1-Bromohexane
- CAS No.
- 111-25-1
- Chemical Name:
- 1-Bromohexane
- Synonyms
- N-HEXYL BROMIDE;Bromohexane;Hexylbromid;1-Bromhexan;1-bromo-hexan;N-BROMOHEXANE;HEXYL BROMIDE;1-BROMOHEXANE;JACS-111-25-1;1-hexylbromide
- CBNumber:
- CB4447030
- Molecular Formula:
- C6H13Br
- Molecular Weight:
- 165.07
- MDL Number:
- MFCD00000271
- MOL File:
- 111-25-1.mol
- MSDS File:
- SDS
Melting point | −85 °C(lit.) |
---|---|
Boiling point | 154-158 °C(lit.) |
Density | 1.176 g/mL at 25 °C(lit.) |
vapor density | 5.7 (vs air) |
vapor pressure | <10 mm Hg ( 20 °C) |
refractive index |
n |
Flash point | 135 °F |
storage temp. | Store below +30°C. |
solubility | <1g/l |
form | Liquid |
color | Clear |
Water Solubility | Immiscible with water. |
BRN | 1731290 |
Dielectric constant | 5.8(24℃) |
Stability | Stable. Incompatible with strong oxidizing agents, strong bases. Combustible. |
InChIKey | MNDIARAMWBIKFW-UHFFFAOYSA-N |
CAS DataBase Reference | 111-25-1(CAS DataBase Reference) |
FDA UNII | WVA0FAX7GA |
NIST Chemistry Reference | Hexane, 1-bromo-(111-25-1) |
EPA Substance Registry System | Hexane, 1-bromo- (111-25-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H226-H315-H319-H335 | |||||||||
Precautionary statements | P210-P233-P240-P241-P303+P361+P353-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38-10 | |||||||||
Safety Statements | 26-36-16 | |||||||||
RIDADR | UN 1993 3/PG 3 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | MO0925000 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29033036 | |||||||||
Toxicity | LD50 orally in Rabbit: > 2000 mg/kg | |||||||||
NFPA 704 |
|
1-Bromohexane price More Price(15)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | B68240 | 1-Bromohexane 98% | 111-25-1 | 100g | $23.5 | 2024-03-01 | Buy |
Sigma-Aldrich | B68240 | 1-Bromohexane 98% | 111-25-1 | 1kg | $171 | 2024-03-01 | Buy |
Sigma-Aldrich | 8.01603 | 1-Bromohexane for synthesis | 111-25-1 | 100mL | $40 | 2024-03-01 | Buy |
Sigma-Aldrich | 8.01603 | 1-Bromohexane for synthesis | 111-25-1 | 500mL | $67.3 | 2024-03-01 | Buy |
TCI Chemical | B0600 | 1-Bromohexane >98.0%(GC) | 111-25-1 | 25g | $25 | 2024-03-01 | Buy |
1-Bromohexane Chemical Properties,Uses,Production
Chemical nature
1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.
Synthesis and reactions
Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons.
Chemical Properties
1-Bromohexane is a colourless liquid organohalide. It is a solvent that is frequently used in grignard reactions. It is also used as Intermediate, for introduction of hexyl group.
Uses
1-Bromohexane is utilized in the preparation of pharmaceuticals and organic chemicals. It is involved in Grignard reactions as an alkylating agent and in the synthesis of bromo-cyclic compounds.
Application
1-Bromohexane is a very useful synthetic intermediate,it can be used to react with Mg to prepare Grignard reagents which play an important role in formation of carbon-carbon bond.
Synthesis Reference(s)
Chemistry Letters, 7, p. 833, 1978
Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0
Purification Methods
Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]
1-Bromohexane Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Yancheng Longshen Chemical Co.,Ltd. | +86-0515-88706880; +8618352073383 | sales@longshenchem.com | China | 79 | 55 |
Hebei Guanlang Biotechnology Co., Ltd. | +8619930503259 | cherry@crovellbio.com | China | 18419 | 58 |
Jinan Qinmu Fine Chemical Co.,Ltd. | +8618660799346 | sales@qinmuchem.com | China | 1009 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12465 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5873 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5895 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20291 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21666 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9287 | 55 |
View Lastest Price from 1-Bromohexane manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-09-23 | bromohexane
111-25-1
|
US $19.00 / KG | 1KG | 99.% | 10 ton | Hebei Chuanghai Biotechnology Co,.LTD | ||
2024-09-19 | Hexylbromid
111-25-1
|
US $20.00 / kg | 1kg | 99.9% | 10000 | Hebei Miaoyin Technology Co.,Ltd | ||
2024-08-15 | 1-Bromohexane
111-25-1
|
US $0.00 / kg | 1kg | 0.99 | 20tons | Hebei Yanxi Chemical Co., Ltd. |
- bromohexane
111-25-1
- US $19.00 / KG
- 99.%
- Hebei Chuanghai Biotechnology Co,.LTD
- Hexylbromid
111-25-1
- US $20.00 / kg
- 99.9%
- Hebei Miaoyin Technology Co.,Ltd
- 1-Bromohexane
111-25-1
- US $0.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.