ChemicalBook >제품 카탈로그 >유기 화학>아미드>나프 텐 아민 유도체>O-페닐렌다이아민

O-페닐렌다이아민

O-페닐렌다이아민 구조식 이미지

카스 번호:: 95-54-5

한글명:: O-페닐렌다이아민

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상품명:: o-Phenylenediamine

동의어(영문):: benzene-1,2-diamine;OPDA;Phenylenediamine;OPD;1,2-PHENYLENEDIAMINE;1,2-DIAMINOBENZENE;orthamine;1,2-BENZENEDIAMINE;ORTHO-TOLUENEDIAMINE;ORTHOPHENYLENEDIAMINE

CBNumber:: CB9854699

분자식:: C6H8N2

포뮬러 무게:: 108.14

MOL 파일:: 95-54-5.mol

MSDS 파일:: SDS

속성

안전

MSDS

용도

공급 업체 559

O-페닐렌다이아민 속성

녹는점: 100-102 °C

끓는 점: 256-258 °C

밀도: 1,27 g/cm³

증기 밀도: 3.7 (vs air)

증기압: 0.01 mm Hg ( 25 °C)

굴절률: 1.6339 (estimate)

인화점: 110°C

저장 조건: 2-8°C

용해도: H₂O: 1정/10mL, 투명, 무색

물리적 상태: 태블릿 형태

색상 색인 번호: 76010

산도 계수 (pKa): 4.46(at 25℃)

색상: 흰색에서 황백색까지

pH 범위: Green Q uorescence (3.1) to nonQ uorescence (4.4)

수소이온지수(pH): 7-8 (50g/l, H2O, 20℃)

폭발한계: 1.5%(V)

수용성: 20°C에서 <0.1g/100mL

감도: Air & Light Sensitive

Merck: 14,7284

BRN: 606074

노출 한도: TLV-TWA 0.1 mg/m³; carcinogenicity: A2- Suspected Human Carcinogen (ACGIH 1989).

안정성: 안정적인. 강한 산화제와 호환되지 않습니다.

주요 응용: bottom antireflective coatings, semiconductor devices, hair dyes, detecting antibody, substrate for horseantibody, glucose, streptomycin, penicillin, sulfonamide, neuroglobin, substrate for horseradish peroxidase

LogP: 0.12-0.17 at 20-25℃ and pH7-8

CAS 데이터베이스: 95-54-5(CAS DataBase Reference)

IARC: 2B (Vol. 123) 2020

NIST: 1,2-Benzenediamine(95-54-5)

EPA: 1,2-Phenylenediamine (95-54-5)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	T,N
위험 카페고리 넘버	20/21-25-36-40-43-50/53-68
안전지침서	28-36/37-45-60-61-1/2
유엔번호(UN No.)	UN 1673 6.1/PG 3
WGK 독일	3
RTECS 번호	SS7875000
F 고인화성물질	8-10-23
자연 발화 온도	540 °C
TSCA	Yes
위험 등급	6.1
포장분류	III
HS 번호	29215119
유해 물질 데이터	95-54-5(Hazardous Substances Data)
독성	LD50 in rats (mg/kg): 1070 orally; 516 i.p., C. Burnett et al., J. Toxicol. Environ. Health 2, 657 (1977)
기존화학 물질	KE-02174
유해화학물질 필터링	97-1-334
함량 및 규제정보	물질구분: 유독물질; 혼합물(제품)함량정보: 페닐렌디아민과 그 염류 및 이를 25% 이상 함유한 혼합물

그림문자(GHS):

신호 어:

Danger

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	P- 코드
H301	삼키면 유독함	급성 독성 물질 - 경구	구분 3	위험	P264, P270, P301+P310, P321, P330,P405, P501
H317	알레르기성 피부 반응을 일으킬 수 있음	피부 과민성 물질	구분 1	경고	P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319	눈에 심한 자극을 일으킴	심한 눈 손상 또는 자극성 물질	구분 2A	경고	P264, P280, P305+P351+P338,P337+P313P
H341	유전적인 결함을 일으킬 것으로 의심됨 (노출되어도 생식세포 유전독성을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재)	생식세포 변이원성 물질	구분 2	경고	P201,P202, P281, P308+P313, P405,P501
H351	암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재)	발암성 물질	구분 2	경고	P201, P202, P281, P308+P313, P405,P501
H410	장기적 영향에 의해 수생생물에 매우 유독함	수생 환경유해성 물질 - 만성	구분 1	경고	P273, P391, P501

예방조치문구:

P202	모든 안전 조치 문구를 읽고 이해하기 전에는 취급하지 마시오.
P273	환경으로 배출하지 마시오.
P280	보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P310	삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P302+P352	피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338	눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

NFPA 704

	1
0		0

O-페닐렌다이아민 MSDS

C.I. Oxidation base 16

O-페닐렌다이아민 C화학적 특성, 용도, 생산

화학적 성질

o-Phenylenediamine is a white to brownish crystalline substance that turns red upon exposure to air.

용도

o-Phenylenediamine is an amino substituted benzene used in the manufacture of dyes. Potential use in sensitive immunosensor for cancer biomarker.Environmental toxin on US EPA Toxic Release Inventory list (TRI) list.

정의

ChEBI: A phenylenediamine in which the two amino groups are ortho to each other.

일반 설명

Colorless monoclinic crystals if pure; technical grade brownish-yellow crystals or a sandy brown solid. Used in manufacture of dyes, photography, organic synthesis.

공기와 물의 반응

Soluble in water [Hawley]. Melting point 219 F. Flash point 277 F. Toxic by skin absorption, inhalation or ingestion. Even as a solid will spot downwind area brown/purple (Roger Patrick, DuPont Engineer).

반응 프로필

o-Phenylenediamine a weak aromatic amine base neutralizes acids in exothermic reactions to form salts. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Darkens on exposure to air (Roger Patrick, DuPont Engineer).

건강위험

The toxic effects of m-phenylenediamineare similar to its ortho- and para-isomers.The toxic symptoms were tremor, excite ment, convulsions, and cyanosis, and col lapse at fatal dose. Other symptoms includeddecreased blood pressure and pulse rate.Chronic toxic effects resulting from the oralapplication of an aqueous solution of thiscompound were increase in liver and to alesser extent, kidney weights. No carcinogenicity was observed in test animals. Thecompound was excreted rapidly, unchanged.
LD50 value, oral (rats): 650 mg/kg.

화재위험

Flash point data for o-Phenylenediamine are not available. o-Phenylenediamine is probably combustible.

Safety Profile

Confirmed carcinogen. Poison by ingestion and intraperitoneal routes. Moderately toxic by subcutaneous route. Mildly toxic by skin contact. Mutation data reported. A pesticide and pharmaceutical. When heated to decomposition it emits toxic fumes of NOx. See also other phenylenediamine entries and AMINES

잠재적 노출

Used as an intermediate in the making of dyes; pesticides, pharmaceuticals, and rubber chemicals; in making fungicides and other chemicals; in photographic and analytical procedures and processes

Carcinogenicity

o-PDA (dihydrochloride) induced hepatocellular carcinomas during an 18-month feeding study in male Charles River CD rats given diets containing 2000 or 4000 ppm of the chemical (female rats not used in this study). No significant carcinogenic effects were observed in male and female CD-1 mice given higher doses (6872 or 13,743 ppm) of the compound.

운송 방법

UN1673 Phenylenediamines (o-, m-, p-), Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Crystallise the diamine from aqueous 1% sodium hydrosulfite (charcoal), wash it with ice-water and dry it in a vacuum desiccator, or sublime it in vacuo. It has been purified by recrystallisation from toluene and zone refined [Anson et al. J Am Chem Soc 108 6593 1986]. Purification by refluxing a CH2Cl2 solution containing charcoal is also carried out followed by evaporation and recrystallisation [Koola & Kochi J Org Chem 52 4545 1987], protect from light. The acetate has m 186o. [Beilstein 13 IV 38.]

비 호환성

Dust may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, acid chlorides; acid anhydrides; chloroformates. Heat and light contribute to instability. Keep away from metals; 1,2-PHENYLENEDIAMINE a weak aromatic amine base neutralizes acids in exothermic reactions to form salts. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Darkens on exposure to air (Roger Patrick, DuPont Engineer).

폐기물 처리

Controlled incineration whereby oxides of nitrogen are removed from the effluent gas by scrubber, catalytic or thermal device.

O-페닐렌다이아민 준비 용품 및 원자재

원자재

황화나트륨(9수화물) 황화나트륨 O-클로로니트로벤젠 트리에틸아민 2-니트로아닐린 1,2-디클로로벤젠

준비 용품

4-QUINOXALIN-2-YLPHENOL 1H-Benzimidazole-2-methanol Quinoxaline Methylcyanocarbamate 2-(a-Hydroxyethyl)benzimidazole (1-METHYL-1H-BENZIMIDAZOL-2-YL)METHYLAMINE 2-(2-PYRIDYL)BENZIMIDAZOLE 2-퀴노자린카르복실산 2,3-피라진디카르복실릭 안하이드라이드 Oxatomide 2-Benzimidazolecarboxylic acid 2'-AMINOACETANILIDE 2-QUINOXALINETHIOL QUINTIOPHOS Oxfendazole O-페난트롤린 FUBERIDAZOLE Sodium benzotriazole 2-Methylbenzimidazole 1H-BENZOIMIDAZOLE-2-THIOL Vat Red 14 2-(DICHLOROMETHYL)BENZIMIDAZOLETHIOL dispersant BZS BASIC YELLOW 40 Vat Brown B 티오판산-메틸 ETHYL 2-QUINOXALINECARBOXYLATE 2,3-DIHYDROXYQUINOXALINE-6-CARBOXYLIC ACID 3-METHYL-2-QUINOXALINOL 5,12-DIHYDRO-5,7,12,14-TETRAZAPENTACENE 오메프라졸 Bendazol 4-bromo-2,1,3-benzothiadiazole 2-메르캅토 벤즈이미다졸 2-CHLORO-3-METHYL-QUINOXALINE 3-AMINO-PHENAZIN-2-OL 1H-BENZIMIDAZOLE-2-CARBONYL CHLORIDE HYDROCHLORIDE 메틸퀴녹스알린 2,3-DIAMINOPHENAZINE QUINOXALINE-2,3-DICARBOXYLIC ACID

O-페닐렌다이아민 공급 업체

글로벌( 559)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Masteam Bio-tech Co., Ltd.	+86-15200345168 +86-15200345168	bruce.lei@masteam.com	CHINA	153	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49739	58
Guangzhou Tosun Pharmaceutical Limited	+8618922120635	sales@toref-standards.com	China	1000	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5993	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1807	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60