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Octadecanamine

Description Octadecanamine The raw material for preparation of softener D3 Raw materials for preparation of dye leveler DC Chemical Properties Uses Production method
Octadecanamine
Octadecanamine structure
CAS No.
124-30-1
Chemical Name:
Octadecanamine
Synonyms
A18;A 86;amineab;alamine7;Amine AB;armeen18;Armofilm;farmin80;Noram SH;Alamine 7
CBNumber:
CB9292633
Molecular Formula:
C18H39N
Formula Weight:
269.51
MOL File:
124-30-1.mol

Octadecanamine Properties

Melting point:
50-52 °C(lit.)
Boiling point:
232 °C32 mm Hg(lit.)
Density 
0.862
vapor pressure 
10 mm Hg ( 72 °C)
refractive index 
1.4522
Flash point:
300 °F
storage temp. 
Store below +30°C.
form 
Prills
pka
10.6(at 25℃)
color 
White
Water Solubility 
practically insoluble
FreezingPoint 
53.1℃
BRN 
636111
InChIKey
REYJJPSVUYRZGE-UHFFFAOYSA-N
CAS DataBase Reference
124-30-1(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS)
OCTADECYLAMINE
FDA 21 CFR
173.310
EWG's Food Scores
1-3
FDA UNII
FFV58UNY7O
NIST Chemistry Reference
1-Octadecanamine(124-30-1)
EPA Substance Registry System
Stearamine (124-30-1)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS05,GHS08,GHS09
Signal word  Danger
Hazard statements  H400-H304-H315-H318-H373-H410
Precautionary statements  P273-P280-P301+P310-P305+P351+P338+P310-P331-P501-P260-P280a-P301+P310a-P305+P351+P338-P405-P501a
Hazard Codes  Xi,N,Xn
Risk Statements  36/37/38-41-38-65-50/53-48/22
Safety Statements  26-36-37/39-28B-62-61-60-36/37/39
RIDADR  3259
WGK Germany  2
RTECS  RG4150000
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29211980
Toxicity LD50 orally in Rabbit: 2395 mg/kg

Octadecanamine price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.41029 Octadecylamine for synthesis 124-30-1 250 g $52.35 2021-03-22 Buy
Sigma-Aldrich 305391 Octadecylamine 97% 124-30-1 25g $131 2021-03-22 Buy
Sigma-Aldrich 8.41029 Octadecylamine for synthesis 124-30-1 1 kg $155.4 2021-03-22 Buy
Sigma-Aldrich 305391 Octadecylamine 97% 124-30-1 100g $391 2021-03-22 Buy
TCI Chemical O0014 Stearylamine >85.0%(GC) 124-30-1 25g $16 2021-03-22 Buy

Octadecanamine Chemical Properties,Uses,Production

Description

Octadecylamine, also known as N-stearylamine or 1-aminooctadecane, belongs to the class of organic compounds known as monoalkylamines. These are organic compounds containing an primary aliphatic amine group. Octadecylamine is a very strong basic compound (based on its pKa). An 18-carbon primary aliphatic amine.

Octadecanamine

Octadecanamine

Octadecanamine (Stearyl amine or 1-amino-octadecane) is a kind of aliphatic amines compound being subject to industrial mass production. At room temperature, it is as white crystals with the molecular weight being 269.5, melting point being 52.8612, boiling point being 232.12 (4.27 kPa), the flash point being 149 ℃, the relative density being 0.8618 and the refractive index being 1.4522. It is slightly soluble in acetone, kerosene and methanol, easily soluble in carbon tetrachloride, chloroform, ethanol, isopropanol and toluene, soluble in alcohol, ether, benzene but insoluble in water. It has alkaline property and can react with hydrochloric acid to generate adduct product. Its toxicity is lower than low-grade amine. Rat being subject to oral administration of 500 × 10-6 Octadecanamine for two consecutive years get no significant adverse consequences. It has irritation effect on human skin and mucous membrane. It can be used as the intermediates for organic synthesis such as for the production of octadecyl quaternary ammonium salts and various kinds of additives such as cationic thickening agent, mineral flotation agents, emulsifier of synthetic resins, pesticides and asphalt, antistatic agents, wetting agents, waterproofing agents, surfactants as well as biocides of fabric, color former of color photo and the corrosion inhibitor of the oil refining device. It can be generated by the reaction of stearic acid and ammonia for generating octadecanitrile and further catalytic hydrogenation under pressure for further reduction of enamine.

The raw material for preparation of softener D3

Softener D3 has its scientific name being N-octadecyl-amino ethyl propionate and belongs to amphoteric surfactants. Common product appears as a white or pale yellow paste-like with the solid content being 20% ± 1% and the pH value of the 2% aqueous solution being 7.0 to 8.0. It can be dissolved in warm water of 50~60 ℃This product is non-toxic, non-corrosive and is mainly used as an additive upon finishing of real silk fabric. It can also be used as the softening finishing agent of silk, wool and chemical fiber. Finishing with it can make the fabrics feel soft, smooth and appear plump, shiny and bright and can also give the fabric elasticity and improve the flex abrasion which can tolerate high temperature of 180 ℃. It can be produced through the condensation reaction between Octadecanamine and methyl acrylate at 80 ℃ and further saponification with triethanolamine and Peregal O.

Raw materials for preparation of dye leveler DC

Dye leveler DC has its chemical name be the octadecyl dimethyl benzyl ammonium chloride. At room temperature, it appears as light yellow sticky liquid and is soluble in water with the pH of its 0.1% aqueous solution being 5.2 to 5.5. It is capable of tolerating the hard water, inorganic salts and acids but not alkali. This product is cationic and has a strong affinity to the acrylic fibers with excellent dye leveling effect on the cationic dyes. It is mainly used as the dye-leveling agent in case of application of cationic dye for dyeing a variety of acrylic fibers and for giving a good hand feeling. The common amount is usually 2% to 3% of the weight of the fabric upon light color while being 0.8% to 1.5% upon dark color.
The product also can be used as the softening agents of cellulose acetate as well as sanitizers. It can be produced through the methylation reaction of Octadecanamine and its further reaction with benzyl chloride.
The above information is edited by the chemicalbook of Dai Xiongfeng.

Chemical Properties

It appears as white waxy crystalline solid with alkalinity. It is soluble in chloroform, soluble in alcohol, ether and benzene, slightly soluble in acetone and insoluble in water.

Uses

It can be used as the intermediates of organic synthesis for the production of octadecyl quaternary ammonium salts and many kinds of additives such as cationic grease thickener, mineral flotation agents, pesticides and asphalt emulsifier, fabric antistatic agents, softeners, wetting agents and waterproofing agents, surfactants, biocides, color former of color photo and the corrosion inhibitor of the oil refining device. Putting the Octadecanamine in mixture with ethylene oxide in a molar ratio of 1: 2 for reaction at 150-190 ℃ can gives stearyl diethanolamine [10213-78-2] with a yield of 80%. Stearyl diethanolamine belongs to a non-ionic antistatic agent and can be applied to polypropylene, polystyrene and ABS resin.

Production method

It can be obtained from stearic acid via ammoniation and hydrogenation. Send stearic acid and ammonia continuously and quantitatively into the liquid phase reaction tower for ammoniation at 350 ℃ to generate octadecane nitrile. After washing with water and refinement, it was sent to the autoclave and was subject to hydrogenation reaction under 130 ℃ and the pressure of about 3.5MPa with the nickel catalyst for generation of Octadecanamine. The hydrogenated product was subject to precipitation for removing the catalyst to derive the final products. During laboratory preparation, the octadecane nitrile and anhydrous ethanol are subject to boiling under reflux and further put into sodium metal for reaction. Pour the reaction mixture into the dilute hydrochloric acid with cooling obtaining the Octadecanamine hydrochloride. Further treat with 20% sodium hydroxide solution treated with 20% sodium hydroxide solution can produce Octadecanamine. The yield is 85%. Fixed consumption amount of material: stearic acid: 1165kg/t, ammonia 151kg/t, hydrogen gas: 211m3, nickel catalyst: 6kg/t.

Chemical Properties

White prills

Definition

ChEBI: An 18-carbon primary aliphatic amine.

Production Methods

Octadecylamine is manufactured under the trade names of Adogen 142D (Ashland), Alamine 7D (General Mills), Armeen 18D (Armak), Kemamine P- 990D (Humko), and Jetamine 18D (Jetco).

General Description

A white solid. Insoluble in water and less dense than water. Hence floats on water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Octadecanamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

ACUTE/CHRONIC HAZARDS: Exposure to Octadecanamine may cause sensitization of the skin.

Fire Hazard

Octadecanamine is combustible.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.

Octadecanamine Preparation Products And Raw materials

Raw materials

Preparation Products


Octadecanamine Suppliers

Global( 289)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5917 58
ShenZhen Ipure Biology import and export company co.,ltd
18071025641 18071025641
eric@ipurechemical.com CHINA 11336 58
Capot Chemical Co.,Ltd.
+86(0)13336195806 +86-571-85586718
+86-571-85864795 sales@capotchem.com China 20010 60
Hangzhou FandaChem Co.,Ltd.
008615858145714
+86-571-56059825 fandachem@gmail.com CHINA 8882 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29959 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6369 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 37282 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58

View Lastest Price from Octadecanamine manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-10-20 Octadecanamine
124-30-1
US $5.00 / KG 1KG 99% 30 Tons Wuhan wingroup Pharmaceutical Co., Ltd
2021-08-31 Octadecanamine
124-30-1
US $10.00 / Kg/Bag 1Kg/Bag 99%min 5000 Wuhan Monad Medicine Tech Co.,LTD
2021-07-22 Octadecanamine
124-30-1
US $86.00 / KG 1GK 99% 1 ton Baoji Guokang Bio-Technology Co., Ltd.

Octadecanamine Spectrum


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