Hydrocarbon halides

Hydrocarbon halide, or hydrocarbon for short, refers to the product produced during the process of hydrogen atoms replaced by by halogen (fluorine, chlorine, bromine, iodine) in the hydrocarbon molecules. According to the different hydrocarbon groups, it could be divided into categories like aliphatic halogenated hydrocarbons (including saturated and unsaturated halogenated hydrocarbons), aromatic halogenated hydrocarbons. According to the amount of halogen atoms contained in the molecule, it could be divided into categories like halogenated hydrocarbons, dihalogenated hydrocarbons and polyhalogenated hydrocarbons. Most of the halogenated hydrocarbons are liquid. The proportion of Iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. They are insoluble in water and could be dissolved in any proportion with hydrocarbons, they also could dissolve many other organics. The proportion of Hydrocarbon halide would decreases with the increase of the amount of carbon atoms. When there are the same hydrocarbon groups, the boiling point and the proportion of the halogenated hydrocarbons would increase in the order of chlorinated hydrocarbons, brominated hydrocarbons, and iodinated hydrocarbons. In the isomer, the more branches it gets, the lower boiling point it has. Most of these substances are toxic and can burn. And their combustion properties decrease with the increase of the amount of halogen atoms in the compound. When it comes to storage, fire hazard should be managed in A, B, C three categories according to fire risk indicators. When it catch fire, the gas should be treated by the C class of fire treatment, liquid by B class of fire treatment. Eenough attention should be payed to anti-virus.
The amount of naturally occurring halo hydrocarbons is very small, and the majority of halo hydrocarbons are synthesized by halogenation of alkanes, and compounded by unsaturated hydrocarbons. It also could be compounded during the reaction between alcohol with hydrohalic acid.
The amount of Halohydrocarbons are more isomers than corresponding hydrocarbons. Apart from the carbon isomerism, unsaturated bond position isomerization, cis-trans isomerism and optical isomerism, there are halogen atom isomerizations as well.. when the Halogenated hydrocarbon was named, the hydrocarbon plays a rule as the matrix while halogen atom plays as substituents. The position, number and name of halogen should be lined out before the name of the hydrocarbon. At room temperature, apart from methyl chloride, methyl bromide, ethyl chloride, vinyl chloride and others which are gas in room temperature, the halo hydrocarbon is liquid in general and the highly  halogenated hydrocarbon is solid.
Halohydrocarbons is not dissolvable in water, but soluble in a variety of organic solvents, and can be dissolved in a variety of weak polarity and non-polar organic compounds. So it  is a kind of commonly used solvent. The relative density of iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. The boiling point of halogenated hydrocarbons increases with the increasing atomic amount of halogen atoms. The boiling point of the same series of halogenated hydrocarbons increases with increase of the amount of carbon chain. The more branched the isomer, the lower the boiling point would it have (except from fluorinated alkanes).
The chemical property of halogenated hydrocarbons is much more active than paraffin, so  halogenated hydrocarbons can produce a variety of chemical reactions, and turn them into various types of compounds. It has an important position in organic synthesis. Halo hydrocarbon has been applied widely in many trades, apart from being used as a solvent, it also could be used as refrigerant, extinguishing agent, anesthetics and preservatives.
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Structure Chemical Name CAS MF
1,1,2-Trichloroethane 1,1,2-Trichloroethane 79-00-5 C2H3Cl3
1-FLUOROHEPTANE 1-FLUOROHEPTANE 661-11-0 C7H15F
3-FLUOROPHENYLACETYLENE 3-FLUOROPHENYLACETYLENE 2561-17-3 C8H5F
1H-PERFLUOROOCTANE 1H-PERFLUOROOCTANE 335-65-9 C8HF17
1-BROMO-2,6-DICHLOROBENZENE 1-BROMO-2,6-DICHLOROBENZENE 19393-92-1 C6H3BrCl2
1-Bromo-3-chloro-2-methylpropane 1-Bromo-3-chloro-2-methylpropane 6974-77-2 C4H8BrCl
Perfluorooctyl iodide Perfluorooctyl iodide 507-63-1 C8F17I
hexafluorobenzene hexafluorobenzene 392-56-3 C6F6
2-Fluorobiphenyl 2-Fluorobiphenyl 321-60-8 C12H9F
1-Chloro-3-iodobenzene 1-Chloro-3-iodobenzene 625-99-0 C6H4ClI
1,2-Dichloroethane 1,2-Dichloroethane 107-06-2 C2H4Cl2
3-Methylbenzyl bromide 3-Methylbenzyl bromide 620-13-3 C8H9Br
5-BROMO-2-IODOTOLUENE 5-BROMO-2-IODOTOLUENE 116632-39-4 C7H6BrI
1,3-Bis(chloromethyl)benzene 1,3-Bis(chloromethyl)benzene 626-16-4 C8H8Cl2
1-Iodonaphthalene 1-Iodonaphthalene 90-14-2 C10H7I
1,2,3-Trichlorobenzene 1,2,3-Trichlorobenzene 87-61-6 C6H3Cl3
1,2,4,5-Tetrachlorobenzene 1,2,4,5-Tetrachlorobenzene 95-94-3 C6H2Cl4
2-Chloro-1,3-dimethylbenzene 2-Chloro-1,3-dimethylbenzene 6781-98-2 C8H9Cl
2,2-bis(pentyloxy)propane 2,2-bis(pentyloxy)propane 10076-57-0 C13H28O2
4-BROMOOCTANE 4-BROMOOCTANE 999-06-4 C8H17Br
Di-tert-butylphosphinic acidchloride Di-tert-butylphosphinic acidchloride 677-74-7 C8H18ClOP
1-Bromo-2,2-dimethyl-3,3,3-trifluoropropane 1-Bromo-2,2-dimethyl-3,3,3-trifluoropropane 1447671-73-9 C5H8BrF3
2-Fluoro-4-iodotoluene 2-Fluoro-4-iodotoluene 39998-81-7 C7H6FI
Phosphinic chloride, bis(1-methylethyl)- Phosphinic chloride, bis(1-methylethyl)- 1112-15-8 C6H14ClOP
5-BROMO-1,2,4-TRIMETHYLBENZENE 5-BROMO-1,2,4-TRIMETHYLBENZENE 5469-19-2 C9H11Br
4-BROMO-8-METHYLQUINOLINE 4-BROMO-8-METHYLQUINOLINE 36075-68-0 C10H8BrN
TETRAIODOETHYLENE TETRAIODOETHYLENE 513-92-8 C2I4
3-(PERFLUOROOCTYL)PROPANOL 3-(PERFLUOROOCTYL)PROPANOL 1651-41-8 C11H7F17O
1-tert-butyl-4-iodobenzene 1-tert-butyl-4-iodobenzene 35779-04-5 C10H13I
4,5-DIBROMO-O-XYLENE 4,5-DIBROMO-O-XYLENE 24932-48-7 C8H8Br2
Octafluoronaphthalene Octafluoronaphthalene 313-72-4 C10F8
1-Bromo-6-chlorohexane 1-Bromo-6-chlorohexane 6294-17-3 C6H12BrCl
Chuxiong Trimethylolpropane Chuxiong Trimethylolpropane
1-dichlorophosphoryl-2-methylpropane 1-dichlorophosphoryl-2-methylpropane 5021-98-7 C4H9Cl2OP
1,3,5-Trichlorobenzene 1,3,5-Trichlorobenzene 108-70-3 C6H3Cl3
1,2,4-Trichlorobenzene 1,2,4-Trichlorobenzene 120-82-1 C6H3Cl3
Bromoform Bromoform 75-25-2 CHBr3
3,4-Dichlorotoluene 3,4-Dichlorotoluene 95-75-0 C7H6Cl2
Phosphonic dichloride, (2,2-dimethylpropyl)- Phosphonic dichloride, (2,2-dimethylpropyl)- 54552-71-5 C5H11Cl2OP
Diphenyldichloromethane Diphenyldichloromethane 2051-90-3 C13H10Cl2
alpha-2-Chloroisodurene alpha-2-Chloroisodurene 1585-16-6 C10H13Cl
1,2,3-Tribromopropane 1,2,3-Tribromopropane 96-11-7 C3H5Br3
2-CHLORO-2-METHYLPROPANE-D9 2-CHLORO-2-METHYLPROPANE-D9 918-20-7 C4ClD9
1-CHLORO-2,4-DIFLUOROBENZENE 1-CHLORO-2,4-DIFLUOROBENZENE 1435-44-5 C6H3ClF2
2-Propynoic acid, 3-(4-chlorophenyl)-, methyl ester 2-Propynoic acid, 3-(4-chlorophenyl)-, methyl ester 7515-18-6 C10H7ClO2
Iodomethane Iodomethane 74-88-4 CH3I
1,4-Dichlorobenzene 1,4-Dichlorobenzene 106-46-7 C6H4Cl2
1,1,2,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane 79-34-5 C2H2Cl4
1,3-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]PROPANE 1,3-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]PROPANE 220185-36-4 C35H42P2
[Bis(trifluoroacetoxy)iodo]benzene [Bis(trifluoroacetoxy)iodo]benzene 2712-78-9 C10H5F6IO4
1,12-Dibromododecane 1,12-Dibromododecane 3344-70-5 C12H24Br2
1-BROMO-3-TERT-BUTYLBENZENE 1-BROMO-3-TERT-BUTYLBENZENE 3972-64-3 C10H13Br
PCB No. 99 PCB No. 99 C12H5Cl5
1-BROMO-1-PROPENE 1-BROMO-1-PROPENE 590-15-8 C3H5Br
Perfluorooctane Perfluorooctane 307-34-6 C8F18
1,1,1,3-Tetrachloro-propane 1,1,1,3-Tetrachloro-propane 1070-78-6 C3H4Cl4
3-bromohexane 3-bromohexane 3377-87-5 C6H13Br
2,6-DIBROMOBENZOTHIAZOLE 2,6-DIBROMOBENZOTHIAZOLE 408328-13-2 C7H3Br2NS
(bromomethyl)benzene (bromomethyl)benzene C7H7Br
Tricyclo[3.3.1.13,7]decane, 1,3,5,7-tetrabroMo- Tricyclo[3.3.1.13,7]decane, 1,3,5,7-tetrabroMo- 7314-86-5 C10H12Br4
Bis(4-tert-butylphenyl)iodonium chloride Bis(4-tert-butylphenyl)iodonium chloride 5421-53-4 C20H26ClI
(S)-(+)-Epiboromohydrin (S)-(+)-Epiboromohydrin 96479-96-8 C3H5BrO
1,3-bis(1,2,4-triazol-4-yl)propane 1,3-bis(1,2,4-triazol-4-yl)propane 1228666-88-3 C7H10N6
Baichuan Trimethylolpropane Baichuan Trimethylolpropane
1,2,2-TRIBROMOPROPANE 1,2,2-TRIBROMOPROPANE 14476-30-3 C3H5Br3
1,1,1,2-TETRACHLOROPROPANE 1,1,1,2-TETRACHLOROPROPANE 812-03-3 C3H4Cl4
Di(trimethylol propane) Di(trimethylol propane) 23235-61-2 C12H26O5
1-BROMO-2-CHLOROPROPANE 1-BROMO-2-CHLOROPROPANE 3017-96-7 C3H6BrCl
3-DIETHYLAMINOPROPYL CHLORIDE 3-DIETHYLAMINOPROPYL CHLORIDE 104-77-8 C7H16ClN
3-(2-METHOXYETHOXY)PROPYL BROMIDE 3-(2-METHOXYETHOXY)PROPYL BROMIDE 59551-75-6 C6H13BrO2
1 3-BIS(P-CARBOXYPHENOXY)PROPANE 1 3-BIS(P-CARBOXYPHENOXY)PROPANE 3753-81-9 C17H16O6
2,2-DIPHENYLPROPANE 2,2-DIPHENYLPROPANE 778-22-3 C15H16
4-N-BUTOXYBENZYL BROMIDE 4-N-BUTOXYBENZYL BROMIDE 2417-74-5 C11H15BrO
(R)-Epibromohydrine (R)-Epibromohydrine 51594-57-1 C3H5BrO
4-BROMO-3-CHLOROIODOBENZENE 4-BROMO-3-CHLOROIODOBENZENE 535934-25-9 C6H3BrClI
1,3-DIPHENYLPROPANE 1,3-DIPHENYLPROPANE 1081-75-0 C15H16
1-(BENZYLOXY)-3-CHLOROPROPANE 1-(BENZYLOXY)-3-CHLOROPROPANE 26420-79-1 C10H13ClO
1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE 1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE 91159-11-4 C15H34P2
1-IODO-2,2,3,3,3-PENTAFLUOROPROPANE 1-IODO-2,2,3,3,3-PENTAFLUOROPROPANE 354-69-8 C3H2F5I
3-CHLORO-5-(TRIFLUOROMETHYL)BENZOIC ACID 3-CHLORO-5-(TRIFLUOROMETHYL)BENZOIC ACID 53985-49-2 C8H4ClF3O2
2-FLUORO-6-NITROBENZYL BROMIDE 2-FLUORO-6-NITROBENZYL BROMIDE 1958-93-6 C7H5BrFNO2
3-chloro-2-(chloromethyl)-2-methylpropan-1-ol 3-chloro-2-(chloromethyl)-2-methylpropan-1-ol 5355-54-4 C5H10Cl2O
2-Bromo-5-chloro-1,3-difluorobenzene 2-Bromo-5-chloro-1,3-difluorobenzene 883546-16-5 C6H2BrClF2
ACETALDEHYDE DIPROPYL ACETAL ACETALDEHYDE DIPROPYL ACETAL 105-82-8 C8H18O2
2-(4-BROMOPHENYL)PROPAN-2-OL 2-(4-BROMOPHENYL)PROPAN-2-OL 2077-19-2 C9H11BrO
Dichloro bis(dicyclohexylphosphino)propane palladium(II) Dichloro bis(dicyclohexylphosphino)propane palladium(II) 1041005-52-0 C27H50Cl2P2Pd
1-(4-METHYOXYPHENYL)-1-PROPANOL  97 1-(4-METHYOXYPHENYL)-1-PROPANOL 97 5349-60-0 C10H14O2
Bis-Tris Propane Buffer Bis-Tris Propane Buffer
9-(2-BROMOETHYL)-9H-FLUORENE 9-(2-BROMOETHYL)-9H-FLUORENE 108012-21-1 C15H13Br
HYDROXYPROPYL GUAR HYDROXYPROPYL GUAR
1,1'-[ethylidenebis(oxy)]bis[2-methylpropane] 1,1'-[ethylidenebis(oxy)]bis[2-methylpropane] 5669-09-0 C10H22O2
Vinylbenzyl chloride Vinylbenzyl chloride 30030-25-2 C9H9Cl
4-bromonaphthalen-2-ol 4-bromonaphthalen-2-ol 5498-31-7 C10H7BrO
Trichlorofluoromethane (CFC-11) Trichlorofluoromethane (CFC-11)
1-BROMO-3-IODOPROPANE 1-BROMO-3-IODOPROPANE 22306-36-1 C3H6BrI
1-Chloro-6,6-dimethyl-2-heptene-4-yne 1-Chloro-6,6-dimethyl-2-heptene-4-yne 126764-17-8 C9H13Cl
2-BROMO-2-CHLOROPROPANE 2-BROMO-2-CHLOROPROPANE 2310-98-7 C3H6BrCl
1,1,2-TRIBROMOPROPANE 1,1,2-TRIBROMOPROPANE 14602-62-1 C3H5Br3
2,2-Diethoxypropane 2,2-Diethoxypropane 126-84-1 C7H16O2
1-BROMOPROPANE-2,2-D2 1-BROMOPROPANE-2,2-D2 40422-15-9 C3H7Br
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