| Identification | More | [Name]
3-Methoxy-2-methylbenzoic acid | [CAS]
55289-06-0 | [Synonyms]
3-METHOXY-2-METHYLBENZOIC ACID
3-METHOXY-O-TOLUIC ACID
2-Methyl-3-Methoxy Benzoic Acid
3-Methoxy-o-toluic acid~2-Methyl-m-anisic acid
2-Methyl-m-anisicacid | [EINECS(EC#)]
1533716-785-6 | [Molecular Formula]
C9H10O3 | [MDL Number]
MFCD02094039 | [Molecular Weight]
166.17 | [MOL File]
55289-06-0.mol |
| Chemical Properties | Back Directory | [Melting point ]
147.0 to 151.0 °C | [Boiling point ]
138 °C(Press: 16 Torr) | [density ]
1.168±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
powder to crystal | [pka]
3.83±0.10(Predicted) | [color ]
White to Yellow to Orange | [Water Solubility ]
Soluble in methanol. Insoluble in water. | [BRN ]
510395 | [InChI]
InChI=1S/C9H10O3/c1-6-7(9(10)11)4-3-5-8(6)12-2/h3-5H,1-2H3,(H,10,11) | [InChIKey]
JPCISVSOTKMFPG-UHFFFAOYSA-N | [SMILES]
C(O)(=O)C1=CC=CC(OC)=C1C | [CAS DataBase Reference]
55289-06-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
WGK 3 | [TSCA ]
TSCA listed | [HS Code ]
2916399090 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
This product is solid and insoluble in water. | [Uses]
3-Methoxy-2-methylbenzoic acid is used as a Corey-Bakshi-Shibata oxazaborolidine catalyst for asymmetric reduction and asymmetric synthesis. It is used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2 symmetrical ferrocenyl diols and propargyl alcohols. It is also used in desymmetrizing reduction leading to (S)-4-hydroxycyclohexenone. |
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