1,3-디클로로프로펜
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1,3-디클로로프로펜 속성
- 녹는점
- -60 °C
- 끓는 점
- 97-112 °C(lit.)
- 밀도
- 1.2
- 증기압
- E-isomer 3700 Pa, Z-isomer 3500 Pa at 25 °C
- 굴절률
- n
20/D 1.472(lit.)
- 인화점
- 78 °F
- 저장 조건
- 2-8°C
- 용해도
- 클로로포름, 메탄올에 용해됨
- 색상
- Colorless to Light yellow to Light orange
- 수용성
- 16.5&C에서 <0.01g/100mL
- Merck
- 14,3075
- BRN
- 1719556
- 노출 한도
- ACGIH: TWA 1 ppm (Skin)
NIOSH: TWA 1 ppm(5 mg/m3)
- InChIKey
- UOORRWUZONOOLO-OWOJBTEDSA-N
- LogP
- 2.040
- CAS 데이터베이스
- 542-75-6(CAS DataBase Reference)
- IARC
- 2B (Vol. 41, Sup 7, 71) 1999
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | T,N | ||
---|---|---|---|
위험 카페고리 넘버 | 10-20/21-25-36/37/38-43-50/53-65-24/25-20 | ||
안전지침서 | 36/37-45-60-61 | ||
유엔번호(UN No.) | UN 1992 3/PG 3 | ||
OEB | B | ||
OEL | TWA: 1 ppm (5 mg/m3) [skin] | ||
WGK 독일 | 3 | ||
RTECS 번호 | UC8310000 | ||
TSCA | Yes | ||
위험 등급 | 3 | ||
포장분류 | II | ||
HS 번호 | 29032990 | ||
유해 물질 데이터 | 542-75-6(Hazardous Substances Data) | ||
기존화학 물질 | KE-05-0466 | ||
유해화학물질 필터링 | 97-1-428 | ||
함량 및 규제정보 | 물질구분: 유독물질; 혼합물(제품)함량정보: 1,3-디클로로프로펜 및 이를 1.0% 이상 함유한 혼합물 |
1,3-디클로로프로펜 C화학적 특성, 용도, 생산
개요
This nematocide is used as a sol fumigant prior to crop cultivation. Mainly farmers and process operators employed at pesticide plants are exposed.화학적 성질
1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.용도
1,3-Dichloropropene (a technical-grade mixture of the cis-and transisomers) is used as a preplanting fumigant, mainly for the control of nematodes affecting the roots of plants, selected plant diseases, garden centipedes, wireworms, and weeds; as a solvent; and as an intermediate in the manufacture of 3,3-dichloro-1-propene and other pesticides. It is registered for use on all vegetable, fruit, and nut crops, all forage crops, tobacco, all fiber crops, and all nursery crops (EPA 1998). In Hawaii, 1,3-dichloropropene is used to control nematodes on pineapples at planting (Albrecht 1987). In 2009, three products containing 1,3-dichloropropene as an active ingredient were registered for restricted, non-residential use in the United States (EPA 2009). No products containing 1,3-dichloropropene are registered for use by homeowners (EPA 1998).생산 방법
1,3-DCP is produced either by high-temperature chlorination of propylene or from 1,3-dichloro-2-propanol by dehydration with phosphoryl chloride or phosphorus pentoxide in benzene. All commercial preparations of 1,3-DCP are mixtures of the cis- and trans-isomers.According to SRI Consulting, Dow AgroSciences LLC (Freeport, Texas) is the only current manufacturer of 1,3- DCP. Active registrants of 1,3-DCP pesticide formulations include Dow AgroSciences LLC (Indianapolis, Indiana),Soil Chemicals Corporation (Hollister, California), and Trical (Hollister, California).
일반 설명
A clear colorless liquid. Flash point 95°F. Denser (at 10.2 lb / gal) than water and insoluble in water. Vapors are heavier than air. Used to make other chemicals and as soil fumigant.공기와 물의 반응
Highly flammable. Insoluble in water.반응 프로필
1,3-Dichloropropene reacts vigorously with oxidizing materials. Reacts with aluminum, active metals, and halogenated compounds. Also reacts with acids and thiocyanates. Corrosive to magnesium, magnesium alloys and aluminum alloys. Incompatible with some metal salts .건강위험
VAPOR: Irritating to eyes, nose and throat. LIQUID: Will burn skin and eyes. Harmful if swallowed.화재위험
FLAMMABLE. POISONOUS GASES ARE PRODUCED IN FIRE. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Toxic and irritating gases may be generated.농업용
Soil fumigant, Nematicide: This chemical is also used in combinations with dichloropropanes as a soil fumigant to kill nematodes, insects and fungus on cotton, potatoes, tobacco, sugar beets, vegetables, grain, citrus planting sites, deciduous fruit and nut-tree planting sites, and ornamental trees and floral sites. Top four applications in California are on sweet potatoes, carrots, wine grapes and outdoor propagation nurseries. It is used on a wide variety of crops. Not approved for use in EU countries. Actively registered in the U.S.상품명
DURHAM NEMATOCIDE®[C]; FUMAZONE®[C]; NEMAGON®[C]; NEMEX®; PROKILL NEMATOCIDE®[C]; TELONE®; TELONE II®; TELONE II-B®; TELONE® EC DRIP; VIDDEN D®; VORLEX®색상 색인 번호
This nematocide is used as a soil fumigant prior to crop cultivation. Farmers and process operators employed at pesticide plants are mainly exposedSafety Profile
Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact. Mildly toxic by inhalation. A strong irritant. Mutation data reported. A pesticide. A flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxidzers. Reacts vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also ALLYL COMPOUNDS and CHLORIDES.잠재적 노출
Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.Carcinogenicity
Technical-grade 1,3-dichloropropene (co ntaining 1.0% epichlorohydrin as a stabilizer) is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals. The technical-grade 1,3-dichloropropene used in the cancer studies in experimental animals was a mixture of cis- and trans-isomers and varied in purity and the stabilizer used (see Properties).신진 대사 경로
Degradation of 14C-1,3-dichloropropene in aerobic soils in the dark at 25℃ at concentration of approximately 100 μg g-1 results in the formation of 3-chloroallyl alchohol, 3-chloroacrylic acid, numerous minor carboxylic acid metabolites, and carbon dioxide. In addition, there is extensive incorporation of 14C labeled material into the soil organic matter in the soils. By a specific bacterium (Pseudomonas cichorii 170) which is isolated from soil, 1,3-dichloropropene is degraded in different pathways from those of soil degradation. The terminal degradate by this bacterium is acetoaldehye which undergoes mineralization.운송 방법
UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.비 호환성
Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.폐기물 처리
Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.1,3-디클로로프로펜 준비 용품 및 원자재
원자재
1,2-디클로로프로판
Chlorinated hydrocarbon
1.3-Dichloropropene
염소(기체)
에피클로로하이드린
N,N-디메틸아세트아미드
염화알릴
1,1,3-트리클로로프로판
디클로로프로펜
아크롤레인
준비 용품
1,3-디클로로프로펜 공급 업체
글로벌( 208)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 |
sales@hbmojin.com | China | 12446 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 18628 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21666 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9295 | 55 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 |
sales@sdzschem.com | China | 2931 | 58 |
Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 |
admin@nexconn.com | China | 10311 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8820 | 58 |
Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 |
info@konochemical.com | China | 2995 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
Shandong chuangyingchemical Co., Ltd. | 18853181302 |
sale@chuangyingchem.com | CHINA | 5909 | 58 |