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Methyl-N-methylanthranilat Produkt Beschreibung

Methyl 2-(methylamino)benzoate Struktur
85-91-6
CAS-Nr.
85-91-6
Bezeichnung:
Methyl-N-methylanthranilat
Englisch Name:
Methyl 2-(methylamino)benzoate
Synonyma:
FEMA 2718;(CH3NH)C6H4CO2CH3;b-Aminocrotonamide;DIMETHYLANTHRANILAT;Dimethylanthanilate;3-Amino-2-butenamide;DIMETHYL ANTHRANILATE;methylmethanthranilate;Me N-methylanthranilate;Methyl methanthranilate
CBNumber:
CB1755530
Summenformel:
C9H11NO2
Molgewicht:
165.19
MOL-Datei:
85-91-6.mol

Methyl-N-methylanthranilat Eigenschaften

Schmelzpunkt:
17-19 °C(lit.)
Siedepunkt:
256 °C(lit.)
Dichte
1.126 g/mL at 25 °C(lit.)
FEMA 
2718 | METHYL N-METHYLANTHRANILATE
Brechungsindex
n20/D 1.579(lit.)
Flammpunkt:
>230 °F
storage temp. 
2-8°C
Löslichkeit
Miscible in all proportions with ethanol 96%, DMSO and diethyl ether.
Aggregatzustand
neat
pka
2.80±0.10(Predicted)
PH
7-8 (H2O, 20℃)
JECFA Number
1545
BRN 
607217
CAS Datenbank
85-91-6(CAS DataBase Reference)
NIST chemische Informationen
Benzoic acid,o-(methylamino)-, methyl ester(85-91-6)
EPA chemische Informationen
Methyl N-methyl anthranilate (85-91-6)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/37/38
S-Sätze: 26-36-36/37/39-22
WGK Germany  1
RTECS-Nr. CB3500000
TSCA  Yes
Giftige Stoffe Daten 85-91-6(Hazardous Substances Data)
Bildanzeige (GHS)
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung P264, P280, P305+P351+P338,P337+P313P
Sicherheit
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

Methyl-N-methylanthranilat Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S22:Staub nicht einatmen.

Beschreibung

Methyl n-methylanthranilate has an orange and mandarin peel-like odor with a musty, grape-like flavor. It is somewhat more berry-like than grape. May be prepared by methylation of methyl anthranilate or esterification of N-methylanthranilic acid.

Chemische Eigenschaften

Methyl-n-methylanthranilate has an orange and mandarin peel-like odor and a musty, grape-like flavor; somewhat more berry-like than grape.

Chemische Eigenschaften

Methyl N-Methylanthranilate is the main component of petitgrain oils from mandarin leaves and is also found in mandarin oil. It is a pale yellow, fluorescent liquid with a delicate mandarin odor. The ester can be prepared by methylation ofmethyl anthranilate. It is used in soap and cosmetic perfumes as well as in aromas, particularly for mandarin flavors.

Occurrence

Reported found in mandarin essential oil and mandarin leaves essential oil (50 to 76.5%); also reported in the oil from bulbs of Kaempferia ethelae L., in orange petitgrain, and in the oil from hyacinth flowers. Also reported found in starfruit, orange peel oil and grapefruit juice.

Verwenden

It is used as a flavorant in a wide range of foods (particularly flour and sugar confections).

synthetische

By methylation of methyl anthranilate or esterification of N-methylanthranillic acid.

Vorbereitung Methode

Methyl N-methanthranilate is a component of mandarin and mandarin tree leaf essential oil. It is also found in oil from bulbs of Kaempferia ethelae L., hyacinth flowers, and orange petitgrain . It is synthesized by methylation of methyl anthranilate or esterification ofN-methylanthranilic acid.

Taste threshold values

Taste characteristics at 10 ppm: fruity grape skin, anthranilate-like with a woody and floral nuance

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 3373, 1984 DOI: 10.1021/jo00192a024

Toxicity evaluation

The acute oral LD50 value in rats was reported as 3.7 ml/kg (Levenstein, 1974). The acute oral LD50 in female rats was reported to be between 2.25 g/kg (no deaths) and 3.38 g/kg (100% deaths) (Gaunt, Sharratt, Grasso & Wright, 1970). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Levenstein, 1974). The LC 50 for larvae of Tribolium destructor was found to be 0-1151 mg/cm3 (Vasechko, Kuznetsov, Smelyanets & Guznenok, 1970).

Sicherheitsprofil

Poison by intravenous route. Moderately toxic by ingestion. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS.

Methyl-N-methylanthranilat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Methyl-N-methylanthranilat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 176)Lieferanten
Firmenname Telefon Fax E-Mail Land Produktkatalog Edge Rate
Capot Chemical Co.,Ltd.
+86(0)13336195806 +86-571-85586718
+86-571-85864795 sales@capotchem.com China 20010 60
Chengdu GLP biotechnology Co Ltd
13350802083 028-87075086
scglp@glp-china.com CHINA 1824 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Accela ChemBio Inc.
(+1)-858-699-3322
(+1)-858-876-1948 info@accelachem.com United States 19969 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930503282
sales3@crovellbio.com China 5019 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58
career henan chemical co
13203830695 0086-371-86658258
0086-371-86658258 factory@coreychem.com CHINA 29865 58
Shaanxi Dideu Medichem Co. Ltd
15319487004
029-88380327 1015@dideu.com CHINA 4154 58
Zhuozhou Wenxi import and Export Co., Ltd
+8613111626072 (WhatsApp)
Wechat: +8613111626072 Wickr me: waynehu zzwenxi@126.com CHINA 13187 58

85-91-6(Methyl-N-methylanthranilat)Verwandte Suche:


  • METHYL 2-(N-METHYLAMINO)BENZOATE
  • METHYL 2-METHYLAMINOBENZOATE
  • METHYL O-(METHYLAMINO)BENZOATE
  • METHYL N-METHYLANTHRANILATE
  • METHYL METHYLANTHRANILATE
  • FEMA 2718
  • DIMETHYL ANTHRANILATE
  • 2-METHYLAMINOBENZOIC ACID METHYL ESTER
  • N-METHYLANTHRANILIC ACID METHYL ESTER
  • N-METHYL-2-AMINOBENZOIC ACID METHYL ESTER
  • 2-Methylaminomethyl benzoate
  • 2-Methylaminomethylbenzoate
  • Anthranilic acid, N-methyl-, methyl ester
  • Methyl 2-methylaminobenzoate, tech.
  • DIMETHYLANTHRANILAT
  • Methyl-N-methylanthranilat
  • 2-(methylamino)-benzoicacimethylester
  • DIMETHYL ANTHRANILATE, NATURAL
  • DIMETHYL ANTHRANILATE, SYNTHETIC
  • (CH3NH)C6H4CO2CH3
  • Dimethyl anthranilate ,98%
  • Dimethyl anthranilate,Methyl N-methylanthranilate
  • Methyl N-methylanthranilate, 2-(Methoxycarbonyl)-N-methylaniline
  • 3-Amino-2-butenamide
  • b-Aminocrotonamide
  • 2-Methylaminobenzoic acid methyl
  • o-(Methylamino)benzoic acid methyl ester
  • N-Methyl-2-aminobenzoic Acid Methyl Ester N-Methylanthranilic Acid Methyl Ester Methyl N-Methyl-2-aminobenzoate
  • METHYL-N-METHYL ANTHRANILATE FOR SYNTHES
  • 5-(2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl)pentanoic acid (13-methyl-17-oxo-7,8,9,11,12,14,15,16-octahydro-6H-cyclopenta[a]phenanthren-3-yl) ester
  • Benzoic acid, 2-(methylamino)-, methyl ester
  • Benzoicacid,2-(methylamino)-,methylester
  • Me N-methylanthranilate
  • Methyl benzoate, 2-methylamino
  • Methyl methanthranilate
  • Methyl methylaminobenzoate
  • Methyl m-methylanthranilate
  • Methyl N-methyl-o-anthranilate
  • methylmethanthranilate
  • N-Methyl methyl anthranilate
  • n-methylanthranilicacid,methyl
  • n-methyl-anthranilicacimethylester
  • N-Methylanthranilic acid methyl ester~Methyl 2-methylaminobenzoate
  • DIMETHYL ANTHRANILATE 97+%
  • DIMETHYL ANTHRANILATE 98+% NATURAL &
  • Dimethylanthanilate
  • N-Methylanthranilic Acid Methyl Ester Methyl N-Methylanthranilate N-Methyl-2-aminobenzoic Acid Methyl Ester methyl 2-(methylamino)benzoate
  • MethylN-Methylanthranilate>
  • Methyl N-Methyl-2-aminobenzoate
  • Methyl 2-(methylamino)benzoate USP/EP/BP
  • 85-91-6
  • 2CH3NHC6H4CO2CH3
  • CH3NHC6H4COOCH3
  • C9H11O2N
  • Organic Building Blocks
  • Esters
  • C8 to C9
  • Carbonyl Compounds
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