Methyl-N-methylanthranilat

Methyl 2-(methylamino)benzoate Struktur
85-91-6
CAS-Nr.
85-91-6
Bezeichnung:
Methyl-N-methylanthranilat
Englisch Name:
Methyl 2-(methylamino)benzoate
Synonyma:
DIMETHYL ANTHRANILATE;METHYL N-METHYLANTHRANILATE;Methyl methanthranilate;Benzoic acid, 2-(methylamino)-, methyl ester;DIMETHYLANTHRANILAT;METHYL METHYLANTHRANILATE;2-Methylaminomethyl benzoate;Dimethylanthanilate;3-Amino-2-butenamide;FEMA 2718
CBNumber:
CB1755530
Summenformel:
C9H11NO2
Molgewicht:
165.19
MOL-Datei:
85-91-6.mol

Methyl-N-methylanthranilat Eigenschaften

Schmelzpunkt:
17-19 °C(lit.)
Siedepunkt:
256 °C(lit.)
Dichte
1.126 g/mL at 25 °C(lit.)
Dampfdruck
2.74Pa at 25℃
Brechungsindex
n20/D 1.579(lit.)
FEMA 
2718 | METHYL N-METHYLANTHRANILATE
Flammpunkt:
>230 °F
storage temp. 
2-8°C
Löslichkeit
Miscible in all proportions with ethanol 96%, DMSO and diethyl ether.
pka
2.80±0.10(Predicted)
Farbe
Colourless to Yellow
PH
7-8 (H2O, 20℃)
Geruch (Odor)
at 100.00 %. fruity musty sweet neroli powdery phenolic wine
Geruchsart
floral
Wasserlöslichkeit
329.792mg/L at 30℃
JECFA Number
1545
BRN 
607217
LogP
2.81-3.08 at 25℃
CAS Datenbank
85-91-6(CAS DataBase Reference)
NIST chemische Informationen
Benzoic acid,o-(methylamino)-, methyl ester(85-91-6)
EPA chemische Informationen
Methyl N-methyl anthranilate (85-91-6)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/37/38
S-Sätze: 26-36-36/37/39-22
WGK Germany  1
RTECS-Nr. CB3500000
TSCA  Yes
HS Code  2922498590
Giftige Stoffe Daten 85-91-6(Hazardous Substances Data)
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
Sicherheit
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P337+P313 Bei anhaltender Augenreizung: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.

Methyl-N-methylanthranilat Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S22:Staub nicht einatmen.

Beschreibung

Methyl n-methylanthranilate has an orange and mandarin peel-like odor with a musty, grape-like flavor. It is somewhat more berry-like than grape. May be prepared by methylation of methyl anthranilate or esterification of N-methylanthranilic acid.

Chemische Eigenschaften

Methyl N-Methylanthranilate is the main component of petitgrain oils from mandarin leaves and is also found in mandarin oil. It is a pale yellow, fluorescent liquid with a delicate mandarin odor. The ester can be prepared by methylation ofmethyl anthranilate. It is used in soap and cosmetic perfumes as well as in aromas, particularly for mandarin flavors.

Occurrence

Reported found in mandarin essential oil and mandarin leaves essential oil (50 to 76.5%); also reported in the oil from bulbs of Kaempferia ethelae L., in orange petitgrain, and in the oil from hyacinth flowers. Also reported found in starfruit, orange peel oil and grapefruit juice.

Verwenden

Methyl 2-(Methylamino)benzoate is one of many volatile components from mango cultivars.

Vorbereitung Methode

Methyl N-methanthranilate is a component of mandarin and mandarin tree leaf essential oil. It is also found in oil from bulbs of Kaempferia ethelae L., hyacinth flowers, and orange petitgrain . It is synthesized by methylation of methyl anthranilate or esterification ofN-methylanthranilic acid.

synthetische

By methylation of methyl anthranilate or esterification of N-methylanthranillic acid.

Sicherheitsprofil

Poison by intravenous route. Moderately toxic by ingestion. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS.

Methyl-N-methylanthranilat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Methyl-N-methylanthranilat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 320)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Mojin Biotechnology Co., Ltd
+8613288715578
sales@hbmojin.com China 12457 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806
sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21695 55
Chengdu GLP biotechnology Co Ltd
028-87075086 13350802083
scglp@glp-china.com CHINA 1824 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
Accela ChemBio Inc.
(+1)-858-699-3322
info@accelachem.com United States 19965 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282
alice@crovellbio.com China 8823 58
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22968 58
career henan chemical co
+86-0371-86658258 15093356674;
factory@coreychem.com China 29826 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-87569266 15319487004
1015@dideu.com China 2263 58

85-91-6(Methyl-N-methylanthranilat)Verwandte Suche:


  • METHYL 2-(N-METHYLAMINO)BENZOATE
  • METHYL 2-METHYLAMINOBENZOATE
  • METHYL O-(METHYLAMINO)BENZOATE
  • FEMA 2718
  • 2-METHYLAMINOBENZOIC ACID METHYL ESTER
  • N-METHYLANTHRANILIC ACID METHYL ESTER
  • N-METHYL-2-AMINOBENZOIC ACID METHYL ESTER
  • 2-Methylaminomethylbenzoate
  • Anthranilic acid, N-methyl-, methyl ester
  • Methyl 2-methylaminobenzoate, tech.
  • Methyl-N-methylanthranilat
  • 2-(methylamino)-benzoicacimethylester
  • DIMETHYL ANTHRANILATE, NATURAL
  • DIMETHYL ANTHRANILATE, SYNTHETIC
  • (CH3NH)C6H4CO2CH3
  • Dimethyl anthranilate ,98%
  • Dimethyl anthranilate,Methyl N-methylanthranilate
  • Methyl N-methylanthranilate, 2-(Methoxycarbonyl)-N-methylaniline
  • b-Aminocrotonamide
  • 2-Methylaminobenzoic acid methyl
  • o-(Methylamino)benzoic acid methyl ester
  • N-Methyl-2-aminobenzoic Acid Methyl Ester N-Methylanthranilic Acid Methyl Ester Methyl N-Methyl-2-aminobenzoate
  • METHYL-N-METHYL ANTHRANILATE FOR SYNTHES
  • Benzoicacid,2-(methylamino)-,methylester
  • Me N-methylanthranilate
  • Methyl benzoate, 2-methylamino
  • Methyl methylaminobenzoate
  • Methyl m-methylanthranilate
  • Methyl N-methyl-o-anthranilate
  • methylmethanthranilate
  • N-Methyl methyl anthranilate
  • n-methylanthranilicacid,methyl
  • n-methyl-anthranilicacimethylester
  • N-Methylanthranilic acid methyl ester~Methyl 2-methylaminobenzoate
  • DIMETHYL ANTHRANILATE 97+%
  • DIMETHYL ANTHRANILATE 98+% NATURAL &
  • N-Methylanthranilic Acid Methyl Ester Methyl N-Methylanthranilate N-Methyl-2-aminobenzoic Acid Methyl Ester methyl 2-(methylamino)benzoate
  • 5-(2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl)pentanoic acid (13-methyl-17-oxo-7,8,9,11,12,14,15,16-octahydro-6H-cyclopenta[a]phenanthren-3-yl) ester
  • MethylN-Methylanthranilate>
  • Methyl N-Methyl-2-aminobenzoate
  • Methyl 2-(methylamino)benzoate USP/EP/BP
  • Dimethyl Anthranilate 6878001
  • METHYL N-METHYLANTHRANILATE
  • METHYL METHYLANTHRANILATE
  • DIMETHYL ANTHRANILATE
  • 2-Methylaminomethyl benzoate
  • DIMETHYLANTHRANILAT
  • 3-Amino-2-butenamide
  • Benzoic acid, 2-(methylamino)-, methyl ester
  • Methyl methanthranilate
  • Dimethylanthanilate
  • 85-91-6
  • 2CH3NHC6H4CO2CH3
  • CH3NHC6H4COOCH3
  • C9H11O2N
  • Organic Building Blocks
  • Esters
  • C8 to C9
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