(1S)-(+)-Camphor-10-sulphonic acid
- CAS No.
- 3144-16-9
- Chemical Name:
- (1S)-(+)-Camphor-10-sulphonic acid
- Synonyms
- CSA;CaMsylate;MOT;D-CAMPHOR-10-SULFONIC ACID;camphersulfosaeure;camphorsulfonicacid;D-CAMPHORSULPHONIC ACID;D-10-CAMPHORSULFONIC ACID;D(-)-CAMPHORSULFONIC ACID;MOT2
- CBNumber:
- CB0395928
- Molecular Formula:
- C10H16O4S
- Molecular Weight:
- 232.3
- MDL Number:
- MFCD00064157
- MOL File:
- 3144-16-9.mol
- MSDS File:
- SDS
Melting point | 196-200 °C (dec.)(lit.) |
---|---|
alpha | 22 º (589nm, c=20, H2O 25 ºC) |
Boiling point | 344.46°C (rough estimate) |
Density | 1.2981 (rough estimate) |
refractive index | 21.5 ° (C=5, H2O) |
storage temp. | Store below +30°C. |
solubility | Exhibit moderate solubility in HCCl. |
pka | 1.17±0.50(Predicted) |
form | Crystalline Powder |
color | White to off-white |
PH | 0.3 (200g/l, H2O) |
optical activity | [α]20/D +21.5±1°, c = 10% in H2O |
Water Solubility | SOLUBLE |
Sensitive | Hygroscopic |
Merck | 14,1734 |
BRN | 2809675 |
Stability | Stable. Protect from moisture. Incompatible with strong oxidizing agents, strong bases. |
InChIKey | MIOPJNTWMNEORI-GMSGAONNSA-N |
CAS DataBase Reference | 3144-16-9(CAS DataBase Reference) |
FDA UNII | 9TLZ01S15L |
EPA Substance Registry System | Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)- (3144-16-9) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H290-H314 | |||||||||
Precautionary statements | P234-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 34 | |||||||||
Safety Statements | 26-36/37/39-45-25-27 | |||||||||
RIDADR | UN 3261 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | ED1550000 | |||||||||
F | 3-10 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29147090 | |||||||||
NFPA 704 |
|
(1S)-(+)-Camphor-10-sulphonic acid price More Price(42)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | SRP5102 | Mortalin (47-end), GST tagged human recombinant, expressed in baculovirus infected Sf9 cells, ≥70% (SDS-PAGE), buffered aqueous glycerol solution | 753517-83-8 | 50μG | $360 | 2024-03-01 | Buy |
Sigma-Aldrich | 21360 | (+)-Camphor-10-sulfonic acid purum, ≥98.0% (T) | 3144-16-9 | 100g | $55.3 | 2024-03-01 | Buy |
Sigma-Aldrich | 8.22311 | (1S)-(+)-Camphor-10-sulfonic acid for resolution of racemates for synthesis | 3144-16-9 | 100g | $56.7 | 2024-03-01 | Buy |
Sigma-Aldrich | 21360 | (+)-Camphor-10-sulfonic acid purum, ≥98.0% (T) | 3144-16-9 | 500g | $125 | 2024-03-01 | Buy |
Sigma-Aldrich | 1087520 | (+)-Camphor-10-sulfonic acid United States Pharmacopeia (USP) Reference Standard | 3144-16-9 | 100mg | $472 | 2024-03-01 | Buy |
(1S)-(+)-Camphor-10-sulphonic acid Chemical Properties,Uses,Production
Synthesis
(1S)-(+)-Camphor-10-sulphonic acid can be obtained from natural camphor by brominated sulfonation .
Chemical Properties
white to light beige powder
Uses
(1S)-(+)-Camphor-10-sulfonic acid is used as stabilizer. (+)-(1S)-camphor-10-sulfonic acid being a very effective resolving agent. . Chiral polyaniline(PANI) nanofibers were synthesized via facilely potentiostatic electropolymerization method without template in the presence of(1S)-(+)camphor-10-sulfonic acid(D-CSA) or(1R)-(-)camphor-10-sulfonic acid(L-CSA) as the dopant. Synthesis of QUATs derived from (1S)-(+)camphor-10-sulfonic acid.
Uses
Used as a resolving agent, and as a catalyst for coupling dipeptides.
Definition
ChEBI: (S)-camphorsulfonic acid is the S enantiomer of camphorsulfonic acid. It is a conjugate acid of a (S)-camphorsulfonate. It is an enantiomer of a (R)-camphorsulfonic acid.
Purification Methods
Crystallise the acid from ethyl acetate and dry it under vacuum (deliquescent). [Loudon J Chem Soc 823 1933, Komppa J Prakt Chem 162 19 1943, Beilstein 11 IV 642.] See above for RS-isomer.
(1S)-(+)-Camphor-10-sulphonic acid Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12446 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5873 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5886 | 58 |
Hebei Kingfiner Technology Development Co.Ltd | +86-15532196582 +86-15373005021 | lisa@kingfinertech.com | China | 2990 | 58 |
Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | Mandy@hangyubiotech.com | China | 10991 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20291 | 58 |
airuikechemical co., ltd. | +undefined86-15315557071 | sales02@sdzhonghuimaterial.com | China | 983 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21667 | 55 |
Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
Related articles
- Synthesis of m-toluidine-aniline chirality copolymers induced by D-camphorsulfonic acid
- Chiral structures exist widely in biological macromolecules and play a significant role in the living system, such as right-ha....
- Nov 20,2019
View Lastest Price from (1S)-(+)-Camphor-10-sulphonic acid manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-09-23 | D-Camphorsulfonic Acid
3144-16-9
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | ||
2024-09-23 | d-camphorsulfonic acid
3144-16-9
|
US $0.00-0.00 / Kg | 1Kg | 99.9% | 200tons | airuikechemical co., ltd. | ||
2024-08-30 | D-Camphorsulfonic acid
3144-16-9
|
US $33.00 / KG | 1KG | 99% | 10000T | Baoji Guokang Bio-Technology Co., Ltd. |
- D-Camphorsulfonic Acid
3144-16-9
- US $5.00-2.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
- d-camphorsulfonic acid
3144-16-9
- US $0.00-0.00 / Kg
- 99.9%
- airuikechemical co., ltd.
- D-Camphorsulfonic acid
3144-16-9
- US $33.00 / KG
- 99%
- Baoji Guokang Bio-Technology Co., Ltd.