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4,4'-Methylenebis(2,6-di-tert-butylphenol)

4,4'-Methylenebis(2,6-di-tert-butylphenol) structure

CAS No.: 118-82-1

Chemical Name:: 4,4'-Methylenebis(2,6-di-tert-butylphenol)

Synonyms: e702;E 702;l3mb1;bimoxm;binoxm;L 3MB1;lz-mb1;binox-m;Binox M;Bimox M

CBNumber:: CB0206363

Molecular Formula:: C29H44O2

Molecular Weight:: 424.66

MDL Number:: MFCD00008822

MOL File:: 118-82-1.mol

MSDS File:: SDS

Last updated:2024-04-24 17:21:45

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4,4'-Methylenebis(2,6-di-tert-butylphenol) Properties

Melting point	155-159 °C(lit.)
Boiling point	289 °C40 mm Hg(lit.)
Density	0.99 g/cm3 (20℃)
vapor pressure	0Pa at 25℃
refractive index	1.4875 (estimate)
Flash point	289°C/40mm
storage temp.	Store below +30°C.
solubility	<0.0001g/l
pka	12.03±0.40(Predicted)
form	solid
color	White
Water Solubility	31.9ng/L at 20℃
BRN	1916919
Stability	Stable for 2 years from date of purchase as supplied. Solutions are not stable. Solutions must be made fresh and used within 1 working day.
InChIKey	MDWVSAYEQPLWMX-UHFFFAOYSA-N
LogP	8.9 at 25℃
Indirect Additives used in Food Contact Substances	4,4'-METHYLENEBIS(2,6-DI-TERT-BUTYLPHENOL)
FDA 21 CFR	175.105; 178.2010
CAS DataBase Reference	118-82-1(CAS DataBase Reference)
FDA UNII	37N5K66648
NIST Chemistry Reference	Phenol, 4,4'-methylenebis[2,6-bis(1,1-dimethylethyl)-(118-82-1)
EPA Substance Registry System	Phenol, 4,4'-methylenebis[2,6-bis(1,1-dimethylethyl)- (118-82-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38-38-37-36

Safety Statements

26-36

WGK Germany

RTECS

SL9650000

TSCA

Yes

HS Code

29072990

Toxicity

LD50 oral in rat: > 24gm/kg

NFPA 704

	1
1		0

4,4'-Methylenebis(2,6-di-tert-butylphenol) price More Price(19)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	8.42857	4,4′-Methylenebis(2,6-di-tert-butylphenol) for synthesis	118-82-1	10g	$39.7	2024-03-01	Buy
Sigma-Aldrich	8.42857	4,4′-Methylenebis(2,6-di-tert-butylphenol) for synthesis	118-82-1	100g	$62	2024-03-01	Buy
TCI Chemical	M0214	4,4'-Methylenebis(2,6-di-tert-butylphenol) >98.0%(GC)	118-82-1	25g	$29	2024-03-01	Buy
TCI Chemical	M0214	4,4'-Methylenebis(2,6-di-tert-butylphenol) >98.0%(GC)	118-82-1	500g	$131	2024-03-01	Buy
Alfa Aesar	A18910	4,4'-Methylenebis(2,6-di-tert-butylphenol), 98%	118-82-1	50g	$22.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
8.42857	10g	$39.7	Buy
8.42857	100g	$62	Buy
M0214	25g	$29	Buy
M0214	500g	$131	Buy
A18910	50g	$22.65	Buy

4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical Properties,Uses,Production

Description

bis-BHT (118-82-1) is a potent antioxidant. Cell permeable.

Chemical Properties

light yellow crystalline

Uses

Antioxidant.

Definition

ChEBI: 4,4'-Methylenebis(2,6-di-tert-butylphenol) is a diarylmethane.

Application

4,4'-Methylenebis(2,6-di-tert-butylphenol), also known as H2-4DBP, could be used as a ligand to react with sets of M(OR)x and MRx. The ligand possesses more flexibility than OBzP or catecholate derivatives, and the para-OH makes it of interest for controlled alcoholysis. This compound has several characteristics, including (i) the ortho position possesses the sterically hindering t-butyl group which will assist in minimizing oligomerization, (ii) the para linkage prevents chelation of the 4DBP ligand to the metal upon coordination, and (iii) may act as a valuable model for complexation behavior of the plastic precursor bisphenol-A [BPA; 4,4' -(propane-2,2-diyl)diphenol] that has become of recent concern[2].

Flammability and Explosibility

Non flammable

References

1) Amorati et al. (2003), Antioxidant activity of 0-bisphenols: the role of intramolecular hydrogen bonding; J. Org. Chem. 68 5198.
[2] T. Boyle, Daniel T Yonemoto, L. Steele. “Synthesis and characterization of 4,4′-methylenebis (2,6-di-tert-butylphenol) derivatives of a series of metal alkoxides and alkyls.” Journal of Coordination Chemistry 65.1(2012): 487–505.

4,4'-Methylenebis(2,6-di-tert-butylphenol) synthesis

Synthesis of 4,4'-Methylenebis(2,6-di-tert-butylphenol) from 3,5-Di-tert-butyl-4-hydroxybenzyl alcohol

4,4'-Methylenebis(2,6-di-tert-butylphenol) Preparation Products And Raw materials

Raw materials

2,6-Di-tert-butylphenol 3,5-DI-TERT-BUTYL-4-HYDROXYBENZYL ETHER 3,5-di-tert-butyl-4-hydroxybenzyl acetate 3,5-Di-tert-butyl-4-hydroxybenzyl alcohol 4,4'-[2,4,6-Trimethyl-1,3-phenylenebis(methylene)]bis[2,6-di(tert-butyl)phenol]

Antioxidant 1330 2,6-Di-tert-butyl-4-(dimethylaminomethyl)phenol Mesitylene Formaldehyde

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Preparation Products

3,5-di-tert-butyl-4-hydroxybenzyl acetate 4,4'-Ethylenebis(2,6-ditert-butylphenol)

4,4'-Methylenebis(2,6-di-tert-butylphenol) Suppliers

Global( 215)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
NANJING PASTEUR ChEMICAL CO.,LTD	+86-18066069912 +86-18066069912	1390310770@qq.com	China	17	58
Qingdao Scienoc Chemical CO Ltd	+86-0532-68076095 +8618661673503	info@scienoc.com	China	113	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7845	58
Hebei Zhuanglai Chemical Trading Co.,Ltd	+8613343047651	admin@zlchemi.com	China	476	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
Zjartschem	+86-571-8723 8903 jocelynpan@zjarts.com	jocelynpan@zjarts.com	CHINA	993	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58

Supplier	Advantage
NANJING PASTEUR ChEMICAL CO.,LTD	58
Qingdao Scienoc Chemical CO Ltd	58
Hebei Mojin Biotechnology Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58
Hebei Zhuanglai Chemical Trading Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
Zjartschem	58
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58

View Lastest Price from 4,4'-Methylenebis(2,6-di-tert-butylphenol) manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-24	Antioxidant 702 118-82-1	US $200.00-95.00 / kg	1kg	99%	20ton	Hebei Zhuanglai Chemical Trading Co.,Ltd
2024-04-24	4,4'-Methylenebis(2,6-di-tert-butylphenol) 118-82-1	US $30.00 / kg	1kg	99%	5000KG/Week	Hebei Zhuanglai Chemical Trading Co.,Ltd
2024-01-18	4,4'-Methylenebis(2,6-di-tert-butylphenol) 118-82-1	US $6.00-0.60 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd

Antioxidant 702
118-82-1
US $200.00-95.00 / kg
99%
Hebei Zhuanglai Chemical Trading Co.,Ltd

4,4'-Methylenebis(2,6-di-tert-butylphenol)
118-82-1
US $30.00 / kg
99%
Hebei Zhuanglai Chemical Trading Co.,Ltd

4,4'-Methylenebis(2,6-di-tert-butylphenol)
118-82-1
US $6.00-0.60 / KG
99%
Henan Fengda Chemical Co., Ltd

4,4'-Methylenebis(2,6-di-tert-butylphenol) Spectrum

4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)MS 4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)¹HNMR 4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)¹³CNMR 4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)IR1 4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)IR2 4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)ESR

118-82-1(4,4'-Methylenebis(2,6-di-tert-butylphenol))Related Search:

Butyl acetate Antioxidant 1098 3-tert-Butylphenol 4-tert-Butylphenol tert-Butanol

p-Cresol tert-Butyl peroxyacetate Butyl acrylate Antioxidant 1010 2-sec-Butylphenol

2,4-Di-tert-butylphenol 4-Butylphenol 4,4'-Thiobis(6-tert-butyl-m-cresol) Antioxidant 1520 2,6-Di-tert-butylphenol

2,2'-Methylenebis(4-methyl-6-tert-butylphenol) tert-Butyldimethylsilyl chloride Butylated Hydroxytoluene

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antioxidante702 Bimox M bimoxm Binox M binoxm binox-m bis(4-Hydroxy-3,5-ditertbutyl)phenylmathane Di(4-hydroxy-3,5-di-tert-butylphenyl)methane E 702 e702 mb1(antioxidant) nsc30551 Phenol, 4,4'-methylenebis*2,6-bis(1,1-dimethylethyl)- Phenol, 4,4'-methylenebis*2,6-di-tert-butyl- Phenol, 4,4'-methylenebis[2,6-di-tert-butyl- Antioxidant 702 BIS(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)METHANE GALVINOXYL PRECURSOR IONOX(R) 220 IONOX(R) 220 AH ETHANOX(R) 702 ANTIOXIDANT 4,4'-DIHYDROXY-3,3',5,5'-TETRA-TERT-BUTYLDIPHENYLMETHANE 4,4'-METHYLENEBIS(2,6-DI-TERT-BUTYLPHENOL) 3,3',5,5'-TETRA-TERT-BUTYL-4,4'-DIHYDROXYDIPHENYLMETHANE 4,4´ -Methylenebis(2,6-di-tert-butylphenol) 4,4'-Methylenebis(2,6-di-tert-butylphenol) TIMTEC-BB SBB007948 RARECHEM AQ BD 0024 RALOX(R) 02 S Antioxidant 728 Tetra-tert-butylbisphenol F 2,6-ditert-butyl-4-(3,5-ditert-butyl-4-hydroxy-benzyl)phenol 2,6-ditert-butyl-4-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]phenol 2,6-ditert-butyl-4-[(3,5-ditert-butyl-4-hydroxy-phenyl)methyl]phenol 4.4'-Methylene bis-(2.6-di-tert-butylphenol) 3g [118-82-1] 4,4zzhlxy-Methylenebis(2,6-di-tert-butylphenol) 4,4-METHYLENEBIS(2,6-DITERTIARYBUTYLPHENOL) 4, 4'-Methylen-bis(2,6-di-tert.-butylphenol) 4,4''-DIHYDROXY-3,3,5,5''-TETRA-TERT-BUTYLDIPHENYLMETHANE 98+% 2,2’,6,6’-tetra-tert-butyl-4,4’-methylenediphenol 4,4’-methylenebis(2,6-bis(1,1-dimethylethyl)-pheno 4,4’-methylenebis(2,6-bis(1,1-dimethylethyl)phenol) 4,4’-methylenebis(2,6-di-t-butylphenol) 4,4’-methylenebis(2,6-di-tert-butyl-pheno 4,4’-methylenebis[2,6-bis(1,1-dimethylethyl)-pheno 4,4’-methylenebis[2,6-bis(1,1-dimethylethyl)-Phenol Ethyl 702 ethyl702 Etil 702 etil702 Ionox 220 Ionox 220 Antioxidant ionox220 ionox220antioxidant L 3MB1 l3mb1 LZ-MB 1