ChemicalBook CAS DataBase List Triethyl orthobenzoate

Triethyl orthobenzoate synthesis

11synthesis methods

Product Name:Triethyl orthobenzoate
CAS Number:1663-61-2
Molecular formula:C13H20O3
Molecular Weight:224.3

60-29-7
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$31.19/50g

93-89-0 Synthesis

93-89-0
503 suppliers
$13.00/100g

1663-61-2
185 suppliers
$10.00/5g

Yield:1663-61-2 95%

Reaction Conditions:

with boron trifluoride in Hexadecane at 110; for 6 h;Autoclave;Temperature;Reagent/catalyst;Time;

Steps:

1; 5; 41-60 Example 1. Preparation of triethyl orthobenzoate

In a 50ml stainless steel autoclave with a magnetic stir bar, add 1.50g (10mmol) ethyl benzoate,In 0.1g n-hexadecane (internal standard) and 7.40g (100mmol) ether solution containing 0.068g (1mmol) boron trifluoride, heat up to 110 and react for 6.0 hours. After the reaction is over, cool down to 0-5 .The sample was analyzed by gas phase, and the conversion rate of ethyl benzoate was 98%, and the yield of triethyl orthobenzoate was 95%.

References:

CN111470954,2020,A Location in patent:Paragraph 0021-0023

141-52-6 Synthesis