4-나이트로-1,2-벤젠 다이아민

4-나이트로-1,2-벤젠 다이아민
4-나이트로-1,2-벤젠 다이아민 구조식 이미지
카스 번호:
99-56-9
한글명:
4-나이트로-1,2-벤젠 다이아민
동의어(한글):
4-나이트로-1,2-벤젠다이아민;4-나이트로-1,2-벤젠다이아민;4-나이트로-o-페닐렌다이아민;p-니트로-o-페닐렌디아민
상품명:
4-Nitro-o-phenylenediamine
동의어(영문):
4-nitrobenzene-1,2-diamine;4-NITRO-1,2-PHENYLENEDIAMINE;4-n-o-pda;p-nitro-o-phenylenediamine;4ndb;4-no;4-nop;4-nopd;4NOPPDA;202-766-3
CBNumber:
CB1453625
분자식:
C6H7N3O2
포뮬러 무게:
153.14
MOL 파일:
99-56-9.mol
MSDS 파일:
SDS

4-나이트로-1,2-벤젠 다이아민 속성

녹는점
199-201 °C (lit.)
끓는 점
276.04°C (rough estimate)
밀도
1.3682 (rough estimate)
굴절률
1.6910 (estimate)
저장 조건
Keep in dark place,Inert atmosphere,Room temperature
용해도
1N HCl: 에탄올, 1:1: 용해성50mg/mL
물리적 상태
가루
산도 계수 (pKa)
2.06±0.10(Predicted)
색상
갈색-빨간색
수용성
1.2g/L(20℃)
Merck
14,6622
BRN
608106
안정성
안정적인. 강산, 강환원제, 강산화제, 산 염화물, 산 무수물과 혼합할 수 없습니다.
InChIKey
RAUWPNXIALNKQM-UHFFFAOYSA-N
CAS 데이터베이스
99-56-9(CAS DataBase Reference)
IARC
3 (Vol. 16, Sup 7) 1987
EPA
Nitro-o-phenylenediamine (99-56-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn
위험 카페고리 넘버 22-43-68-40-36/37/38-20/21/22
안전지침서 36/37-45-36-26-22
유엔번호(UN No.) 2811
WGK 독일 3
RTECS 번호 ST2975000
TSCA Yes
위험 등급 6.1
포장분류 II
HS 번호 29215119
유해 물질 데이터 99-56-9(Hazardous Substances Data)
독성 LD50 oral in rat: 681mg/kg
기존화학 물질 KE-25967
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
예방조치문구:
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
NFPA 704
1
2 0

4-나이트로-1,2-벤젠 다이아민 MSDS


3,4-Diaminonitrobenzene

4-나이트로-1,2-벤젠 다이아민 C화학적 특성, 용도, 생산

화학적 성질

This substance is an orange-red powder that can be dissolved in ethanol, acetone, and hydrochloric acid solution, but is not soluble in water.

주요 응용

4-Nitro-1,2-phenylenediamine is a hair dye constituent with potential mutagenic activity. It is used in oxidation hair dye formulations at a maximum concentration of 1.0 %, which after mixing typically in a 1:1 ratio with hydrogen peroxide just prior to use, corresponds to a concentration of 0.5% upon application.

생산 방법

Commercial production of 4-nitro-o-PDA was first reported in the United States in 1946. Two U.S. companies were reported to produce undisclosed amounts of the chemical in 1975. U.S. imports of 4-nitro-o-PDA were reported to be about 1900 kg in 1973 and 1100 kg in 1975. 4-Nitro-o-PDAis used in fur dyes, inks, and semipermanent yellow hair coloring formulations requiring a yellow color component that does not involve the use of hydrogen peroxide in the color development.
Occupational exposure to 4-nitro-o-PDA may occur through inhalation and dermal contact with this compound at workplaces where p-PDA is produced or used. The general population may be exposed to the compound via dermal contact, primarily through the use of hair dyes containing this compound.

정의

ChEBI: 4-nitro-1,2-phenylenediamine is the primary amino compound that is 1,2-phenylenediamine (o-phenylenediamine) substituted at the 4- (para-) position by a nitro group. It is a primary amino compound and a C-nitro compound. It is functionally related to a 1,2-phenylenediamine.

일반 설명

4-nitro-o-phenylenediamine appears as dark red needles or red solid.

공기와 물의 반응

Insoluble in water.

반응 프로필

4-Nitro-o-phenylenediamine is incompatible with strong oxidizing agents, strong acids, strong reducing agents, acid chlorides and acid anhydrides.

화재위험

Flash point data for 4-Nitro-o-phenylenediamine are not available; however, 4-Nitro-o-phenylenediamine is probably combustible.

Safety Profile

Moderately toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Questionable carcinogen. When heated to decomposition it emits toxic fumes of NOx,.

Purification Methods

Crystallise the diamine from water. [Beilstein 13 IV 75.]

4-나이트로-1,2-벤젠 다이아민 준비 용품 및 원자재

원자재

준비 용품


4-나이트로-1,2-벤젠 다이아민 공급 업체

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