322, P363,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P311 Call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.

MESITYL OXIDE price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 281832 Mesityl oxide technical grade, 90% 141-79-7 100g $37.2 2018-11-13 Buy
Sigma-Aldrich 49722 4-Methyl-3-penten-2-one analytical standard 141-79-7 1ml $64.4 2018-11-13 Buy
TCI Chemical M0069 4-Methyl-3-penten-2-one >95.0%(GC) 141-79-7 25mL $24 2018-11-22 Buy
TCI Chemical M0069 4-Methyl-3-penten-2-one >95.0%(GC) 141-79-7 500mL $170 2018-11-22 Buy
Alfa Aesar A15111 Mesityl oxide, 90+%, remainder 4-methyl-4-penten-2-one 141-79-7 250ml $81 2018-11-13 Buy

MESITYL OXIDE Chemical Properties,Uses,Production

Description

Mesity oxide is a tri-functional intermediate of considerable utility in the synthesis of a number of different types of organic compounds, such as mesityl oxide can be hydrogenated to methyl isobutyl ketone and other flavor ingredients in foods, such as 4- methyl-pentanone. Mesityl oxide can be used as a solvent for resins, gums, nitrocellulose, oils, lacquers, and inks. It is also used as an insect repellant and used in ore flotation.

References

[1] Pradyot Patnaik, A Comprehensive Guide to the Hazardous Properties of Chemical Substances, 3rd Edition, 2007
[2] Klaus Weissermel, and Hans-Jürgen Arpe, Industrial Organic Chemistry, 3rd Edition, 1997
[3] George A. Burdock, Fenaroli’s Handbook of Flavor Ingredients, 4th Edition, 2001

Chemical Properties

Mesityl oxide is a clear, pale yellow, or colorless liquid with a strong peppermint odor. The odor threshold is 0.05 ppm.

Chemical Properties

CLEAR LIGHT YELLOW LIQUID

Uses

Solvent for nitrocellulose, many gums and resins, particularly vinyl resins. In lacquers, varnishes and enamels. In making methyl isobutyl ketone.

General Description

A colorless, oily liquid with a pungent honey-like odor. Flash point 87°F. Less dense than water and slightly soluble in water. Vapors heavier than air. Used in paint removers, as a solvent for plastics, and as an insect repellent.

Air & Water Reactions

Highly flammable. Slightly soluble in water

Reactivity Profile

Mixing MESITYL OXIDE in equal molar proportions with any of the following substances in a closed container caused the temperature and pressure to increase: 2-aminoethanol, chlorosulfonic acid, ethylene diamine, nitric acid, oleum, or sulfuric acid [NFPA 1991].

Hazard

Flammable, moderate fire risk. Toxic by ingestion, inhalation, and skin absorption. Eye and upper respiratory tract irritant, central nervous system impairment.

Health Hazard

Inhalation causes irritation of nose and throat, headache, dizziness, difficult breathing. Contact with liquid or concentrated vapor causes severe eye irritation. Liquid irritates skin. Ingestion causes irritation of mouth and stomach.

Fire Hazard

Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. Human systemic effects by inhalation: conjunctiva irritation. This compound is highly irritating to all tissues on contact; its vapors also are irritating. High concentrations are narcotic. It is readdy absorbed through intact skin. Single exposures tend to indicate that ths ketone has greater acute and narcotic action than isophorone. It can have harmful effects upon the hdneys and liver, and may damage the eyes and lungs to a serious degree. Prolonged exposure can injure liver, kidneys, and lungs. It can cause opaque cornea, keratoconus, and extensive necrosis of cornea. Dangerous fire hazard when exposed to heat, sparks, or flame; can react with oxidzing materials. Reacts violently with 2-amino ethanol, chlorosulfonic acid, ethylene diamine, HNO3, oleum, H2SO4. An insect repellent. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also KETONES.

Potential Exposure

Mesityl oxide is used as a solvent for cellulose esters and ethers and other resins in lacquers and inks. It is used in paint and varnish removers and as an insect repellent

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit

Shipping

UN1229 Mesitly oxide, Hazard Class: 3; Labels: 3-Flammable liquid.

Purification Methods

Purify it by distillation, preferably in a vacuum or via the semicarbazone (m 165o) which is decomposed to pure ketone. The 2,4-dinitrophenylhydrazone (m 205-206o) crystallises from EtOH. [Johnson J Am Chem Soc 73 5888 1951, Johnson J Am Chem Soc 75 2720 1953, Erskine & Waight J Chem Soc 3425 1960, Beilstein 1 H 736, 1 I 382, 1 II 793, 1 III 2995, 1 IV 3471.]

Incompatibilities

May form explosive mixture with air. May be able to form explosive peroxides. May react violently with nitric acid; aliphatic amines; alkanolamines, 2- aminoethanol, ethylene diamine; chlorosulfonic acid; oleum (fuming sulfuric acid). Not compatible with oxidizers, strong acids; strong bases; reducing agents; halogens. Dissolves some forms of plastics, resins and rubber. Attacks copper.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

MESITYL OXIDE Preparation Products And Raw materials

Raw materials

Preparation Products


MESITYL OXIDE Suppliers

Global( 158)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22063 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20795 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com CHINA 1374 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32764 55
PI & PI BIOTECH INC.
020-81716320
020-81716319 Sales@pipitech.com CHINA 2549 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20001 58
hebei chisure biotechnology co.,ltd
0311 66567340
0311 66567340 admin@SpeedGainpharma.com CHINA 403 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40399 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30308 84

View Lastest Price from MESITYL OXIDE manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-24 MESITYL OXIDE
141-79-7
US $1.00 / kg 1kg 95%-99% as request career henan chemical co
2018-09-03 4-Methyl-2-pentanone
141-79-7
US $10.00-10.00 / G 10UG 99% 1000kg/month hebei chisure biotechnology co.,ltd
2018-09-03 Mesityl oxide
141-79-7
US $10.00-10.00 / G 10UG 99% 1000kg/month hebei chisure biotechnology co.,ltd

MESITYL OXIDE Spectrum


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