ChemicalBook CAS DataBase List methyl cyclooctanecarboxylate

methyl cyclooctanecarboxylate synthesis

10synthesis methods

Product Name:methyl cyclooctanecarboxylate
CAS Number:3724-54-7
Molecular formula:C10H18O2
Molecular Weight:170.25

67-56-1 Synthesis

67-56-1
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201230-82-2 Synthesis

201230-82-2
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3958-30-3
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3724-54-7
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Yield:3724-54-7 89%

Reaction Conditions:

with palladium(II) acetylacetonate;1,2-bis((tert-butyl(pyridin-2-yl)phosphanyl)methyl)benzene;toluene-4-sulfonic acid at 120; under 30003 Torr; for 20 h;Catalytic behavior;Schlenk technique;Inert atmosphere;Autoclave;Reagent/catalyst;

Steps:

General procedure: Reaction conditions for ligand 1:In a 25 ml Schlenk container under argon[Pd (acac) 2] (12.2 mg, 0.04 mol),1 (69.8 mg, 0.16 mmol),PTSA (114 mg, 0.6 mmol) and MeOH (25 ml).In a 4 ml glass vial equipped with a magnetic stirrer, 2 mmol of olefin was charged.Add 1.25 ml of the previously prepared mother liquor to the syringe.The vial was placed on a metal plate in a 300 ml Parr autoclave under argon.The autoclave was purged with CO three times and then pressed into 40 bar of CO.Then under magnetic stirring and the reaction carried out at 120 deg.] C 20 h.Then cool and slowly release the pressure.Add 0.2 ml of isooctane as an internal standard.The conversion and yield were determined by GC and GC-MS analysis.

References:

CN106366126,2017,A Location in patent:Paragraph 0180; 0181; 0184

67-56-1 Synthesis

67-56-1
790 suppliers
$9.00/25ml

64-18-6 Synthesis