제1인산암모늄

제1인산암모늄
제1인산암모늄 구조식 이미지
카스 번호:
7722-76-1
한글명:
제1인산암모늄
동의어(한글):
암모늄인산염1가산용액1M;암모늄디하이드로인산염;암모늄이수소오르토인산염;암모늄인산염;암모늄일염기인산염AMMONIUMBIPHOSPHATE;인산이수소암모늄;제1인산암모늄;인산암모늄1염기성;암모늄포스페이트
상품명:
Ammonium dihydrogen phosphate
동의어(영문):
MAP;MONOAMMONIUM PHOSPHATE;AMMONIUM PHOSPHATE;12-61-00;Ammonium dihydrogen;AMMONIUM BIPHOSPHATE;monoammoniumacidphosphate;PHOSPHORIC ACID MONOAMMONIUM SALT;AMMONIUM DIHYDROGEN ORTHOPHOSPHATE;Ammonium Hydrogen Monohydric Phosphate
CBNumber:
CB6131092
분자식:
H6NO4P
포뮬러 무게:
115.03
MOL 파일:
7722-76-1.mol

제1인산암모늄 속성

녹는점
190 °C (dec.) (lit.)
끓는 점
87.4 °C
밀도
1.02 g/mL at 20 °C
증기압
0.066 hPa (125 °C)
RTECS 번호
TC6587000
저장 조건
Inert atmosphere,Room Temperature
용해도
H2O: 0.1 M at 20 °C, 투명, 무색
물리적 상태
고체
물리적 상태
단단한 모양
Specific Gravity
1.803
색상
흰색 또는 무색
pH 범위
3.8 - 4.4
수소이온지수(pH)
3.8-4.4 (25℃, 50mg/mL in H2O)
냄새
백색 결정 또는 분말, 무취
수용성
368g/L(20℃)
최대 파장(λmax)
λ: 260 nm Amax: ≤0.059
λ: 280 nm Amax: ≤0.050
Merck
14,543
InChIKey
LFVGISIMTYGQHF-UHFFFAOYSA-N
LogP
-2.148 (est)
CAS 데이터베이스
7722-76-1(CAS DataBase Reference)
EPA
Monoammonium phosphate (7722-76-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 24/25-36-26
유엔번호(UN No.) UN3264
WGK 독일 1
TSCA Yes
위험 등급 8
포장분류 III
HS 번호 31054000
유해 물질 데이터 7722-76-1(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 5750 mg/kg LD50 dermal Rabbit > 7940 mg/kg
기존화학 물질 KE-01656
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P304+P340 흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P405 밀봉하여 저장하시오.

제1인산암모늄 MSDS


Ammonium dihydrogen phosphate

제1인산암모늄 C화학적 특성, 용도, 생산

순도시험

  (1) 액성 : 이 품목의 수용액(1→100)의 pH는 4.3~5.0이어야 한다.

  (2) 비소 : 이 품목을 비소시험법에 따라 시험할 때, 그 양은 4.0ppm 이하이어야 한다.

  (3) 납 : 「메타인산나트륨」의 순도시험 (2)에 따라 시험한다(4.0ppm 이하).

  (4) 불소화물 : 이 품목 1g을 정밀히 달아 「구연산칼슘」의 순도시험 (8)에 따라 시험한다(10ppm 이하).

확인시험

  이 품목은 확인시험법 중 암모늄염 및 인산염의 반응을 나타낸다.

정량법

  이 품목 약 3g을 정밀히 달아 물 30mL에 녹이고 염화나트륨 5g을 가하여 잘 흔들어 섞고 약 15℃로 유지하면서 1N 수산화나트륨용액으로 적정한다(지시약 : 치몰블루시액 3~4방울).

1N 수산화나트륨용액 1mL = 115.0mg NH4H2PO4

화학적 성질

Ammonium phosphate occurs in two forms-the monobasic, NH4H2P04, and dibasic,(NH4)2HP04, forms, It is a white crystalline solid that is soluble in water. Ammonium phosphate is a product of the reaction between ammonia and phosphoric acid.Ammonium phosphate is an important fertilizer and is used as a fire retardant

물리적 성질

Electrooptic coefficient (cm/stat-volt): γ63=-2.54×10-7, γ41=62×10-7
Dielectric constants: ε0=56.4–55.9 (102 –108 Hz, EC), 16.4–13.7 (102 –10 Hz, E//C).

물리적 성질

White crystalline powder; odorless; density 1.80 g/cm3; readily dissolves in water (40 g/ 100 g); pH of 0.2 molar solution 4.2; slightly soluble in alcohol; insoluble in acetone.

용도

Ammonium dihydrogen phosphate is a general purpose food additive which is readily soluble in water. A 1% solution has a ph of 4.3–5.0. It is used as a dough strengthener and leavening agent in baked goods and as a firming agent and ph control agent in condiments and puddings. It is also used in baking powder with sodium bicarbonate and as a yeast food.

정의

ChEBI: The ammonium salt of phosphoric acid (molar ratio 1:1).

제조 방법

Preparative method similar to its dibasic salt; obtained by reaction of equimolar amounts of ammonia and phosphoric acid:
NH3 + H3PO4 → (NH4)H2PO4.

일반 설명

Ammonium phosphate monobasic (APM) is an inorganic salt widely used in fertilizer, baking powder and yeast production. It is also employed as an agent to control pH of a solution and in corrosion inhibition. APM can be prepared by reacting phosphoric acid with anhydrous ammonia maintaining the pH below 5.8. The change in some of the physical characteristics on its addition to a high carbonate containing unfired and fired illitic shale has been studied.

농업용

Ammonium phosphates refer to a generic class of phosphorus fertilizers and are manufactured by reacting anhydrous ammonia with orthophosphoric acid or superphosphoric acid. These are either in solid or liquid form.
Ammonium phosphate fertilizers are highly soluble in water and fast acting in soil to give nitrogen and phosphorus in a chemical combination. They form an important base for many compound fertilizers. Both mono and diammonium phosphates have good physical properties when synthesized from the wetprocess phosphoric acid. Storage properties and the ease of granulation depends on the amount of impurities, which form a gel like structure (mainly aluminum and iron phosphates). This gel promotes granulation and serves as a conditioner to prevent caking even at moderately high moisture levels. A small proportion of phosphate rock added to phosphoric acid before ammoniation improves the granulation.
Ammonium phosphates, particularly Ammonium dihydrogen phosphate(DAP), are the most popular phosphate fertilizers worldwide because of their high utility and good physical properties. The standard commodity grade of diammonium phosphate is 18-46-0. Pure and completely soluble ammonium phosphates are used mainly as liquid fertilizers. In Britain, diammonium phosphate is not sold directly in this form, but is used to make compound fertilizers with a wide variety of plant foods.

잠재적 노출

Used in fireproofing of textiles; wood and paper; in soldering flux; as a fertilizer; a buffer; in baking powder and food additives.

운송 방법

There are no DOT/UN listed requirements.

Purification Methods

Crystallise it from water (0.7mL/g) between 100o and 0o.

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with air causes this chemical to produce anhydrous ammonia fumes.

폐기물 처리

May be flushed to sewer with huge volumes of water.

제1인산암모늄 준비 용품 및 원자재

원자재

준비 용품


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