ChemicalBook--->CAS DataBase List--->693-95-8

693-95-8

693-95-8 Structure

693-95-8 Structure
IdentificationMore
[Name]

4-Methylthiazole
[CAS]

693-95-8
[Synonyms]

4-METHYL-1,3-THIAZOLE
4-METHYLTHIAZOLE
FEMA 3716
FEMA NUMBER 3716
METHYLTHIAZOLE, 4-
4-methyl-thiazol
Thiazole, 4-methyl-
4-METHYLTHIAZOLE 98+%
4-Methylthiazole,99%
4-methylthiazole,4-methyl-1,3-thiazole
4-Methylthizaole
[EINECS(EC#)]

211-764-1
[Molecular Formula]

C4H5NS
[MDL Number]

MFCD00005340
[Molecular Weight]

99.15
[MOL File]

693-95-8.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
[Melting point ]

134 °C
[Boiling point ]

133-134 °C (lit.)
[density ]

1.09 g/mL at 25 °C(lit.)
[FEMA ]

3716
[refractive index ]

n20/D 1.524(lit.)
[Fp ]

90 °F
[storage temp. ]

Flammables area
[form ]

Liquid
[pka]

pK1:3.16(+1) (25°C,μ=0.1)
[color ]

Clear colorless to slightly yellow
[Specific Gravity]

1.090
[Odor]

at 0.10 % in dipropylene glycol. nutty green vegetable tomato
[biological source]

synthetic
[Odor Type]

nutty
[JECFA Number]

1043
[BRN ]

105228
[InChI]

1S/C4H5NS/c1-4-2-6-3-5-4/h2-3H,1H3
[InChIKey]

QMHIMXFNBOYPND-UHFFFAOYSA-N
[SMILES]

Cc1cscn1
[LogP]

0.90
[CAS DataBase Reference]

693-95-8(CAS DataBase Reference)
[NIST Chemistry Reference]

4-Methylthiazole(693-95-8)
[EPA Substance Registry System]

693-95-8(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)
GHS02,GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H226-H302-H315-H318-H335
[Precautionary statements ]

P261-P280-P305+P351+P338
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R10:Flammable.
R22:Harmful if swallowed.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[RTECS ]

XJ5096000
[TSCA ]

T
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29341000
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
[Hazardous Substances Data]

693-95-8(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Formamide-->methylthiazoline,4-methyl-3-thiazoline-->2-Amino-4-methylthiazole-->4-Methylisothiazole-->4-methylthiazole-2(3H)-thione-->(4-Methyl-thiazol-2-yl)-hydrazine HCl-->4-Methylthiazole-5-carboxylic acid-->Thioformamide
[Preparation Products]

5-(2-Hydroxyethyl)-4-methylthiazole-->3-Methylisothiazole-->4-(Chloromethyl)thiazole-->4-Methyl-2-(tributylstannyl)thiazole-->4-Methyl-2-thiazolecarboxaldehyde 97-->5-bromo-4-methylthiazole-->4-Hydroxymethylthiazole-->2,4-Dimethylthiazole
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-Methylthiazole(693-95-8).msds
Hazard InformationBack Directory
[Description]

4-Methylthiazole has a nutty, green odor.
[Chemical Properties]

4-Methylthiazole has a nutty, green odo
[Chemical Properties]

CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
[Occurrence]

Reported found in cooked asparagus, roasted barley, cooked beef, cocoa, cooked pork, roasted coffee, roasted peanuts, boiled egg, malt, wort and cooked shrimp.
[Uses]

4-Methylthiazole was used in the synthesis of catalytic dendrophanes, as functional mimics of the thiamine-diphosphate-dependent enzyme pyruvate oxidase. It was used in small scale preparation of 3-butyl-4-methylthiazolium bromide.
[Definition]

ChEBI: A 1,3-thiazole substituted by a methyl group at position 4.
[Taste threshold values]

Taste characteristics at 10 ppm: green, vegetative and meaty with an alliaceous nuance
[General Description]

4-Methylthiazole forms complexes with cobalt(II), zinc(II), nickel(II) and copper(II) halides.
Spectrum DetailBack Directory
[Spectrum Detail]

4-Methylthiazole(693-95-8)MS
4-Methylthiazole(693-95-8)1HNMR
4-Methylthiazole(693-95-8)13CNMR
4-Methylthiazole(693-95-8)IR1
4-Methylthiazole(693-95-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-Methylthiazole, 99%(693-95-8)
[Alfa Aesar]

4-Methylthiazole, 99%(693-95-8)
[Sigma Aldrich]

693-95-8(sigmaaldrich)
[TCI AMERICA]

4-Methylthiazole,>98.0%(GC)(693-95-8)
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