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Triethylene glycol dimethacrylate

Description Application Reference
Triethylene glycol dimethacrylate
Triethylene glycol dimethacrylate structure
CAS No.
109-16-0
Chemical Name:
Triethylene glycol dimethacrylate
Synonyms
tgm3;Ethy;TGM 3;TEDMA;tgm35;tgm3s;tgm3pc;TGM 35;TGM 3S;TEGDMA
CBNumber:
CB8485829
Molecular Formula:
C14H22O6
Formula Weight:
286.32
MOL File:
109-16-0.mol

Triethylene glycol dimethacrylate Properties

Melting point:
-52°C
Boiling point:
170-172 °C5 mm Hg(lit.)
Density 
1.092 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.461(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
Specific Gravity
1.092
BRN 
1797351
InChIKey
HWSSEYVMGDIFMH-UHFFFAOYSA-N
CAS DataBase Reference
109-16-0(CAS DataBase Reference)
FDA UNII
14I47YJ5EY
NIST Chemistry Reference
2-Propenoic acid, 2-methyl-, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester(109-16-0)
EPA Substance Registry System
Triethylene glycol dimethacrylate (109-16-0)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H317
Precautionary statements  P280-P333+P313
Hazard Codes  Xi
Risk Statements  36/37/38-43
Safety Statements  26-28-36/37
RIDADR  UN 3334
WGK Germany  1
RTECS  OZ4100000
8-19
HS Code  29161900
Toxicity LD50 oral in rat: 10837mg/kg

Triethylene glycol dimethacrylate price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 261548 Triethylene glycol dimethacrylate contains 80-120 ppm MEHQ as inhibitor, 95% 109-16-0 250ml $65.9 2021-12-16 Buy
Sigma-Aldrich 261548 Triethylene glycol dimethacrylate contains 80-120 ppm MEHQ as inhibitor, 95% 109-16-0 1l $177 2021-12-16 Buy
TCI Chemical T0948 Triethylene Glycol Dimethacrylate (stabilized with MEHQ) >95.0%(GC) 109-16-0 25mL $22 2021-12-16 Buy
TCI Chemical T0948 Triethylene Glycol Dimethacrylate (stabilized with MEHQ) >95.0%(GC) 109-16-0 500mL $71 2021-12-16 Buy
Usbiological 359247 TGM3 109-16-0 48Tests $588 2021-12-16 Buy

Triethylene glycol dimethacrylate Chemical Properties,Uses,Production

Description

Triethylene glycol dimethacrylate is used as a cross-linking agent in the synthesis of poly (methacrylic acid-g-ethylene glycol) hydrogels which shows large changes in swelling due to changes in pH, temperature and solvent composition. They are also used as divinylic methacrylic monomers which are widely used to form copolymers with divinylbenzene (DVB) and glycidyl methacrylate (GMA) or hydroxyethyl methacrylate (HEMA) comonomers. As a monomer, it is typically used in dental resin materials that can cause specific stress responses in eukaryotic cells. It commonly used to aesthetically restore the structure and function of teeth impaired by caries, erosion, or fracture.
It is cytotoxic via apoptosis, induce genotoxic effects, and delay the cell cycle. It also influences the response of cells of the innate immune system, inhibit specific odontoblast cell functions, or delay the odontogenic differentiation and mineralization processes in pulp-derived cells including stem cells. It is also used as a diluent co-monomer in dimethacrylate based dental composites as well as being used as a branching agent in the atom transfer radical polymerization (ATRP) of styrene.

Application

Triethylene glycol dimethacrylate (TEGDMA) is a resin monomer widely used in the composition of dentin bonding agents and composite resins to restore teeth structures impaired by caries and/or fractures. However, resin monomers can be released into the oral environment and can trigger hazardous biological effects on oral tissues. The release of the resin monomers due to degradation and incomplete polymerization can occur hours or days after the treatment. Due to its hydrophilic nature, hydrolysis plays an important role in the degradation processe of TEGDMA. Chemical interactions with oral fluids and mechanical influences may also cause the degradation of resin monomers. Direct contact or diffusion of resin monomers through the dentinal tubules creates ways of interaction between dental pulp tissue and resin monomers. Dentin thickness and the severity of caries lesions are important factors in determining the amount of resin monomers interacting with dental pulp tissue. TEGDMA has been reported to cause cytotoxicity, impaired cellular functions, pulpal inflammatory responses, and changes in the immune system. In addition, TEGDMA may reduce the mineralization capacity of dental pulp cells by decreasing the expression of the mineralization related genes pathways and causing adverse effects.

Reference

Krifka, S, et al. "A review of adaptive mechanisms in cell responses towards oxidative stress caused by dental resin monomers. " Biomaterials 34.19(2013):4555-4563.

Description

Triethylene glycol dimethacrylate was employed to optimize the dilution of high-viscosity monomers and to link together the macromolecules constituting the polymer, to make their three-dimentional structure more rigid. It is also a crosslinking agent of acrylic resins, used in sealents or in dental bonding resins. These are mainly used in dentistry, by dental technicians and dentists.

Chemical Properties

Colorless liquid

Uses

Esters of acrylic acid and methacrylic acid, more commonly known as acrylates and methacrylates are key raw materials in the coatings and printing industry, and in food packaging.

Uses

Triethyleneglycol dimethacrylate is a methacrylic monomer for use as cross-linking agent for adhesives and dental restorative materials.

Uses

TEGDMA is a monomer typically used in dental resin materials that can cause specific stress responses in eukaryotic cells.

General Description

Triethylene glycol dimethacrylate (TEGDMA) is a hydrophilic, low viscosity, difunctional methacrylic monomer employed as a crosslinking agent.

Triethylene glycol dimethacrylate synthesis

753-73-1
150-76-5
80-62-6
109-16-0
Synthesis of Triethylene glycol dimethacrylate from DIMETHYLTIN DICHLORIDE and 4-Methoxyphenol and Methyl methacrylate

Triethylene glycol dimethacrylate Preparation Products And Raw materials

Raw materials

Preparation Products


Triethylene glycol dimethacrylate Suppliers

Global( 216)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 15427 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com China 22607 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679
86-0551-65418697 info@tnjchem.com China 3000 55
career henan chemical co
+86-0371-55982848
sales@coreychem.com China 29954 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293
+86 0531-67809011 sales@sdzschem.com CHINA 2940 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930503282
sales3@crovellbio.com China 5942 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5917 58

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View Lastest Price from Triethylene glycol dimethacrylate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2022-01-20 Triethylene glycol dimethacrylate
109-16-0
US $0.00 / Kg/Drum 1KG 99.9% 100000kg per month Wuhan Mulei New Material Technology Co. Ltd
2021-12-01 Triethylene Glycol Dimethacrylate
109-16-0
US $10.00 / Kg/Drum 10g 99 % 10000kg Hebei Crovell Biotech Co Ltd
2021-07-13 Triethylene glycol dimethacrylate
109-16-0
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd

Triethylene glycol dimethacrylate Spectrum


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