Hydrocarbon halides

Hydrocarbon halide, or hydrocarbon for short, refers to the product produced during the process of hydrogen atoms replaced by by halogen (fluorine, chlorine, bromine, iodine) in the hydrocarbon molecules. According to the different hydrocarbon groups, it could be divided into categories like aliphatic halogenated hydrocarbons (including saturated and unsaturated halogenated hydrocarbons), aromatic halogenated hydrocarbons. According to the amount of halogen atoms contained in the molecule, it could be divided into categories like halogenated hydrocarbons, dihalogenated hydrocarbons and polyhalogenated hydrocarbons. Most of the halogenated hydrocarbons are liquid. The proportion of Iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. They are insoluble in water and could be dissolved in any proportion with hydrocarbons, they also could dissolve many other organics. The proportion of Hydrocarbon halide would decreases with the increase of the amount of carbon atoms. When there are the same hydrocarbon groups, the boiling point and the proportion of the halogenated hydrocarbons would increase in the order of chlorinated hydrocarbons, brominated hydrocarbons, and iodinated hydrocarbons. In the isomer, the more branches it gets, the lower boiling point it has. Most of these substances are toxic and can burn. And their combustion properties decrease with the increase of the amount of halogen atoms in the compound. When it comes to storage, fire hazard should be managed in A, B, C three categories according to fire risk indicators. When it catch fire, the gas should be treated by the C class of fire treatment, liquid by B class of fire treatment. Eenough attention should be payed to anti-virus.
The amount of naturally occurring halo hydrocarbons is very small, and the majority of halo hydrocarbons are synthesized by halogenation of alkanes, and compounded by unsaturated hydrocarbons. It also could be compounded during the reaction between alcohol with hydrohalic acid.
The amount of Halohydrocarbons are more isomers than corresponding hydrocarbons. Apart from the carbon isomerism, unsaturated bond position isomerization, cis-trans isomerism and optical isomerism, there are halogen atom isomerizations as well.. when the Halogenated hydrocarbon was named, the hydrocarbon plays a rule as the matrix while halogen atom plays as substituents. The position, number and name of halogen should be lined out before the name of the hydrocarbon. At room temperature, apart from methyl chloride, methyl bromide, ethyl chloride, vinyl chloride and others which are gas in room temperature, the halo hydrocarbon is liquid in general and the highly  halogenated hydrocarbon is solid.
Halohydrocarbons is not dissolvable in water, but soluble in a variety of organic solvents, and can be dissolved in a variety of weak polarity and non-polar organic compounds. So it  is a kind of commonly used solvent. The relative density of iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. The boiling point of halogenated hydrocarbons increases with the increasing atomic amount of halogen atoms. The boiling point of the same series of halogenated hydrocarbons increases with increase of the amount of carbon chain. The more branched the isomer, the lower the boiling point would it have (except from fluorinated alkanes).
The chemical property of halogenated hydrocarbons is much more active than paraffin, so  halogenated hydrocarbons can produce a variety of chemical reactions, and turn them into various types of compounds. It has an important position in organic synthesis. Halo hydrocarbon has been applied widely in many trades, apart from being used as a solvent, it also could be used as refrigerant, extinguishing agent, anesthetics and preservatives.
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Structure Chemical Name CAS MF
4-Bromo-4'-fluorobiphenyl 4-Bromo-4'-fluorobiphenyl 398-21-0 C12H8BrF
EXO-2-CHLORONORBORNANE EXO-2-CHLORONORBORNANE 765-91-3 C7H11Cl
1-IODO-2,4,5-TRICHLOROBENZENE 1-IODO-2,4,5-TRICHLOROBENZENE 7145-82-6 C6H2Cl3I
4,4'-DIBROMOOCTAFLUOROBIPHENYL 4,4'-DIBROMOOCTAFLUOROBIPHENYL 10386-84-2 C12Br2F8
(3-CHLOROPHENYLETHYNYL)TRIMETHYLSILAN& (3-CHLOROPHENYLETHYNYL)TRIMETHYLSILAN& 227936-62-1 C11H13ClSi
2-BROMOTETRADECANE 2-BROMOTETRADECANE 74036-95-6 C14H29Br
Hexadecafluoroheptane Hexadecafluoroheptane 335-57-9 C7F16
ALLYL(CHLOROMETHYL)DIMETHYLSILANE ALLYL(CHLOROMETHYL)DIMETHYLSILANE 33558-75-7 C6H13ClSi
1,1-DICHLORO-3,3-DIMETHYLBUTANE 1,1-DICHLORO-3,3-DIMETHYLBUTANE 6130-96-7 C6H12Cl2
2,3,5,6-TETRAFLUORO-4-(TRIFLUOROMETHYL)BENZYL BROMIDE 2,3,5,6-TETRAFLUORO-4-(TRIFLUOROMETHYL)BENZYL BROMIDE 76437-40-6 C8H2BrF7
(Z)-2-BROMO-2-BUTENE (Z)-2-BROMO-2-BUTENE 3017-68-3 C4H7Br
2,7-DIIODOFLUORENE 2,7-DIIODOFLUORENE 16218-28-3 C13H8I2
2-(CHLOROMETHYL)NAPHTHALENE 2-(CHLOROMETHYL)NAPHTHALENE 2506-41-4 C11H9Cl
2,5-DIBROMOBENZOTRIFLUORIDE 2,5-DIBROMOBENZOTRIFLUORIDE 7657-09-2 C7H3Br2F3
Octachloronaphthalene Octachloronaphthalene 2234-13-1 C10Cl8
3,3',5,5'-TETRABROMOBIPHENYL 3,3',5,5'-TETRABROMOBIPHENYL 16400-50-3 C12H6Br4
1-CHLORO-2,2-DIMETHYLPROPANE 1-CHLORO-2,2-DIMETHYLPROPANE 753-89-9 C5H11Cl
Trichlorofluoromethane Trichlorofluoromethane 75-69-4 CCl3F
4H,4'H-OCTAFLUOROBIPHENYL 4H,4'H-OCTAFLUOROBIPHENYL 3883-86-1 C12H2F8
CIS-3,4-DICHLOROCYCLOBUTENE CIS-3,4-DICHLOROCYCLOBUTENE 2957-95-1 C4H4Cl2
CIS-1-BROMO-1-PROPENE CIS-1-BROMO-1-PROPENE 590-13-6 C3H5Br
1,1-DICHLOROPROPANE 1,1-DICHLOROPROPANE 78-99-9 C3H6Cl2
2,3,5,6-TETRAFLUORO-P-XYLENE 2,3,5,6-TETRAFLUORO-P-XYLENE 703-87-7 C8H6F4
TRANS-1,4-DIBROMO-2-BUTENE TRANS-1,4-DIBROMO-2-BUTENE 6974-12-5 C4H6Br2
1,1,2,2-TETRABROMOETHANE 1,1,2,2-TETRABROMOETHANE 25167-20-8 C2H2Br4
1-(2-BROMOETHYL)NAPHTHALENE 1-(2-BROMOETHYL)NAPHTHALENE 13686-49-2 C12H11Br
2,2'-BIS(BROMOMETHYL)-1,1'-BIPHENYL 2,2'-BIS(BROMOMETHYL)-1,1'-BIPHENYL 38274-14-5 C14H12Br2
1,2-DIBROMO-1,1,2-TRICHLOROETHANE 1,2-DIBROMO-1,1,2-TRICHLOROETHANE 13749-38-7 C2HBr2Cl3
1,1,1,2,2,3,3-HEPTAFLUORO-5-IODOPENTANE 1,1,1,2,2,3,3-HEPTAFLUORO-5-IODOPENTANE 1513-88-8 C5H4F7I
11-CHLORO-1-UNDECENE 11-CHLORO-1-UNDECENE 872-17-3 C11H21Cl
3,4-DIBROMOHEXANE 3,4-DIBROMOHEXANE 16230-28-7 C6H12Br2
TRANS-3-BROMO-BETA-NITROSTYRENE  97 TRANS-3-BROMO-BETA-NITROSTYRENE 97 115665-95-7 C8H6BrNO2
1-BROMO-3,5-DIFLUOROBENZENE 1-BROMO-3,5-DIFLUOROBENZENE 461-91-6 C4As2F12O
1-BROMOHEPTADECANE 1-BROMOHEPTADECANE 3508-00-7 C17H35Br
6-CHLORO-1-HEXYNE 6-CHLORO-1-HEXYNE 10297-06-0 C6H9Cl
1-CHLORO-5-IODOPENTANE 1-CHLORO-5-IODOPENTANE 60274-60-4 C5H10ClI
2-PHENYLBENZYL BROMIDE 2-PHENYLBENZYL BROMIDE 19853-09-9 C13H11Br
Dichlorodifluoromethane Dichlorodifluoromethane 75-71-8 CCl2F2
1,2-DICHLOROTETRAFLUOROETHANE 1,2-DICHLOROTETRAFLUOROETHANE 76-14-2 C2Cl2F4
PERFLUORODIMETHYLCYCLOBUTANE PERFLUORODIMETHYLCYCLOBUTANE 2994-71-0 C6F12
3-CHLORO-3-METHYLPENTANE 3-CHLORO-3-METHYLPENTANE 918-84-3 C6H13Cl
1-BROMO-2-PENTENE  95%  PREDOMINANTLY 1-BROMO-2-PENTENE 95% PREDOMINANTLY 7348-71-2 C5H9Br
PERFLUOROPENTADECANE PERFLUOROPENTADECANE 2264-03-1 C15F32
1-CHLORO-6-IODOHEXANE 1-CHLORO-6-IODOHEXANE 34683-73-3 C6H12ClI
1-Iodoadamantane 1-Iodoadamantane 768-93-4 C10H15I
2-Bromo-1,3-diisopropylbenzene 2-Bromo-1,3-diisopropylbenzene 57190-17-7 C12H17Br
1-Fluoro-2-(2-nitrovinyl)benzene 1-Fluoro-2-(2-nitrovinyl)benzene 399-25-7 C8H6FNO2
(4-FLUOROPHENYLETHYNYL)TRIMETHYLSILANE (4-FLUOROPHENYLETHYNYL)TRIMETHYLSILANE 130995-12-9 C11H13FSi
2-ETHYLHEXYL IODIDE 2-ETHYLHEXYL IODIDE 1653-16-3 C8H17I
TRANS-2-BROMO-BETA-NITROSTYRENE  95 TRANS-2-BROMO-BETA-NITROSTYRENE 95 155988-33-3 C8H6BrNO2
2 7-DIIODO-9 9-DIOCTYL-9H-FLUORENE  97 2 7-DIIODO-9 9-DIOCTYL-9H-FLUORENE 97 278176-06-0 C29H40I2
2-BROMO-3-METHYL-2-BUTENE 2-BROMO-3-METHYL-2-BUTENE 3017-70-7 C5H9Br
1H,1H,5H-OCTAFLUOROPENTYL IODIDE 1H,1H,5H-OCTAFLUOROPENTYL IODIDE 678-74-0 C5H3F8I
1-Fluorooctane 1-Fluorooctane 463-11-6 C8H17F
(3,5-BIS(TRIFLUOROMETHYL)PHENYLETHYNYL)& (3,5-BIS(TRIFLUOROMETHYL)PHENYLETHYNYL)& 618092-28-7 C13H12F6Si
1,1-DIIODO-2,2-DIMETHYLPROPANE 1,1-DIIODO-2,2-DIMETHYLPROPANE 2443-89-2 C5H10I2
2,3-DIBROMOHEXANE 2,3-DIBROMOHEXANE 6423-02-5 C6H12Br2
1-BROMO-2-PENTYNE 1-BROMO-2-PENTYNE 16400-32-1 C5H7Br
Hexafluoropropene trimer Hexafluoropropene trimer 6792-31-0 C3F6
Chlorotrifluoroethylene Chlorotrifluoroethylene 79-38-9 C2ClF3
1,1,1-TRIS(CHLOROMETHYL)ETHANE 1,1,1-TRIS(CHLOROMETHYL)ETHANE 1067-09-0 C5H9Cl3
1-CHLORO-4-(1,2-DIBROMOETHYL)BENZENE 1-CHLORO-4-(1,2-DIBROMOETHYL)BENZENE 23135-16-2 C8H7Br2Cl
Perfluorododecyl iodide Perfluorododecyl iodide 307-60-8 C12F25I
2,7-BIS(BROMOMETHYL)NAPHTHALENE 2,7-BIS(BROMOMETHYL)NAPHTHALENE 38309-89-6 C12H10Br2
(+/-)-2 3-DIBROMOBUTANE  98 (+/-)-2 3-DIBROMOBUTANE 98 598-71-0 C4H8Br2
(2 4-DIFLUOROPHENYLETHYNYL)TRIMETHYLSIL& (2 4-DIFLUOROPHENYLETHYNYL)TRIMETHYLSIL& 480438-92-4 C11H12F2Si
2 6-BIS(BROMOMETHYL)NAPHTHALENE  97 2 6-BIS(BROMOMETHYL)NAPHTHALENE 97 4542-77-2 C12H10Br2
1 4-DICYCLOHEXYL-2 5-DIIODOBENZENE  95 1 4-DICYCLOHEXYL-2 5-DIIODOBENZENE 95 236407-24-2 C18H24I2
1 4-DIIODO-2 5-DIOCTYLBENZENE 1 4-DIIODO-2 5-DIOCTYLBENZENE 171569-01-0 C22H36I2
1-(2-bromoethyl)-2-(trifluoromethyl)benzene 1-(2-bromoethyl)-2-(trifluoromethyl)benzene 94022-95-4 C9H8BrF3
2,3-DIBROMOPENTANE 2,3-DIBROMOPENTANE 5780-13-2 C4H8Br2
1,2-DIBROMOHEXANE 1,2-DIBROMOHEXANE 624-20-4 C6H12Br2
1,4-DIIODOTETRAFLUOROBENZENE 1,4-DIIODOTETRAFLUOROBENZENE 392-57-4 C6F4I2
(4-CHLOROPHENYLETHYNYL)TRIMETHYLSILANE (4-CHLOROPHENYLETHYNYL)TRIMETHYLSILANE 78704-49-1 C11H13ClSi
(3 5-DIFLUOROPHENYLETHYNYL)TRIMETHYLSIL& (3 5-DIFLUOROPHENYLETHYNYL)TRIMETHYLSIL& 445491-09-8 C11H12F2Si
1,5-DIBROMO-1,1,3,3,5,5-HEXAFLUOROPENTANE 1,5-DIBROMO-1,1,3,3,5,5-HEXAFLUOROPENTANE 371-83-5 C5H4Br2F6
1,3,5-TRIS(BROMOMETHYL)-2,4,6-TRIETHYLBENZENE 1,3,5-TRIS(BROMOMETHYL)-2,4,6-TRIETHYLBENZENE 181058-08-2 C15H21Br3
2-CHLORO-2-PROPEN-1-OL 2-CHLORO-2-PROPEN-1-OL 5976-47-6 C3H5ClO
9-CHLOROANTHRACENE 9-CHLOROANTHRACENE 716-53-0 C14H9Cl
4-CHLOROMETHYLSTILBENE  95 4-CHLOROMETHYLSTILBENE 95 150253-59-1 C15H13Cl
Bromoiodomethane Bromoiodomethane 557-68-6 CH2BrI
1-CHLORO-4-(PHENYLETHYNYL)BENZENE  98 1-CHLORO-4-(PHENYLETHYNYL)BENZENE 98 5172-02-1 C14H9Cl
1-Chloro-1,1-difluoroethane 1-Chloro-1,1-difluoroethane 75-68-3 C2H3ClF2
1-(1-bromoethyl)-4-fluorobenzene 1-(1-bromoethyl)-4-fluorobenzene 65130-46-3 C8H8BrF
1-FLUORODECANE 1-FLUORODECANE 334-56-5 C10H21F
2-CYCLOHEXYL-ETHYLAMINE HYDROCHLORIDE 2-CYCLOHEXYL-ETHYLAMINE HYDROCHLORIDE 5471-55-6 C8H18ClN
4-BROMO-5-FLUORO-2-IODOTOLUENE 4-BROMO-5-FLUORO-2-IODOTOLUENE 870704-15-7 C7H5BrFI
1,2-DIIODOTETRAFLUOROBENZENE 1,2-DIIODOTETRAFLUOROBENZENE 2708-97-6 C6F4I2
2-IODONAPHTHALENE 2-IODONAPHTHALENE 612-55-5 C10H7I
O-XYLYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE) O-XYLYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE) 1519-46-6 C44H38BrP2+
3-broMo-2-(broMoMethy)prop-1-ene 3-broMo-2-(broMoMethy)prop-1-ene 15378-31-1 C4H6Br2
1,2-DICHLOROETHANE-D4 1,2-DICHLOROETHANE-D4 17060-07-0 C2H4Cl2
HEPTAFLUOROBENZYL IODIDE HEPTAFLUOROBENZYL IODIDE 79865-03-5 C7F7I
BROMOTRIFLUOROMETHANE BROMOTRIFLUOROMETHANE 75-63-8 CBrF3
BROMOCHLORODIFLUOROMETHANE BROMOCHLORODIFLUOROMETHANE 353-59-3 CBrClF2
(3-BROMOPHENYLETHYNYL)TRIMETHYLSILANE (3-BROMOPHENYLETHYNYL)TRIMETHYLSILANE 3989-13-7 C11H13BrSi
ALLYL 2-BROMOBENZYL ETHER  95 ALLYL 2-BROMOBENZYL ETHER 95 87280-01-1 C10H11BrO
1 4-DIDODECYL-2 5-DIIODOBENZENE 1 4-DIDODECYL-2 5-DIIODOBENZENE 162715-93-7 C30H52I2
7-BROMOBICYCLO[2.2.1]HEPTANE 7-BROMOBICYCLO[2.2.1]HEPTANE 13237-88-2 C7H11Br
TRANS-3-CHLORO-4,5-DIMETHOXY-BETA-NITRO& TRANS-3-CHLORO-4,5-DIMETHOXY-BETA-NITRO& 871126-37-3 C10H10ClNO4
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