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4-Chloro-2-methylaniline

4-Chloro-2-methylaniline
4-Chloro-2-methylaniline
CAS No.
95-69-2
Chemical Name:
4-Chloro-2-methylaniline
Synonyms
Ipsilon;devalredk;fastredtr;redbasentr;devalredtr;RED TR BASE;Deval Red K;Fast Red TR;fastredtr11;Deval Red TR
CBNumber:
CB9854705
Molecular Formula:
C7H8ClN
Formula Weight:
141.6
MOL File:
95-69-2.mol

4-Chloro-2-methylaniline Properties

Melting point:
29 °C
Boiling point:
241 °C(lit.)
Density 
1.19 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.583(lit.)
Flash point:
211 °F
storage temp. 
2-8°C
form 
neat
BRN 
878505
CAS DataBase Reference
95-69-2(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, 4-chloro-2-methyl-(95-69-2)
EPA Substance Registry System
Benzenamine, 4-chloro-2-methyl-(95-69-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,N
Risk Statements  45-23/24/25-50/53-68
Safety Statements  53-45-60-61
RIDADR  UN 2239 6.1/PG 3
WGK Germany  3
RTECS  XU5000000
8-10
HazardClass  6.1(b)
PackingGroup  III
Hazardous Substances Data 95-69-2(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P311 Call a POISON CENTER or doctor/physician.
P391 Collect spillage. Hazardous to the aquatic environment
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container to..…

4-Chloro-2-methylaniline price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 590711 4-Chloro-2-methylaniline 98% 95-69-2 10g $39.5 2018-11-13 Buy
Sigma-Aldrich 46282 4-Chloro-2-methylaniline analytical standard 95-69-2 250mg $46.4 2018-11-13 Buy
TCI Chemical A0704 4-Chloro-2-methylaniline >98.0%(GC)(T) 95-69-2 25g $29 2018-11-22 Buy
TCI Chemical A0704 4-Chloro-2-methylaniline >98.0%(GC)(T) 95-69-2 100g $76 2018-11-22 Buy
TCI Chemical A0704 4-Chloro-2-methylaniline >98.0%(GC)(T) 95-69-2 500g $231 2018-11-22 Buy

4-Chloro-2-methylaniline Chemical Properties,Uses,Production

Chemical Properties

clear brown liquid

Chemical Properties

The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.

Uses

Intermediate.

General Description

Gray to white solid with a weak fishy odor. Sinks in water. Freezing point is 77°F.

Air & Water Reactions

May be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

4-Chloro-2-methylaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. . A halogenated amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Hazard

Toxic by ingestion and inhalation. Probable carcinogen.

Health Hazard

Inhalation, ingestion, or skin contact causes bluish tint in fingernails, lips, and ears. Headache, drowsiness, and nausea also occur. Contact with eyes causes irritation.

Fire Hazard

Special Hazards of Combustion Products: Toxic oxides of nitrogen and hydrochloric acid fumes may form.

Safety Profile

Confirmed carcinogen. Poison by ingestion and subcutaneous routes. Human mutation data reported. In the presence of copperpI) chloride catalyst decomposition occurs above 239'C. When heated to decomposition it emits toxic fumes of Cland NOx. See also other chloro toluidme entries.

Potential Exposure

Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

Shipping

UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials

Incompatibilities

Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.

4-Chloro-2-methylaniline Preparation Products And Raw materials

Raw materials

Preparation Products


4-Chloro-2-methylaniline Suppliers

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4-Chloro-2-methylaniline Spectrum


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