Hydrocarbon halides

Hydrocarbon halide, or hydrocarbon for short, refers to the product produced during the process of hydrogen atoms replaced by by halogen (fluorine, chlorine, bromine, iodine) in the hydrocarbon molecules. According to the different hydrocarbon groups, it could be divided into categories like aliphatic halogenated hydrocarbons (including saturated and unsaturated halogenated hydrocarbons), aromatic halogenated hydrocarbons. According to the amount of halogen atoms contained in the molecule, it could be divided into categories like halogenated hydrocarbons, dihalogenated hydrocarbons and polyhalogenated hydrocarbons. Most of the halogenated hydrocarbons are liquid. The proportion of Iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. They are insoluble in water and could be dissolved in any proportion with hydrocarbons, they also could dissolve many other organics. The proportion of Hydrocarbon halide would decreases with the increase of the amount of carbon atoms. When there are the same hydrocarbon groups, the boiling point and the proportion of the halogenated hydrocarbons would increase in the order of chlorinated hydrocarbons, brominated hydrocarbons, and iodinated hydrocarbons. In the isomer, the more branches it gets, the lower boiling point it has. Most of these substances are toxic and can burn. And their combustion properties decrease with the increase of the amount of halogen atoms in the compound. When it comes to storage, fire hazard should be managed in A, B, C three categories according to fire risk indicators. When it catch fire, the gas should be treated by the C class of fire treatment, liquid by B class of fire treatment. Eenough attention should be payed to anti-virus.
The amount of naturally occurring halo hydrocarbons is very small, and the majority of halo hydrocarbons are synthesized by halogenation of alkanes, and compounded by unsaturated hydrocarbons. It also could be compounded during the reaction between alcohol with hydrohalic acid.
The amount of Halohydrocarbons are more isomers than corresponding hydrocarbons. Apart from the carbon isomerism, unsaturated bond position isomerization, cis-trans isomerism and optical isomerism, there are halogen atom isomerizations as well.. when the Halogenated hydrocarbon was named, the hydrocarbon plays a rule as the matrix while halogen atom plays as substituents. The position, number and name of halogen should be lined out before the name of the hydrocarbon. At room temperature, apart from methyl chloride, methyl bromide, ethyl chloride, vinyl chloride and others which are gas in room temperature, the halo hydrocarbon is liquid in general and the highly  halogenated hydrocarbon is solid.
Halohydrocarbons is not dissolvable in water, but soluble in a variety of organic solvents, and can be dissolved in a variety of weak polarity and non-polar organic compounds. So it  is a kind of commonly used solvent. The relative density of iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. The boiling point of halogenated hydrocarbons increases with the increasing atomic amount of halogen atoms. The boiling point of the same series of halogenated hydrocarbons increases with increase of the amount of carbon chain. The more branched the isomer, the lower the boiling point would it have (except from fluorinated alkanes).
The chemical property of halogenated hydrocarbons is much more active than paraffin, so  halogenated hydrocarbons can produce a variety of chemical reactions, and turn them into various types of compounds. It has an important position in organic synthesis. Halo hydrocarbon has been applied widely in many trades, apart from being used as a solvent, it also could be used as refrigerant, extinguishing agent, anesthetics and preservatives.
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Structure Chemical Name CAS MF
1-Bromobutane 1-Bromobutane 109-65-9 C4H9Br
2,4-Dichlorotoluene 2,4-Dichlorotoluene 95-73-8 C7H6Cl2
4-Bromoethylbenzene 4-Bromoethylbenzene 1585-07-5 C8H9Br
1-BROMOPERFLUOROHEPTANE 1-BROMOPERFLUOROHEPTANE 375-88-2 C7BrF15
2,2'-DIFLUOROBIPHENYL 2,2'-DIFLUOROBIPHENYL 388-82-9 C12H8F2
1-Bromo-2,5-difluorobenzene 1-Bromo-2,5-difluorobenzene 399-94-0 C6H3BrF2
2,3-DICHLOROHEXAFLUORO-2-BUTENE 2,3-DICHLOROHEXAFLUORO-2-BUTENE 303-04-8 C4Cl2F6
3-Bromobiphenyl 3-Bromobiphenyl 2113-57-7 C12H9Br
IODOPENTAFLUOROBENZENE IODOPENTAFLUOROBENZENE 827-15-6 C6F5I
1-Chloro-3-fluorobenzene 1-Chloro-3-fluorobenzene 625-98-9 C6H4ClF
Benzyl chloride Benzyl chloride 100-44-7 C7H7Cl
2-Chloro-6-fluorobenzyl chloride 2-Chloro-6-fluorobenzyl chloride 55117-15-2 C7H5Cl2F
3,5-BIS(TRIFLUOROMETHYL)PHENYLACETYLENE 3,5-BIS(TRIFLUOROMETHYL)PHENYLACETYLENE 88444-81-9 C10H4F6
1-Bromo-2,6-difluorobenzene 1-Bromo-2,6-difluorobenzene 64248-56-2 C6H3BrF2
1,2,4-Trifluorobenzene 1,2,4-Trifluorobenzene 367-23-7 C6H3F3
5-BROMO-2-CHLOROTOLUENE 5-BROMO-2-CHLOROTOLUENE 54932-72-8 C7H6BrCl
2,6-Difluorobenzyl chloride 2,6-Difluorobenzyl chloride 697-73-4 C7H5ClF2
1,3-Dinitro-2-chloro-5-trifluoromethylbenzene 1,3-Dinitro-2-chloro-5-trifluoromethylbenzene 393-75-9 C7H2ClF3N2O4
3,5-Difluorobenzyl bromide 3,5-Difluorobenzyl bromide 141776-91-2 C7H5BrF2
Chloroiodomethane Chloroiodomethane 593-71-5 CH2ClI
CHLORODIBROMOMETHANE CHLORODIBROMOMETHANE 124-48-1 CHBr2Cl
2,4,6-Tris(bromomethyl)mesitylene 2,4,6-Tris(bromomethyl)mesitylene 21988-87-4 C12H15Br3
2,3-Dibromopropene 2,3-Dibromopropene 513-31-5 C3H4Br2
1,4-Dichloro-2-butyne 1,4-Dichloro-2-butyne 821-10-3 C4H4Cl2
1-(2-BROMOETHYL)-4-FLUOROBENZENE 1-(2-BROMOETHYL)-4-FLUOROBENZENE 332-42-3 C8H8BrF
1-Fluoro-3-iodobenzene 1-Fluoro-3-iodobenzene 1121-86-4 C6H4FI
2-FLUORO-3-(TRIFLUOROMETHYL)BENZYL BROMIDE 2-FLUORO-3-(TRIFLUOROMETHYL)BENZYL BROMIDE 184970-25-0 C8H5BrF4
1-ETHYNYL-2-FLUOROBENZENE 1-ETHYNYL-2-FLUOROBENZENE 766-49-4 C8H5F
2,5-BIS(TRIFLUOROMETHYL)BENZYL BROMIDE 2,5-BIS(TRIFLUOROMETHYL)BENZYL BROMIDE 302911-98-4 C9H5BrF6
4-Bromo-1,3-bis(trifluoromethyl)benzene 4-Bromo-1,3-bis(trifluoromethyl)benzene 327-75-3 C8H3BrF6
1-BROMO-2-BUTYNE 1-BROMO-2-BUTYNE 3355-28-0 C4H5Br
TRANS-1,2-DICHLOROCYCLOHEXANE TRANS-1,2-DICHLOROCYCLOHEXANE 822-86-6 C6H10Cl2
1-Bromo-2,3,5-trifluorobenzene 1-Bromo-2,3,5-trifluorobenzene 133739-70-5 C6H2BrF3
4-Iodobiphenyl 4-Iodobiphenyl 1591-31-7 C12H9I
3,4-Difluorobenzyl bromide 3,4-Difluorobenzyl bromide 85118-01-0 C7H5BrF2
1,2-Dichloropropane 1,2-Dichloropropane 78-87-5 C3H6Cl2
2-BROMO-1-CHLOROPROPANE 2-BROMO-1-CHLOROPROPANE 3017-95-6 C3H6BrCl
2,2,3,3-Tetrafluoropropyl iodide 2,2,3,3-Tetrafluoropropyl iodide 679-87-8 C3H3F4I
1-BROMO-2,3,5-TRICHLOROBENZENE 1-BROMO-2,3,5-TRICHLOROBENZENE 81067-38-1 C6H2BrCl3
1-CHLORO-2-ETHYNYLBENZENE 1-CHLORO-2-ETHYNYLBENZENE 873-31-4 C8H5Cl
Cylopropylmethyl chloride Cylopropylmethyl chloride 5911-08-0 C4H7Cl
3,5-Dichloroiodobenzene 3,5-Dichloroiodobenzene 3032-81-3 C6H3Cl2I
3-Iodobenzyl bromide 3-Iodobenzyl bromide 49617-83-6 C7H6BrI
4-BROMO-2-CHLOROTOLUENE 4-BROMO-2-CHLOROTOLUENE 89794-02-5 C7H6BrCl
1-Bromo-4-tert-butylbenzene 1-Bromo-4-tert-butylbenzene 3972-65-4 C10H13Br
4-Bromochlorobenzene 4-Bromochlorobenzene 106-39-8 C6H4BrCl
1,2-Difluoro-4-iodobenzene 1,2-Difluoro-4-iodobenzene 64248-58-4 C6H3F2I
6-Bromo-1-hexene 6-Bromo-1-hexene 2695-47-8 C6H11Br
4-IODO-M-XYLENE 4-IODO-M-XYLENE 4214-28-2 C8H9I
1,4-DICHLORO-2-IODOBENZENE 1,4-DICHLORO-2-IODOBENZENE 29682-41-5 C6H3Cl2I
1-BROMO-4-DIFLUOROMETHYLBENZENE 1-BROMO-4-DIFLUOROMETHYLBENZENE 51776-71-7 C7H5BrF2
Pentafluorobenzene Pentafluorobenzene 363-72-4 C6HF5
2-Chlorofluorobenzene 2-Chlorofluorobenzene 348-51-6 C6H4ClF
4-tert-Butylbenzyl bromide 4-tert-Butylbenzyl bromide 18880-00-7 C11H15Br
2,4,6-TRIBROMOTOLUENE 2,4,6-TRIBROMOTOLUENE 6320-40-7 C7H5Br3
1-BROMO-2-METHYLPROPENE 1-BROMO-2-METHYLPROPENE 3017-69-4 C4H7Br
1,2-Bis(chloromethyl)benzene 1,2-Bis(chloromethyl)benzene 612-12-4 C8H8Cl2
1-Chloronaphthalene 1-Chloronaphthalene 90-13-1 C10H7Cl
8-BROMO-IMIDAZO[1,2-A]PYRIDINE 8-BROMO-IMIDAZO[1,2-A]PYRIDINE 850349-02-9 C7H5BrN2
7-Bromo-1-heptene 7-Bromo-1-heptene 4117-09-3 C7H13Br
1-Bromo-2,3-dichlorobenzene 1-Bromo-2,3-dichlorobenzene 56961-77-4 C6H3BrCl2
1,1,1,2,2,3,3-HEPTACHLOROPROPANE 1,1,1,2,2,3,3-HEPTACHLOROPROPANE 594-89-8 C3HCl7
1-(4-Chlorophenyl)-2-nitroethene 1-(4-Chlorophenyl)-2-nitroethene 706-07-0 C8H6ClNO2
PERFLUOROKEROSENE PERFLUOROKEROSENE
Isobutyl iodide Isobutyl iodide 513-38-2 C4H9I
CIS-1-BROMO-2-ETHOXYETHYLENE CIS-1-BROMO-2-ETHOXYETHYLENE 23521-49-5 C4H7BrO
(1,2-DIBROMOETHYL)BENZENE (1,2-DIBROMOETHYL)BENZENE 93-52-7 C8H8Br2
2,5-DICHLORO-P-XYLENE 2,5-DICHLORO-P-XYLENE 1124-05-6 C8H8Cl2
8-Bromo-1-octene 8-Bromo-1-octene 2695-48-9 C8H15Br
1,1,2,2-Tetrabromoethane 1,1,2,2-Tetrabromoethane 79-27-6 C2H2Br4
1,2-DICHLOROISOBUTANE 1,2-DICHLOROISOBUTANE 594-37-6 C4H8Cl2
2,5-DICHLOROTOLUENE 2,5-DICHLOROTOLUENE 19398-61-9 C7H6Cl2
2-Iodobenzyl bromide 2-Iodobenzyl bromide 40400-13-3 C7H6BrI
3,5-Difluorochlorobenzene 3,5-Difluorochlorobenzene 1435-43-4 C6H3ClF2
1-Chloro-3,4-difluorobenzene 1-Chloro-3,4-difluorobenzene 696-02-6 C6H3ClF2
3,4-DICHLORO-OMEGA-NITROSTYRENE 3,4-DICHLORO-OMEGA-NITROSTYRENE 18984-16-2 C8H5Cl2NO2
1-Chloro-N,N,2-trimethylpropenylamine 1-Chloro-N,N,2-trimethylpropenylamine 26189-59-3 C6H12ClN
5-Chloro-1-pentyne 5-Chloro-1-pentyne 14267-92-6 C5H7Cl
2,5-Dibromotoluene 2,5-Dibromotoluene 615-59-8 C7H6Br2
2,4-Dibromo-1-fluorobenzene 2,4-Dibromo-1-fluorobenzene 1435-53-6 C6H3Br2F
1-(2-Chlorophenyl)-2-nitroethylene 1-(2-Chlorophenyl)-2-nitroethylene 3156-34-1 C8H6ClNO2
Hexachloroethane Hexachloroethane 67-72-1 C2Cl6
4,4'-Bis(chloromethyl)-1,1'-biphenyl 4,4'-Bis(chloromethyl)-1,1'-biphenyl 1667-10-3 C14H12Cl2
3-Chloro-4-nitrotoluene 3-Chloro-4-nitrotoluene 38939-88-7 C7H6ClNO2
2,2'-DIBROMOBIPHENYL 2,2'-DIBROMOBIPHENYL 13029-09-9 C12H8Br2
1-FLUOROPENTANE 1-FLUOROPENTANE 592-50-7 C5H11F
1,5-Dichloropentane 1,5-Dichloropentane 628-76-2 C5H10Cl2
1-Chloromethyl naphthalene 1-Chloromethyl naphthalene 86-52-2 C11H9Cl
1,4-DIBROMO-2-FLUOROBENZENE 1,4-DIBROMO-2-FLUOROBENZENE 1435-52-5 C6H3Br2F
3-CHLORO-O-XYLENE 3-CHLORO-O-XYLENE 608-23-1 C8H9Cl
2-Bromoheptane 2-Bromoheptane 1974-04-5 C7H15Br
Heptafluoroisopropyl iodide Heptafluoroisopropyl iodide 677-69-0 C3F7I
1,2,4,5-Tetrafluorobenzene 1,2,4,5-Tetrafluorobenzene 327-54-8 C6H2F4
1-Bromononane 1-Bromononane 693-58-3 C9H19Br
2,7-Dibromonaphthalene 2,7-Dibromonaphthalene 58556-75-5 C10H6Br2
3-Bromobenzyl chloride 3-Bromobenzyl chloride 932-77-4 C7H6BrCl
Carbon tetrachloride Carbon tetrachloride 56-23-5 CCl4
1-Bromo-2-ethylbutane 1-Bromo-2-ethylbutane 3814-34-4 C6H13Br
3-Chlorophenylacetylene 3-Chlorophenylacetylene 766-83-6 C8H5Cl
Benzotrichloride Benzotrichloride 98-07-7 C7H5Cl3
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