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Mesosulfuron-methyl

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CAS:208465-21-8
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Mesosulfuron-methyl Basic information
Product Name:Mesosulfuron-methyl
Synonyms:Benzoic acid, 2-(((((4,6-dimethoxy-2-pyrimidinyl)amino)carbonyl)amino)sulfonyl)-4-(((methylsulfonyl)amino)methyl)-, methyl ester;Benzoic acid, 2-(4,6-dimethoxy-2-pyrimidinyl)aminocarbonylaminosulfonyl-4-(methylsulfonyl)amin;Mesosulfuron-methyl [iso];Methyl 2-(N-((4,6-diMethoxypyriMidin-2-yl)carbaMoyl)sulfaMoyl)-4-(MethylsulfonaMidoMethyl)benzoate;Methyl 2-(N-((4,6-dimethoxypyrimidin-2-yl)carbamoyl)-sulfamoyl)-4-(methylsulfonamidomethyl)ben;AEF130060;AEF154851;AEF6012-33H
CAS:208465-21-8
MF:C17H21N5O9S2
MW:503.51
EINECS:
Product Categories:Alphabetic;M;MEA - MES
Mol File:208465-21-8.mol
Mesosulfuron-methyl Structure
Mesosulfuron-methyl Chemical Properties
Melting point 195.4°
density 1.498±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,2-8°C
solubility Solubility in organic solvents (g/l at 20 °C) Acetone 13.66 Ethyl acetate 2.0 Dichloromethane 3.8 n‐Hexane <0.0002 Toluene 0.013.
form Powder
PkaDissociation constant (pKa at 20 °C):4.35.
color White to off-white
Water Solubility Solubility in water (g/l at 20 °C) 0.007 (pH 5) 0.483 (pH 7) 15.39 (pH 9).
InChIInChI=1S/C17H21N5O9S2/c1-29-13-8-14(30-2)20-16(19-13)21-17(24)22-33(27,28)12-7-10(9-18-32(4,25)26)5-6-11(12)15(23)31-3/h5-8,18H,9H2,1-4H3,(H2,19,20,21,22,24)
InChIKeyNIFKBBMCXCMCAO-UHFFFAOYSA-N
SMILESC(OC)(=O)C1=CC=C(CNS(C)(=O)=O)C=C1S(NC(NC1=NC(OC)=CC(OC)=N1)=O)(=O)=O
EPA Substance Registry SystemMesosulfuron-methyl (208465-21-8)
Safety Information
Hazard Codes N
Risk Statements 50
Safety Statements 60-61
RIDADR UN 3077
WGK Germany 2
Hazardous Substances Data208465-21-8(Hazardous Substances Data)
ToxicityLD50 in rats (mg/kg): >5000 orally; >5000 dermally; LC50 in rats: >1.33 mg/l air (Hacker)
MSDS Information
Mesosulfuron-methyl Usage And Synthesis
UsesHerbicide.
Agricultural UsesMesosulfuron methyl (AE F130060) was the second safened sulfonylurea herbicide for cereal crops to be commercialized, having been introduced by Bayer CropScience in 2001. Its strength is broad spectrum post emergence grass weed control. Mesosulfuron methyl, at a dose rate of 4.5– 15 g a.i. ha−1, reliably controls 24 different grass weed species from 12 different families. Among the commercially important grass weed species, it provides good control of Agrostis spp., A. myosuroides, A. spica‐venti, Avena spp., Lolium spp., P. brachystachys, P. minor, P. paradoxa, P. annua, P. trivialis, Pucciniella spp., and Sclerochloa kengiana. Additionally, mesosulfuron‐methyl controls, or has a strong suppressive effect on, some very persistent grass weed species, such as Bromus catharticus, B. diandrus, B. erectus, B. japonicus, B. mollis, B. tectorum, B. secalinus, B. sterilis, and Vulpia spp. The compound is applied on soft and durum wheat, triticale, and rye, together with mefenpyr‐diethyl as safener as the straight products “Atlantis OF,” “Silverado®,” and “Osprey®” or in combination with iodosulfuron methylsodium (“Atlantis WG,” “Cossack,” “Pacifica®”), diflufenican, and propoxycarbazone sodium.
“Atlantis WG” is positioned in market segments where grass weeds are the main target, whereas “Cossack” is a cross spectrum product that is active against both grasses and a large number of important broadleaf weeds. Mesosulfuronmethyl belongs to the group of modern OnePass® products. It acts predominantly via the leaves of treated weeds; however, highly susceptible grasses, such as Apera and Alopecurus, can also be successfully controlled by uptake of mesosulfuron methyl via the soil and the roots.
The safener mefenpyr diethyl, as with iodosulfuron methyl sodium, selectively accelerates the degradation of the active ingredient to nonphytotoxic compounds in cereals, but not in weeds.
Mesosulfuron-methyl Preparation Products And Raw materials
Raw materialsBenzoic acid, 2-[[(1,1-dimethylethyl)amino]sulfonyl]-4-methyl-, methyl ester
Tag:Mesosulfuron-methyl(208465-21-8) Related Product Information
METSULFURON METHYL Methylparaben Sulfanilamide Sulfamethoxazole Methyl methoxyacetate Methyl acetate Methyl 2-(chlorosulfonyl)benzoate Kresoxim-methyl Iodosulfuron-methyl Methyl benzoate Sulfometuron-methyl Methyl 2-iodobenzoate 4-Methoxybenzoic acid Bensulfuron methyl 2-Carbomethoxybenzenesulfonamide Methyl acrylate Thiophanate-methyl Methyl

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