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Polyphosphoric acid

CAS No.
8017-16-1
Chemical Name:
Polyphosphoric acid
Synonyms
PPA;polyphosphoric acids;Super Phos 105;Polyphoshoric acid;acidepolyphosphorique;condensedphosphoricacid;Polyphosphoric acid joyce;83%, P2O5;phospholeum;yphosphoric acid
CBNumber:
CB6437945
Molecular Formula:
(H)n+2.(P)n.(O)3n+1
Molecular Weight:
0
MDL Number:
MFCD00084480
MOL File:
Mol file
Last updated:2023-09-07 16:59:03

Polyphosphoric acid Properties

Melting point -20°C
Boiling point 550 °C
Density 2.06 g/mL at 25 °C
vapor pressure 2 hPa (20 °C)
storage temp. Store below +30°C.
solubility Methanol (Soluble), Water (Soluble)
pka 0.91[at 20 ℃]
form Viscous Liquid
color Colorless
Specific Gravity 2.06
Viscosity 311.4mm2/s
Water Solubility MAY DECOMPOSE
Sensitive Hygroscopic
Merck 14,7580
Stability Stable. Incompatible with strong bases. Hygroscopic.
CAS DataBase Reference 8017-16-1(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances POLYPHOSPHORIC ACID
EPA Substance Registry System Polyphosphoric acids (8017-16-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H290-H314
Precautionary statements  P234-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34
Safety Statements  45-36/37/39-25-26
RIDADR  3264
WGK Germany  1
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  28092000
NFPA 704
0
3 1

Polyphosphoric acid price More Price(23)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.07471 Polyphosphoric acid for synthesis 8017-16-1 500mL $74.2 2024-03-01 Buy
Sigma-Aldrich 8.07471 Polyphosphoric acid for synthesis 8017-16-1 2.5L $254 2024-03-01 Buy
Sigma-Aldrich 208213 Polyphosphoric acid reagent grade, 115% H3PO4 basis 8017-16-1 25g $49.6 2024-03-01 Buy
Sigma-Aldrich 208213 Polyphosphoric acid reagent grade, 115% H3PO4 basis 8017-16-1 1kg $89.6 2024-03-01 Buy
Alfa Aesar L14856 Polyphosphoric acid, ca 84% (as phosphorus pentoxide) 8017-16-1 100ml $33.1 2024-03-01 Buy
Product number Packaging Price Buy
8.07471 500mL $74.2 Buy
8.07471 2.5L $254 Buy
208213 25g $49.6 Buy
208213 1kg $89.6 Buy
L14856 100ml $33.1 Buy

Polyphosphoric acid Chemical Properties,Uses,Production

Description

Superphosphoric acid is made by the concentration of regular wet-process acid up to P2O5 concentrations of 78%. Granular polyphosphates suitable for bulk blending are made by reacting ammonia with regular wet process acid of 52% P2O5 content and using the heat of reaction to drive off water to produce a phosphate melt of 10-43-0, with about 40% of the phosphorus in the polyphosphate form. These materials are, however, not suitable for bulk blending due to their “sticky” nature (10).

Chemical Properties

Viscous, water-white liquid. Water solu- ble. Does not crystallize on standing; hygroscopic. The commercial acid is a mixture of orthophos- phoric acid with pyrophosphoric, triphosphoric, and higher acids and is sold on the basis of its calcu- lated content of H3PO4, e.g., 115%. Superphospho- ric acid is a similar mixture sold at 105% H3PO4. These acids revert slowly to orthophosphoric acid on dilution with water.

Uses

Polyphosphoric Acid is a ligand used as an analytical tool to image nanoparticles through photon emission topography. Used also in the synthesis of pharmaceuticals.

Uses

Polyphosphoric acid can be used as an analytical reagent in chemical industry and a powerful dehydrating agent for organic synthesis. It is used in production of acid phosphates and pharmaceuticals. Intermediate for production of phosphate esters with high mono-ester content. Polyphosphoric acid can be used as a catalyst during synthesis of dimethyl carbonate from urea and methanol. It is widely employed as acylation and alkylation reagent in various reactions. It can be used as a catalyst in the synthesis of various aromatic ketones. It may be used to prepare silica-supported polyphosphoric acid, an easy to handle, reusable heterogeneous catalyst. Polyphosphoric acid may be used in the synthesis of aromatic sulfones, N-substituted amides and 4-aminobenzophenones. Used as a catalyst and absorbent of ammonia during the synthesis of dimethyl carbonate (DMC). Used as a solvent in the synthesis of hyperbranched polybenzoxazoles.

Uses

Dehydrating, catalytic, and sequestering agents, for metal treating; many applications where a con- centrated monooxidizing acid is needed; laboratory reagent.

Definition

ChEBI: A polymerized phosphorus oxoacid of general formula HO[PO2OH]nH formed by condensation of orthophosphoric acid molecules and containing a backbone chain consisting of alternating P and O atoms covalent y bonded together.

General Description

Polyphosphoric acid (PPA) is widely employed as acylation and alkylation reagent in various reactions. It is a strong mineral acid with excellent dehydrating properties.

Hazard

Toxic by ingestion; strong irritant.

Agricultural Uses

Polyphosphoric acid is obtained by heating the wetprocess phosphoric acid. It contains around 72% phosphorus (as P2O5) and represents a series of phosphoric acids containing more than one atom of phosphorus (such as H4P2O7). The general formula is Hn+2PnO3n+1.

Solubility in water

Polyphosphoric acids are miscible with water, hydrolyzing to orthophosphoric acid with the generation of heat. They are insoluble in hydrocarbons and halogenated hydrocarbons. 

Global( 362)Suppliers
Supplier Tel Email Country ProdList Advantage
Yangzhou Ruiyang Chemical Co.,Ltd
+86-051486368666 +86-13915319893 765299674@qq.com China 1 58
Chongqing Chuandong Chemical (Group) Co. Ltd.
+86-13637972665 +86-13637972665 wxc@cd1958.com China 81 58
Mascot I.E.Co .,Ltd.
+86-0519-85010339 +8613584504415 info@mascotchem.com China 309 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12468 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Hangzhou Bayee Chemical Co., Ltd.
0086-571-86990109 rachelhoo@bayeechem.com China 104 55
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21688 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9341 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58

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View Lastest Price from Polyphosphoric acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Polyphosphoric acid PPA pictures 2024-04-30 Polyphosphoric acid PPA
8017-16-1
US $3.75-3.40 / KG 100KG 115%116% 20tons per month Shenyang Simchoice Chemical Co.,Ltd
Tetraphosphoric acid pictures 2024-01-18 Tetraphosphoric acid
8017-16-1
US $16.00 / KG 1600KG 99% 20T Xiamen Wonderful Bio Technology Co., Ltd.
Polyphosphoric acid pictures 2023-09-07 Polyphosphoric acid
8017-16-1
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
acidesuperphosphorique condensedphosphoricacid(non-specificname) Phosphoric acids, super- or poly- Polyphosphoric acid, > 84% phosphate (as P2O5), pure POLYPHOSPHORIC ACID , 84% MIN. Polyphosphorsuren Polyphosphoric acid PPA 105% , 115%, 116% 83%, P2O5 Polyphosphoric acid,pure,> 84% phosphate (asP2O5) Polyphosphoric Acid, ca (as Phosphorus Pentoxide) Polyphosphoric acid ,84% phosphate(as P2O5) Polyphosphoric acid, > 84% phosphate (as P2O5), pure 1KG phospholeum superphosphoricacid POLYPHOSPHORIC ACID Polyphosphoic Acid Polyphosphoric acid (83% P2O5) PolyphosphoricacidPOviscousliq POLYPHOSPHORIC ACID REAGENT GRADE 115& POLYPHOSPHORIC ACID FOR SYNTHESIS Polyphosphoricacid,ca84%(asphosphoruspentoxide) Polyphosphoric acid,ca>=85%(as phosphorus pentoxide) Polyphosphoric acid, ca 84% Polyphosphoric acids(PPA) Polyphosphoric acid ~105% H3PO4 basis Polyphosphoric acid >=83% phosphate (as P2O5) basis Polyphosphoric acid reagent grade, 115% H3PO4 basis Polyphosphoric acid PPA Polyphosphoric acid, phosphate (as P2O5), pure POLYPHOSPHORIC ACIDPOLYPHOSPHORIC ACIDPOLYPHOSPHORIC ACIDPOLYPHOSPHORIC ACID Polyphosphoric Acid,>85%(P2O5) yphosphoric acid Polyphosphoric acid ISO 9001:2015 REACH Polyphosphoric acid, GR Polyphosphoric Acid extrapure, 83-87% P2O5 84% phosphate (as P2O5) Polyphosphoric acid, pure, > POLYPHOSPHORIC ACID Extra Pure acidepolyphosphorique condensedphosphoricacid Super Phos 105 PPA polyphosphoric acids Polyphoshoric acid Polyphosphoric acid joyce polyphosphric acid 8017-16-1 Hn2PnOn2 H3PO4稰2O5 H6P4O13 H3P4O13 H3O9P3 Hn2PnO3n1 H3PO4P2O5 H2OHO3Pn UVCBs-polymer inorganic acid Reagent Grade Acids &