ChemicalBook
Chinese Japanese Germany

Nickelous oxide

Physical Properties Occurrence Uses Preparation Reactions
Nickelous oxide
Nickelous oxide
CAS No.
1313-99-1
Chemical Name:
Nickelous oxide
Synonyms
bunsenite;C.I. 77777;OXIDICNICKEL;CATALYST R1-10;nickd monoxide;NICKEL MONOXIDE;NICKELOUS OXIDE;NICKEL(+2)OXIDE;mononickeloxide;Nickelprotoxide
CBNumber:
CB2358284
Molecular Formula:
NiO
Formula Weight:
74.69
MOL File:
1313-99-1.mol

Nickelous oxide Properties

Melting point:
1960 °C
Density 
6.67 g/mL at 25 °C(lit.)
form 
Powder/Solid
color 
green
Specific Gravity
6.67
Water Solubility 
insoluble
Merck 
14,6512
Stability:
Stable. Incompatible with strong acids.
InChIKey
GNRSAWUEBMWBQH-UHFFFAOYSA-N
CAS DataBase Reference
1313-99-1(CAS DataBase Reference)
EPA Substance Registry System
Nickel oxide (NiO)(1313-99-1)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,Xi
Risk Statements  49-43-53-48/23-36/37
Safety Statements  53-45-61-36/37-26
RIDADR  3288
WGK Germany  1
RTECS  QR8400000
TSCA  Yes
HS Code  28254000
Hazardous Substances Data 1313-99-1(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H413 May cause long lasting harmful effects to aquatic life Hazardous to the aquatic environment, long-term hazard Category 4
Precautionary statements:
P201 Obtain special instructions before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.

Nickelous oxide price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 203882 Nickel(II) oxide 99.99% trace metals basis 1313-99-1 20g $96.5 2018-11-13 Buy
Sigma-Aldrich 203882 Nickel(II) oxide 99.99% trace metals basis 1313-99-1 100g $369 2018-11-13 Buy
Alfa Aesar 010819 Nickel(II) oxide, Puratronic?, 99.998% (metals basis) 1313-99-1 25g $112 2018-11-16 Buy
Alfa Aesar 010819 Nickel(II) oxide, Puratronic?, 99.998% (metals basis) 1313-99-1 5g $34.7 2018-11-16 Buy
Strem Chemicals 28-1475 Nickel(II) oxide (99.998%-Ni) PURATREM 1313-99-1 10g $72 2018-11-13 Buy

Nickelous oxide Chemical Properties,Uses,Production

Physical Properties

Green cubic crystals; transforms to a grayish black octahedral form, known as black oxide, when strongly ignited; black oxide has a metallic luster; density of green oxide is 6.72 g/cm3; Mohs hardness 5.5; melts at 1955°C; insoluble in water; soluble in acids at ordinary temperatures; black form dissolves in hot acids.

Occurrence

The oxide occurs in nature in the mineral, bunsenite.

Uses

Nickel oxide is used in the ceramic industry for making frit, ferrites, and coloring porcelain. The oxide in sinter form is used in the production of nickelsteel alloys. It supplies oxygen to the melt for removal of carbon as carbon dioxide. Some other important uses of nickel oxide include preparation of many nickel salts, specialty chemicals, and nickel catalysts. It also is used as an electrode in fuel cells.

Preparation

Nickel oxide is prepared by heating pure nickel powder with oxygen at a temperature above 400°C. In some commercial processes, green nickel oxide is made by heating a mixture of nickel powder and water in air at 1,000°C. Adding some nickel oxide to the above mixture enhances the rate of reaction. An alternative method of preparation of the green oxide involves thermal decomposition of an oxo acid salt of nickel at elevated temperatures. Thus, nickel nitrate, nickel sulfate or, more conveniently, nickel carbonate when heated at 1,000°C, yields the green oxide. The black oxide, on the other hand, is produced at a lower temperature from incomplete calcination of the carbonate or nitrate salt at 600°C. The oxygen content of the black form is slightly greater than its green counterpart.

Reactions

Several nickel salts are obtained by reactions of nickel oxide with mineral acids. Thus, the reaction of black nickel oxide with hot dilute sulfuric acid forms nickel sulfate, NiSO4•6H2O. Similarly, dilute nitric acid, hydrochloric, and hydrobromic acids when heated react with the black form of nickel oxide to yield corresponding nickel salts as hexahydrates.
Heating nickel oxide with hydrogen, carbon, or carbon monoxide reduces it to metallic nickel.
Nickel oxide combines with sodium or potassium hydroxide at elevated temperatures (>700°C), forming sodium or potassium nickelate; i.e., K2NiO2:
NiO + 2NaOH → Na2NiO2 + H2O

Chemical Properties

Brownish black or black powder

Uses

Nickel salts, porcelain painting, fuel cell electrodes.

Hazard

Confirmed carcinogen.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intratracheal, intravenous, and subcutaneous routes. Mutation data reported. Can react violently with fluorine, hydrogen peroxide, hydrogen sulfide, iodine, barium oxide + air. See also NICKEL COMPOUNDS.

Nickelous oxide Preparation Products And Raw materials

Raw materials

Preparation Products


Nickelous oxide Suppliers

Global( 188)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22049 58
Shanghai Bojing Chemical Co.,Ltd.
+86-21-37122233
+86-21-37127788 Candy@bj-chem.com CHINA 500 55
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20786 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32651 55
Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 1659 55
Hubei Jusheng Technology Co.,Ltd.
86-155-27864001
peter@hubeijusheng.com CHINA 18004 58
City Chemical LLC
2039322489
203.937.8400 sales@citychemical.com United States 100 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19990 58
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701 sale@aladdin-e.com China 25106 65
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76

View Lastest Price from Nickelous oxide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-07-24 Nickelous oxide
1313-99-1
US $30.00 / KG 25KG 76% 1T career henan chemical co

Nickelous oxide Spectrum


1313-99-1(Nickelous oxide)Related Search:


Copyright 2017 © ChemicalBook. All rights reserved