| Identification | More | [Name]
BIS(4-NITROPHENYL) CARBONATE | [CAS]
5070-13-3 | [Synonyms]
4-NITROPHENYL CARBONATE
BIS(4-NITROPHENYL) CARBONATE
BIS(P-NITROPHENYL) CARBONATE
CARBONIC ACID BIS(4-NITROPHENYL) ESTER
BIS(4-NITROPHENYL) CARBONATE, 99+%
4-4'-DINITRODIPHENYL CARBONATE
Bis(4-nitrophenyl) carbonate ,97%
p,p'-Dinitrodiphenylcarbonate
NPC [Bis(4-nitrophenyl)carbonate] | [EINECS(EC#)]
225-775-4 | [Molecular Formula]
C13H8N2O7 | [MDL Number]
MFCD00007322 | [Molecular Weight]
304.21 | [MOL File]
5070-13-3.mol |
| Chemical Properties | Back Directory | [Appearance]
white to pale yellow or beige powder | [Melting point ]
136-139 °C(lit.)
| [Boiling point ]
475.9±30.0 °C(Predicted) | [density ]
1.501±0.06 g/cm3(Predicted) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Soluble in chloroform and tetrahydrofuran. | [form ]
Liquid | [color ]
Clear slightly yellow or greenish to brown | [Sensitive ]
Moisture Sensitive | [Detection Methods]
HPLC,NMR | [BRN ]
1892897 | [InChIKey]
ACBQROXDOHKANW-UHFFFAOYSA-N | [CAS DataBase Reference]
5070-13-3(CAS DataBase Reference) | [Storage Precautions]
Moisture sensitive |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [F ]
10-21 | [HS Code ]
29209090 |
| Hazard Information | Back Directory | [Chemical Properties]
white to pale yellow or beige powder | [Uses]
Bis(4-nitrophenyl) carbonate is used as a reagent for preparation of symmetrical and unsymmetrical urea and 4-nitrophenyl esters of N-protected amino acids. It acts as a peptide coupling reagent. It finds application as a reagent for the preparation of carbamate linked cytosines. | [Purification Methods]
Dissolve the carbonate in CHCl3, wash it with 2N NaOH (3 x) and once with conc HCl, dry (Na2SO4), evaporate and crystallise the residue from toluene (authors say prisms from 15 volumes of *benzene). [Glatthard & Matter Helv Chim Acta 46 795 1963, Beilstein 6 III 820.] |
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