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THIOPHOSPHORYL CHLORIDE

THIOPHOSPHORYL CHLORIDE
THIOPHOSPHORYL CHLORIDE structure
CAS No.
3982-91-0
Chemical Name:
THIOPHOSPHORYL CHLORIDE
Synonyms
tl262;NSC 158334;thiophosphoryl;AURORA KA-1089;fosforthiochlorid;Thiophosphoryl chlor;thiochloridfosforecny;Thiophosphorylchlorid;PHOSPHORSULFOCHLORIDE;phosphorousthiochloride
CBNumber:
CB6115317
Molecular Formula:
Cl3PS
Formula Weight:
169.4
MOL File:
3982-91-0.mol

THIOPHOSPHORYL CHLORIDE Properties

Melting point:
-35 °C
Boiling point:
125 °C(lit.)
Density 
1.668 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.555(lit.)
solubility 
benzene: soluble(lit.)
form 
liquid
color 
colorless
Specific Gravity
1.668
Water Solubility 
hydrolyzes in H2O, forming H3PO4, HCl, H2S; hydrolyzes rapidly in alkaline solutions; soluble benzene, CCl4, CS2, chloroform [MER06]
Sensitive 
moisture sensitive
Merck 
14,7356
CAS DataBase Reference
3982-91-0(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T+
Risk Statements  22-26-34-52/53
Safety Statements  26-28-36/37/39-45-61
RIDADR  UN 1837 8/PG 2
WGK Germany  2
RTECS  XN2930000
21
HazardClass  8
PackingGroup  II
HS Code  28273985
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

THIOPHOSPHORYL CHLORIDE price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 224294 Thiophosphoryl chloride 98% 3982-91-0 100g $40.7 2018-11-20 Buy
Sigma-Aldrich 224294 Thiophosphoryl chloride 98% 3982-91-0 1.4kg $256 2018-11-20 Buy
Strem Chemicals 93-1591 Thiophosphoryl chloride, 98% 3982-91-0 100g $38 2018-11-13 Buy
Strem Chemicals 93-1591 Thiophosphoryl chloride, 98% 3982-91-0 500g $157 2018-11-13 Buy
Sigma-Aldrich 224294 Thiophosphoryl chloride 98% 3982-91-0 350g $105 2018-11-20 Buy

THIOPHOSPHORYL CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

clear colourless to slightly yellowish liquid

General Description

A colorless fuming liquid. Boiling point 257°F (125 °C). Irritates the eyes and mucous membranes. Corrosive to metals and tissue.

Air & Water Reactions

Fumes in air. Decomposes in water to form phosphoric acid and hydrochloric acid (hydrogen chloride). Both substances are corrosive to metal or tissue. Can also form hydrogen sulfide (H2S), a toxic flammable gas, in reaction with water [AAR 1991].

Reactivity Profile

THIOPHOSPHORYL CHLORIDE is acidic. Incompatible with bases (including amines), with strong oxidizing agents, and with alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Hazard

Strong irritant to skin and tissue.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

Poison by inhalation. Moderately toxic by ingestion. A corrosive irritant to skin, eyes, and mucous membranes. Explosive reaction with methylmagnesium iodlde. Explosive reaction with pentaerythritol + heat. Reacts with water or steam to produce toxic and corrosive fumes. When heated to decomposition it emits highly toxic fumes of POx, SOx, and Cl-.

Purification Methods

Possible impurities are PCl5, H3PO4, HCl and AlCl3. Gently mix it with H2O to avoid a heavy emulsion; the product decoulorises immediately and settles to the bottom layer. It is soluble in *C6H6 and CCl4. [Duval Inorg Synth IV 73 1953.] HARMFUL VAPOURS.

THIOPHOSPHORYL CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products


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