ChemicalBook--->CAS DataBase List--->118-58-1

118-58-1

118-58-1 Structure

118-58-1 Structure
IdentificationMore
[Name]

Benzyl salicylate
[CAS]

118-58-1
[Synonyms]

2-HYDROXYBENZOIC ACID BENZYL ESTER
2-hydroxybenzoic acid phenylmethyl ester
BENZYL 2-HYDROXYBENZOATE
BENZYL O-HYDROXYBENZOATE
BENZYL ORTHO HYDROXY BENZOATE
BENZYL SALICYLATE
FEMA 2151
SALICYLIC ACID BENZYL ESTER
2-hydroxy-benzoicaciphenylmethylester
Benzoicacid,2-hydroxy-,phenylmethylester
benzyle salicylate
benzylhydroxybenzoate
Salicyclic acid benzyl ester
SALICILATO DE BENCILO
BENZYL SALICYLATE 98+% FCC
SALICYLIC ACID BENZYL ESTER, SECONDARY STANDARD
Benzyl salicylate, 98+%
Benzylsalicylat
Benzoic acid, 2-hydroxy-, phenylme
2-Hydroxybenzone acid benzoate
[EINECS(EC#)]

204-262-9
[Molecular Formula]

C14H12O3
[MDL Number]

MFCD00020034
[Molecular Weight]

228.24
[MOL File]

118-58-1.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR SLIGHTLY PINKISH LIQUID
[Melting point ]

18-20 °C
[Boiling point ]

168-170 °C5 mm Hg(lit.)
[density ]

1.176 g/mL at 25 °C(lit.)
[vapor pressure ]

0.01Pa at 25℃
[FEMA ]

2151
[refractive index ]

n20/D 1.581(lit.)
[Fp ]

>230 °F
[storage temp. ]

-20°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

neat
[pka]

8.11±0.30(Predicted)
[color ]

Thick colorless liquid
[Odor]

pleasant odor
[biological source]

synthetic
[Odor Type]

balsamic
[Water Solubility ]

Slightly soluble
[JECFA Number]

904
[Merck ]

14,1144
[BRN ]

2115365
[Dielectric constant]

4.1(20℃)
[Major Application]

flavors and fragrances
[Cosmetics Ingredients Functions]

PERFUMING
LIGHT STABILIZER
[Cosmetic Ingredient Review (CIR)]

Benzyl salicylate (118-58-1)
[InChI]

1S/C14H12O3/c15-13-9-5-4-8-12(13)14(16)17-10-11-6-2-1-3-7-11/h1-9,15H,10H2
[Contact allergens]

Benzyl salicylate is used as fixer in perfumery and sunscreen preparations. As a (weak) perfume sensitizer, it has to be listed by name in cosmetic preparations in the EU.
[InChIKey]

ZCTQGTTXIYCGGC-UHFFFAOYSA-N
[SMILES]

Oc1ccccc1C(=O)OCc2ccccc2
[LogP]

4
[Uses]

benzyl salicylate is a fragrance found naturally occurring in carnations and in certain members of the primrose family. Although it can be derived for cosmetic use from natural essential oils, such as jasmine oil, neroli, and ylang-ylang, it can also be synthetically manufactured.
[CAS DataBase Reference]

118-58-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzoic acid, 2-hydroxy-, phenylmethyl ester(118-58-1)
[EPA Substance Registry System]

118-58-1(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

CLEAR SLIGHTLY PINKISH LIQUID
[Uses]

Benzyl Salicylate is an chemical compound commonly used in the cosmetic industry. Benzyl Salicylate is also found in essential oils from green tea and was shown to exhibit antioxidant and antimicrobia l activity.
[Uses]

As fixer in perfumery; in sunscreen preparations.
[General Description]

Colorless liquid. Melting point near room temperature (18-20°C).
[Reactivity Profile]

BENZYL SALICYLATE(118-58-1) may hydrolyze in aqueous acid or basic solutions. BENZYL SALICYLATE(118-58-1) can react with oxidizing materials.
[Air & Water Reactions]

Slightly water soluble .
[Fire Hazard]

Flash point data for this chemical are not available, but BENZYL SALICYLATE is probably combustible.
[Description]

Benzyl salicylate is a salicylic acid benzyl ester, a chemical compound most frequently used in cosmetics. It appears as an almost colorless liquid with a mild odor described as "very faint, sweetfloral, slightly balsamic" by those who can smell it, but many people either can't smell it at all or describe its smell as "musky". Trace impurities can have a significant influence on the odour.[1] It occurs naturally in a variety of plants and plant extracts and is widely used in blends of fragrance materials.
There is some evidence that people can become sensitized to this material and as a result there is a restriction standard concerning the use of this material in fragrances by the International Fragrance Association.
It is used as a solvent for crystalline synthetic musks and as a component and fixative in floral perfumes such as carnation, jasmine, lilac, and wallflower.
[Occurrence]

It has been reported in small amounts in carnation oil (Dianthus caryophyllus L.) and in larger amounts in the oil of Primula auricula. Also found in American cranberry, clove bud, peppermint oil and buckwheat.
[Definition]

ChEBI: Benzyl salicylate is a benzoate ester and a member of phenols. It is functionally related to a salicylic acid.
[Preparation]

By esterification of salicylic acid with benzyl alcohol.
[Flammability and Explosibility]

Nonflammable
[Safety Profile]

Moderately toxic by ingestion. Seealso BENZYL ALCOHOL, SALICYLIC ACID, andESTERS. Combustible when exposed to heat or flame.When heated to decomposition it emits acrid smoke andirritating fumes. Incompatible with oxidizing materials.
[Safety]

Benzyl salicylate poses dangers to sensitive skin.  Even in very small amounts, it may cause allergic reactions when applied to the skin. Benzyl salicylate can cause contact dermatitis (skin irritation) to people with sensitive skin types. It is also on the European Commission's list of 26 known allergens. Some of the other ingredients on the fragrance allergen list include linalool, coumarin, geraniol, and limonene.
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H317-H319-H412
[Precautionary statements ]

P261-P264-P273-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

2
[RTECS ]

VO1750000
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29182900
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Aquatic Chronic 3
Eye Irrit. 2
Skin Sens. 1B
[Hazardous Substances Data]

118-58-1(Hazardous Substances Data)
[Toxicity]

LD50 orl-rat: 2227 mg/kg FCTXAV 11,1029,73
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Benzyl chloride-->Diethylamine-->Phenethyl alcohol-->Salicylic acid-->Sodium salicylate-->2-Propanamine, N-ethyl-N-(1-methylethyl)-, hydrochloride (1:1)-->HYIPKILWQXALOW-UHFFFAOYSA-N-->2,4,6-tris(phenylmethoxy)-1,3,5-triazine-->ethyl salicylate-->Isoamyl o-hydroxybenzoate-->Methyl salicylate
[Preparation Products]

Methyl 1-((2-Benzyloxycarbonxyl)phenyl)-2,3,4-tri-O-acetyl--D-glucopyranuronate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Salicylic acid benzyl ester(118-58-1).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Benzyl salicylate(118-58-1)MS
Benzyl salicylate(118-58-1)1HNMR
Benzyl salicylate(118-58-1)13CNMR
Benzyl salicylate(118-58-1)IR1
Benzyl salicylate(118-58-1)IR2
Benzyl salicylate(118-58-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Benzyl salicylate, 98+%(118-58-1)
[Alfa Aesar]

Benzyl salicylate, 99%(118-58-1)
[Sigma Aldrich]

118-58-1(sigmaaldrich)
[TCI AMERICA]

Benzyl Salicylate,>99.0%(GC)(118-58-1)
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