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메틸 N-메틸안트라닐레이트

메틸 N-메틸안트라닐레이트
메틸 N-메틸안트라닐레이트 구조식 이미지
카스 번호:
85-91-6
한글명:
메틸 N-메틸안트라닐레이트
동의어(한글):
N-메틸엔트라닐산메틸;메틸N-메틸안트라닐레이트;메틸 N-메틸안트라닐레이트
상품명:
Methyl 2-(methylamino)benzoate
동의어(영문):
FEMA 2718;(CH3NH)C6H4CO2CH3;b-Aminocrotonamide;DIMETHYLANTHRANILAT;Dimethylanthanilate;3-Amino-2-butenamide;DIMETHYL ANTHRANILATE;methylmethanthranilate;Me N-methylanthranilate;Methyl methanthranilate
CBNumber:
CB1755530
분자식:
C9H11NO2
포뮬러 무게:
165.19
MOL 파일:
85-91-6.mol

메틸 N-메틸안트라닐레이트 속성

녹는점
17-19 °C(lit.)
끓는 점
256 °C(lit.)
밀도
1.126 g/mL at 25 °C(lit.)
FEMA
2718 | METHYL N-METHYLANTHRANILATE
굴절률
n20/D 1.579(lit.)
인화점
>230 °F
저장 조건
Store below +30°C.
용해도
Miscible in all proportions with ethanol 96%, DMSO and diethyl ether.
물리적 상태
neat
산도 계수 (pKa)
2.80±0.10(Predicted)
수소이온지수(pH)
7-8 (H2O, 20℃)
JECFA Number
1545
BRN
607217
CAS 데이터베이스
85-91-6(CAS DataBase Reference)
NIST
Benzoic acid,o-(methylamino)-, methyl ester(85-91-6)
EPA
Methyl N-methyl anthranilate (85-91-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 26-36-36/37/39-22
WGK 독일 1
RTECS 번호 CB3500000
TSCA Yes
유해 물질 데이터 85-91-6(Hazardous Substances Data)
기존화학 물질 KE-24372
그림문자(GHS):
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
2
1 0

메틸 N-메틸안트라닐레이트 MSDS


Methyl 2-(methylamino)benzoate

메틸 N-메틸안트라닐레이트 C화학적 특성, 용도, 생산

개요

Methyl n-methylanthranilate has an orange and mandarin peel-like odor with a musty, grape-like flavor. It is somewhat more berry-like than grape. May be prepared by methylation of methyl anthranilate or esterification of N-methylanthranilic acid.

화학적 성질

Methyl-n-methylanthranilate has an orange and mandarin peel-like odor and a musty, grape-like flavor; somewhat more berry-like than grape.

화학적 성질

Methyl N-Methylanthranilate is the main component of petitgrain oils from mandarin leaves and is also found in mandarin oil. It is a pale yellow, fluorescent liquid with a delicate mandarin odor. The ester can be prepared by methylation ofmethyl anthranilate. It is used in soap and cosmetic perfumes as well as in aromas, particularly for mandarin flavors.

출처

Reported found in mandarin essential oil and mandarin leaves essential oil (50 to 76.5%); also reported in the oil from bulbs of Kaempferia ethelae L., in orange petitgrain, and in the oil from hyacinth flowers. Also reported found in starfruit, orange peel oil and grapefruit juice.

용도

It is used as a flavorant in a wide range of foods (particularly flour and sugar confections).

생산 방법

Methyl N-methanthranilate is a component of mandarin and mandarin tree leaf essential oil. It is also found in oil from bulbs of Kaempferia ethelae L., hyacinth flowers, and orange petitgrain . It is synthesized by methylation of methyl anthranilate or esterification ofN-methylanthranilic acid.

제조 방법

By methylation of methyl anthranilate or esterification of N-methylanthranillic acid.

Taste threshold values

Taste characteristics at 10 ppm: fruity grape skin, anthranilate-like with a woody and floral nuance

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 3373, 1984 DOI: 10.1021/jo00192a024

Toxicity evaluation

The acute oral LD50 value in rats was reported as 3.7 ml/kg (Levenstein, 1974). The acute oral LD50 in female rats was reported to be between 2.25 g/kg (no deaths) and 3.38 g/kg (100% deaths) (Gaunt, Sharratt, Grasso & Wright, 1970). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Levenstein, 1974). The LC 50 for larvae of Tribolium destructor was found to be 0-1151 mg/cm3 (Vasechko, Kuznetsov, Smelyanets & Guznenok, 1970).

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS.

메틸 N-메틸안트라닐레이트 준비 용품 및 원자재

원자재

준비 용품


메틸 N-메틸안트라닐레이트 공급 업체

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Accela ChemBio Inc.
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Hebei Guanlang Biotechnology Co., Ltd.
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career henan chemical co
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