| Identification | More | [Name]
(R)-(+)-Methyl (R)-2-chloropropionate | [CAS]
77287-29-7 | [Synonyms]
METHYL (R)-(+)-2-CHLOROPROPIONATE
(R)-(+)-2-CHLOROPROPIONIC ACID METHYL ESTER
(R)-(+)-METHYL 2-CHLOROPROPIONATE
(R)-(+)-Methyl (R)-2-chloropropionate
2 METHYL CHLORPROPIONATE
METHYL (R)-(+)-2-CHLOROPROPIONATE, 99% (
2-Methylchloroproprionate
2-Methylchlorproprionate
(2R)-2-Chloropropanoic acid methyl ester
(R)-2-Chloropropionic acid methyl | [EINECS(EC#)]
278-658-5 | [Molecular Formula]
C4H7ClO2 | [MDL Number]
MFCD00062940 | [Molecular Weight]
122.55 | [MOL File]
77287-29-7.mol |
| Chemical Properties | Back Directory | [alpha ]
26 º (neat) | [Boiling point ]
132-134 °C(lit.) | [density ]
1.152 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.418
| [Fp ]
99 °F
| [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Optical Rotation]
[α]20/D +26°, neat | [BRN ]
1720590 | [InChI]
1S/C4H7ClO2/c1-3(5)4(6)7-2/h3H,1-2H3/t3-/m1/s1 | [InChIKey]
JLEJCNOTNLZCHQ-GSVOUGTGSA-N | [SMILES]
COC(=O)[C@@H](C)Cl | [CAS DataBase Reference]
77287-29-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 2933 3/PG 3
| [WGK Germany ]
3
| [F ]
19 | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29159000 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless liquid | [Uses]
Chiral starting material | [Purification Methods]
Purify the ester by repeated distillation [Walker J Chem Soc 67 916 1895, Walden Chem Ber 28 1293 1985, see also Gless Synth Commun 16 633 1986]. [Beilstein 2 H 248.] |
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