피리메탄일

피리메탄일
피리메탄일 구조식 이미지
카스 번호:
53112-28-0
한글명:
피리메탄일
동의어(한글):
피리메탄일
상품명:
Pyrimethanil
동의어(영문):
Pyrimethani;Mytho;SCALA;MYTHOS;Penbotec;Hsdb 6916;Dynmethanil;PYRIMETHANIL;Pyrimethanil 0;Pyrimethanil [iso]
CBNumber:
CB4473703
분자식:
C12H13N3
포뮬러 무게:
199.25
MOL 파일:
53112-28-0.mol
MSDS 파일:
SDS

피리메탄일 속성

녹는점
96°C
끓는 점
362.8±45.0 °C(Predicted)
밀도
1.15
증기압
2.2 x l0-5 Pa (25 °C)
저장 조건
Keep in dark place,Inert atmosphere,Room temperature
용해도
DMSO: 130 mg/mL (652.45 mM)
산도 계수 (pKa)
3.52
물리적 상태
Solid
색상
White to off-white
수용성
0.121g/L(25℃)
BRN
151589
InChI
InChI=1S/C12H13N3/c1-9-8-10(2)14-12(13-9)15-11-6-4-3-5-7-11/h3-8H,1-2H3,(H,13,14,15)
InChIKey
ZLIBICFPKPWGIZ-UHFFFAOYSA-N
SMILES
C1(NC2=CC=CC=C2)=NC(C)=CC(C)=N1
CAS 데이터베이스
53112-28-0(CAS DataBase Reference)
EPA
Pyrimethanil (53112-28-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 N
위험 카페고리 넘버 51/53
안전지침서 60
유엔번호(UN No.) UN 3077
WGK 독일 2
HS 번호 2933599590
유해 물질 데이터 53112-28-0(Hazardous Substances Data)
독성 LD50 (mg/kg): 4061-5358 orally in mice; 4150-5971 orally in rats; >5000 dermally in rats; LC50 (96 hr) in mirror carp, rainbow trout (mg/l): 35.36, 10.56 (Neumann)
기존화학 물질 97-3-245
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P273 환경으로 배출하지 마시오.

피리메탄일 C화학적 특성, 용도, 생산

화학적 성질

Pyrimethanil is a white to light yellow crystalline powder which is sparingly soluble in water but soluble in most organic solvents. Commercial product is available as a brown emulsifiable concentrate.

용도

Pyrimethanil is a broad spectrum anilino-pyrimidine foliar fungicide. Pyrimethanil functions by inhibiting the biosynthesis of methionine in Botrytis cinerea.

제조 방법

Pyrimethanil is produced by reaction of 2-bromo-4,6-dimethylpyrimidine with aniline.

정의

ChEBI: Pyrimethanil is a member of the class of aminopyrimidines that is N-phenylpyrimidin-2-amine carrying two additional methyl substituents at positions 4 and 6. A fungicide used to control grey mould on fruit, vegetables and ornamentals as well as leaf scab on pome fruit. Also commonly employed to control Botrytis cinerea throughout the winemaking process in grapes, must, fermenting must and wine. It has a role as an aryl hydrocarbon receptor agonist, an environmental contaminant, a xenobiotic and an antifungal agrochemical. It is an aminopyrimidine, a secondary amino compound and an anilinopyrimidine fungicide.

일반 설명

Pyrimethanil is an anilino-pyrimidine, broad spectrum fungicide primarily used for the control of gray mould and leaf scab on fruits, vegetables and ornamentals. Its mode of action involves inhibition of the secretion of hydrolytic enzymes by the fungi during the infection process, thus stopping the further development of the disease.

농업용

Fungicide: Used on grapes, strawberries, tomatoes, onions, beans, cucumbers, eggplant, and ornamental.

상품명

SCALA®; SN 100309®

잠재적 노출

A pyrimidine fungicide used on grapes, strawberries, tomatoes, onions, beans, cucumbers, eggplant, and ornamental plants.

신진 대사 경로

Limited data are available in the open literature. Information presented in this summary is abstracted from the data evaluation published by the Pesticide Safety Directorate (PSD, 1995). Hydroxylation at the methyl, phenyl or pyrimidine moiety is the primary metabolic pathway of pyrimethanil in soil, plants and animals. Cleavage of the aniho-pyrimidine linkage was observed as a minor metabolic reaction. The formation of nitro- analogues of pyrimethanil is a novel nitration reaction observed in the soil metabolism study (Scheme 1).

운송 방법

UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo- sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

폐기물 처리

Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. If this material cannot be disposed of according to label instruc- tions, it may be dissolved or mixed with a combustible sol- vent and burned in a chemical incinerator equipped with an afterburner and scrubber. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

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