Pyridaphenthion | 119-12-0

Pyridaphenthion Properties

Melting point	54.5～56.5℃
Boiling point	416.2±28.0 °C(Predicted)
Density	1.30±0.1 g/cm3(Predicted)
vapor pressure	1.47×10^-6 Pa (20 °C)
Flash point	-4 °C
storage temp.	APPROX 4°C
Water Solubility	100mg l^-1 （20°C）
pka	-2.09±0.40(Predicted)
BRN	302741
CAS DataBase Reference	119-12-0(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	98M0VDD56Z
NIST Chemistry Reference	Phosphorothioic acid, o-(1,6-dihydro-6-oxo-1-phenyl-3-pyridazinyl) o,o-diethyl ester(119-12-0)
EPA Substance Registry System	Pyridaphenthion (119-12-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302+H332
Precautionary statements	P261-P264-P270-P271-P301+P312-P304+P340+P312
Hazard Codes	F,Xi,N,Xn
Risk Statements	11-36-66-67-57-51/53-20/22
Safety Statements	26-61-33-16
RIDADR	2783
WGK Germany	3
RTECS	TF2275000
HazardClass	6.1(a)
PackingGroup	II

Pyridaphenthion price More Price(5)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	36895	Pyridaphenthion solution 10?μg/mL in ethyl acetate, PESTANAL?, analytical standard	119-12-0	2ml	$62	2022-05-15	Buy
Sigma-Aldrich	32538	Pyridaphenthion PESTANAL?, analytical standard	119-12-0	100mg	$126	2022-05-15	Buy
AK Scientific	S535	Pyridaphenthion	119-12-0	100mg	$189	2021-12-16	Buy
American Custom Chemicals Corporation	CHM0290691	PYRIDAPHENTHION 98.00%	119-12-0	2.5G	$1265	2021-12-16	Buy
AHH	MT-58329	Pyridaphenthion 98%	119-12-0	2.5g	$436	2021-12-16	Buy

Product number	Packaging	Price	Buy
36895	2ml	$62	Buy
32538	100mg	$126	Buy
S535	100mg	$189	Buy
CHM0290691	2.5G	$1265	Buy
MT-58329	2.5g	$436	Buy

Pyridaphenthion Chemical Properties,Uses,Production

Description

Pyridaphenthion is a pale yellow solid, mp 54.5–56 ?C, vp 0.00147 mPa (20 ?C). Solubility in water is 100 mg/L (20 ?C). It is very soluble in acetone, methanol, and diethyl ether. Log Kow = 3.2.

Uses

Pyridaphenthion is used to control a wide range of chewing and sucking insects and mites in rice, vegetables, fruit and ornamentals.

Definition

ChEBI: Pyridaphenthion is an organic thiophosphate, an organothiophosphate insecticide and a pyridazinone. It has a role as an EC 3.1.1.7 (acetylcholinesterase) inhibitor and an agrochemical. It is functionally related to a 6-hydroxy-2-phenylpyridazin-3-one.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion and skin contact. When heated to decomposition it emits very toxic fumes of SOx, POx, and NOx. Used to control chewing and suckmg insects on rice, fruits, vegetables, and cereals.

Metabolic pathway

Pyridaphentluon is photolytically transformed into the oxon and phenylmaleic hydrazide. In the mouse its metabolism involves oxidative dearylation, oxidative desulfuration to the oxon, de-ethylation and conjugation of phenylmaleic hydrazide produced as the ultimate product of stage I metabolism and is typical of many phosphorothioates. A marked difference between metabolism in mice and rats was shown, with rats excreting no desethylpyridaphenthion and excreting all of the phenyl-maleic hydrazide in an unconjugated form.

Metabolism

More than 70% of the dose administered to rats and mice was excreted within 24 h in the urine. The major metabolites excreted are phenylmaleic hydrazide and desethyl pyridafenthion-oxon. The half-life in soil is 11–24 d.

Toxicity evaluation

The acute oral LD₅₀ for rats is 769–850 mg/kg. Inhalation LC50 (4 h) for rats is >1.13 mg/L air.

Degradation

The photolysis of pyridaphenthion on a glass slide irradiated with both short wavelength UV light and light of wavelength >300 nm was investigated by Tsao et al. (1989). Samples were irradiated for 48 hours at unrecorded light intensity as thin films spread on petri dishes or in solution in water, methanol or hexane under an oxygen atmosphere. The effects of photosensitisers was also assessed in the thin film experiments. The photoproducts were analysed by TLC, GC-MS and ¹H NMR spectroscopy. Under thin film conditions pyridaphenthion was photodegraded more quickly with light >300 nm than by 254 um light and was degraded faster as a thin film than in solution. The main photoproducts from the glass surface and aqueous solution were pyridaphenthion oxon (2) and phenylmaleic hydrazide (3) (Scheme 1); the only other products were small amounts of polymers. Photosensitisers accelerated photolysis markedly with the most effective being a plant-derived natural product, cis-dehydromatricaria ester. It is notable that a simple chemical oxidation using 3-chloroperoxybenzoic acid gave the same two products, 2 and 3.

Pyridaphenthion Preparation Products And Raw materials

Raw materials

2-tert-Butyl-4,5-dichloro-3-2H-pyridazinone CIS-BUTENEDIOIC ANHYDRIDE THIOPHOSPHORYL CHLORIDE

Preparation Products

Pyridaphenthion Suppliers

Global( 116)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22968	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49390	58
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
SIMAGCHEM CORP	+86-13806087780	sale@simagchem.com	China	17367	58
TargetMol Chemicals Inc.	+1-781-999-5354 +1-00000000000	marketing@targetmol.com	United States	19892	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34572	58

Supplier	Advantage
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
Hubei Jusheng Technology Co.,Ltd.	58
Hubei xin bonus chemical co. LTD	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
SIMAGCHEM CORP	58
TargetMol Chemicals Inc.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58

View Lastest Price from Pyridaphenthion manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-01-22	Pyridaphenthion 119-12-0	US $1.00 / KG	1KG	98%HPLC	10tons	Career Henan Chemical Co

Pyridaphenthion
119-12-0
US $1.00 / KG
98%HPLC
Career Henan Chemical Co

Pyridaphenthion Spectrum

Pyridaphenthion(119-12-0)¹HNMR

119-12-0(Pyridaphenthion)Related Search:

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Diphenyl ether Tris(2-chloroethyl) phosphate Celiprolol Phenylacetic acid 3-HYDROXY-1-PHENYL-6-PYRIDAZONE

O,O,O-TRIETHYLPHOSPHOROTHIOATE 3-HYDROXY-1-METHYLPYRIDAZIN-6(1H)-ONE Diethyl ether

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PYRIDAPHENTHION OFUNACK ORESTE 3(2H)-Pyridazinone, 6-hydroxy-2-phenyl-, O-ester with O,O-diethyl phosphorothioate 3(2h)-pyridazinone,6-hydroxy-2-phenyl-,o-esterwitho,o-diethylphosphoroth American cyanamid 12,503 americancyanamid12,503 CL 12503 cl12503 DiethylO-(2,3-dihydro-3-oxo-2-phenyl-6-pyridazinyl)phosphorothioate ENT 23,968 ent23,968 O-(1,6-dihydro-6-oxo-1-phenyl-3-pyridazinyl)O,O-diethylphosphorothioate O-(1,6-Dihydro-6-oxo-1-phenylpyridazin-3-yl) O,O-diethyl phosphorothioate o-(1,6-dihydro-6-oxo-1-phenylpyridazin-3-yl)o,o-diethylphosphorothioate O,O-Diethyl O-(2,3-dihydro-3-oxo-2-phenyl-6-pyridazinyl)phosphorothioate o,o-Diethyl o-(6-oxo-1-phenyl-1,6-dihydro-3-pyridazinyl) thiophosphate o,o-diethylo-(2,3-dihydro-3-oxo-2-phenyl-6-pyridazinyl)phosphorothioate O,O-Diethylphosphorothioate, O-ester with 6-hydroxy-2-phenyl-3(2H)-pyridazinone o,o-diethylphosphorothioate,o-esterwith6-hydroxy-2-phenyl-3(2h)-pyridazino Ofnack Ofnak Ofun ofunack,e.c.(20%) Phosphorothioic acid, O,O-diethyl ester, O-ester with 6-hydroxy-2-phenyl-3(2H)pyridazinone Phosphorothioicacid,esters,O-(1,6-dihydro-6-oxo-1-phenyl-3-pyridazinyl)-O,O-diethylester phosphorothioicacid,o,o-diethylester,o-esterwith6-hydroxy-2-phenyl-3(2h)p Pyridafenthion pyridiphenthion yridazinone O,O-diethyl O-(1,6-dihydro-6-oxo-1-phenylpyridazin-3-yl) thiophosphate Pyridaphenthione pyridaphenthio (jmaf) O,O-Diethyl-O-(3-oxo-2-phenyldihydro-6-pyridazinyl)- phosphorodithionate 6-Diethoxyphosphinothioyloxy-2-phenylpyridazin-3-one O-(1,6-Dihydro-6-oxo-1-phenyl-3-pyridazinyl)phosphorothioic acid O,O-diethyl ester O,O-Diethyl-O-thiophosphat Pyridafethion O-(1,6-Dihydro-6-oxo-1-phenylpyridazin-3-yl)-O,O-diethylphosphorothionate Pyridaphenthion solution Pyridaphenthion E.C.(20%) O，O-dietyl-O-(2,3-dihydro-3-oxo-2-phenyl-dazine-6-yl) phosphorothionate Pyridaphenthion Solution, 100ppm AC-12503 Phosphorothioic acid O-(1,6-dihydro-6-oxo-1-phenylpyridazin-3-yl) O,O-diethyl Thiophosphoric acid O,O-diethyl-O-(6-oxo-1-phenyl-1,6-dihydropyridazin-3-yl) ester 6-diethoxythiophosphoryloxy-2-phenyl-pyridazin-3-one Pyridahenthion Pyridaphenthion 250mg [119-12-0] Purity of Pyridaphenthione O,O-diethyl O-(6-oxo-1-phenyl-1,6-dihydropyridazin-3-yl) phosphorothioate Ofunack(TM) PyridaphenthionSolution,100mg/L,1ml Pyridaphenthion @100 μg/mL in MeOH Pyridaphenthion@1000 μg/mL in Acetone Phosphorothioic acid, O-(1,6-dihydro-6-oxo-1-phenyl-3-pyridazinyl) O,O-diethyl ester PyridaphePyridaphenthionnthion 4'-Tetramethoxyflavone