테르피놀렌

테르피놀렌
테르피놀렌 구조식 이미지
카스 번호:
586-62-9
한글명:
테르피놀렌
동의어(한글):
테르피놀렌;테르피놀렌(TERPINOLENE);과산화물가가10mmol/L을초과하는터피놀렌;터피노렌;p-멘타-1,4(8)-디엔;터피놀렌
상품명:
Terpinolene
동의어(영문):
p-Mentha-1,4(8)-diene;TERPINOLEN;ALPHA-TERPINOLENE;isoterpinene;TERPINOLENE NATURAL;1-methyl-4-(1-methylethylidene)cyclohexene;TERPINOLENE 90;alpha- Terpinolen;4-ISOPROPYLIDENE-1-METHYLCYCLOHEXENE;1-methyl-4-isopropylidene-1-cyclohexene
CBNumber:
CB6742399
분자식:
C10H16
포뮬러 무게:
136.23
MOL 파일:
586-62-9.mol
MSDS 파일:
SDS

테르피놀렌 속성

녹는점
<25 °C
끓는 점
184-185 °C (lit.)
밀도
0.861 g/mL at 25 °C (lit.)
증기 밀도
~4.7 (vs air)
증기압
~0.5 mm Hg ( 20 °C)
FEMA
3046 | TERPINOLENE
굴절률
n20/D 1.489(lit.)
인화점
148 °F
저장 조건
2-8°C
용해도
Chloroform: Slightly Soluble; Methanol: Slightly Soluble
물리적 상태
투명한 액체
Specific Gravity
0.84
색상
무색 또는 연한 밀짚색 액체.
냄새
디프로필렌 글리콜 중 10.00%. 신선한 우디 달콤한 소나무 감귤류
?? ??
약초
수용성
6.812mg/L(25℃)
JECFA Number
1331
BRN
1851203
Dielectric constant
2.3(Ambient)
안정성
감광성
InChIKey
MOYAFQVGZZPNRA-UHFFFAOYSA-N
LogP
4.33-4.38 at 20-37℃
CAS 데이터베이스
586-62-9(CAS DataBase Reference)
NIST
Cyclohexene, 1-methyl-4-(1-methylethylidene)-(586-62-9)
EPA
Terpinolene (586-62-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 N
위험 카페고리 넘버 50/53-65-43
안전지침서 60-61-24/25-22-23-62
유엔번호(UN No.) UN 2541 3/PG 3
WGK 독일 3
RTECS 번호 WZ6870000
F 고인화성물질 10
위험 등급 3.2
포장분류 III
HS 번호 29021990
유해 물질 데이터 586-62-9(Hazardous Substances Data)
독성 The acute oral LD50 value in rats was reported as 4.39 ml/kg (Levenstein, 1975) and similarly that in mice and rats was reported to be 4.4 ml/kg (Hisamitsu Pharmaceutical Co., Inc., 1973). The acute dermal LD50 value in rabbits exceeded 5 g/kg (Levenstein, 1975).
기존화학 물질 KE-24415
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H304 삼켜서 기도로 유입되면 치명적일 수 있음 흡인 유해성물질 구분 1 위험 GHS hazard pictograms
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
NFPA 704
2
1 0

테르피놀렌 MSDS


p-Menth-1,4(8)-diene

테르피놀렌 C화학적 특성, 용도, 생산

화학적 성질

Terpinolene has a pleasant sweet-piney odor with a somewhat sweet, citrus flavor.

출처

Reported found in citrus juices and oils, black currant, guava, papaya, raspberry, various spice and mint oils, tea, passion fruit, litchi, lovage oil, distilled lime peel oil, ginger, nutmeg, pepper, mace, coriander seed, lovage seed, lovage root, myrtle leaf, pimento berry, pimento leaf, winter savory, smaller galanga, Ethiopian or guinea pepper and ashanti pepper.

용도

Solvent for resins, essential oils; manufacture of synthetic resins, synthetic flavors.

정의

ChEBI: A p-menthadiene with double bonds at positions 1 and 4(8).

제조 방법

By alcoholic sulphuric acid treatment of pinene (Arctander, 1969).

생산 방법

Terpinolene used to be extracted by fractional distillation of wood turpentine. It is now produced bytreatinga-pinene with aqueous H3PO4 at 75 ℃. It is preferable to distill terpinolene under vacuum to minimize the formation of polymeric products at elevated temperatures.

일반 설명

A water-white to light amber colored liquid. Insoluble in water and less dense than water. Flash point 99°F. Used to make plastics and resins.

공기와 물의 반응

Highly flammable. Insoluble in water.

반응 프로필

Terpinolene may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.

위험도

Flammable, moderate fire risk.

건강위험

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Pharmacology

Combinations of terpenes, such as terpinolene, with nonionic surfactants and stabilizers have been patented for use as gallstone solvents. Human cholesterol calculi heated in mixtures containing terpinolene and human bile were dissolved within 1-2 hr (Hisamitsu Pharmaceutical Co., Inc., 1973).

Safety Profile

Mildly toxic by ingestion. A very dangerous fire hazard when exposed to heat or flame. To fight fire, use foam, CO2, dry chemical. Can react with oxidning materials. When heated to decomposition it emits acrid smoke and irritating fumes.

테르피놀렌 준비 용품 및 원자재

원자재

준비 용품


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