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Methyl trifluoroacetate

CAS No.
431-47-0
Chemical Name:
Methyl trifluoroacetate
Synonyms
Methyl 2,2,2-trifluoroacetate;TFAME;Methyl trifluoroacet;Methyltrifluoracetat;Mthyl trifluoroacetate;METHYL TRIFLUOROACETATE;Methyletrifluoroacetate;Methyl perfluoroacetate;Methyltrifluoroacetate99%;Methyltrifluoroacetate,97%
CBNumber:
CB0737399
Molecular Formula:
C3H3F3O2
Molecular Weight:
128.05
MDL Number:
MFCD00000417
MOL File:
431-47-0.mol
MSDS File:
SDS
Last updated:2024-04-08 17:36:13

Methyl trifluoroacetate Properties

Melting point -78 °C
Boiling point 43-43.5 °C (lit.)
Density 1.273 g/mL at 25 °C (lit.)
vapor pressure 5.77 psi ( 20 °C)
refractive index n20/D 1.291(lit.)
Flash point 19 °F
storage temp. Inert atmosphere,2-8°C
solubility 8g/l
form Liquid
Specific Gravity 1.273
color Clear colorless
PH 7 (8g/l, H2O, 20℃)
explosive limit 6.1-24.8%(V)
Water Solubility 8 g/L
Sensitive Moisture Sensitive
BRN 1756070
Dielectric constant 11.460000000000001
Stability Volatile
LogP 0.6
CAS DataBase Reference 431-47-0(CAS DataBase Reference)
NIST Chemistry Reference CF3C(O)OCH3(431-47-0)
EPA Substance Registry System Acetic acid, trifluoro-, methyl ester (431-47-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05
Signal word  Danger
Hazard statements  H225-H314
Precautionary statements  P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  F,C
Risk Statements  11-34
Safety Statements  16-26-36/37/39-45
RIDADR  UN 2924 3/PG 2
WGK Germany  1
19
Hazard Note  Flammable/Corrosive
TSCA  T
HazardClass  3
PackingGroup  II
HS Code  29159080
NFPA 704
3
3 0

Methyl trifluoroacetate price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 249831 Methyl trifluoroacetate 99% 431-47-0 25g $51.6 2024-03-01 Buy
Sigma-Aldrich 249831 Methyl trifluoroacetate 99% 431-47-0 100g $165 2024-03-01 Buy
TCI Chemical T0680 Methyl Trifluoroacetate >98.0%(GC) 431-47-0 25g $19 2024-03-01 Buy
TCI Chemical T0680 Methyl Trifluoroacetate >98.0%(GC) 431-47-0 500g $126 2021-12-16 Buy
Alfa Aesar A17338 Methyl trifluoroacetate, 98+% 431-47-0 50g $61.65 2024-03-01 Buy
Product number Packaging Price Buy
249831 25g $51.6 Buy
249831 100g $165 Buy
T0680 25g $19 Buy
T0680 500g $126 Buy
A17338 50g $61.65 Buy

Methyl trifluoroacetate Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

Methyl trifluoroacetate has been used as reagent for trifluoroacetylation of amines and amino acids.

Synthesis Reference(s)

Journal of the American Chemical Society, 113, p. 700, 1991 DOI: 10.1021/ja00002a063

General Description

Methyl trifluoroacetate along with cesium fluoride or cesium chloride and CuI constitutes a valuable trifluoromethylating reagent for substituting aromatic (or heteroaromatic) iodides and bromides. Adsorption of methyl trifluoroacetate on amorphous silica has been investigated. Fragmentation mechanism of generation of metastable ions from methyl trifluoroacetate has been investigated by mass analyzed ion kinetic energy spectra and ab initio molecular orbital calculations.

Flammability and Explosibility

Flammable

67-56-1
354-34-7
431-47-0
Synthesis of Methyl trifluoroacetate from Methanol and Perfluoroacetyl fluoride
Global( 332)Suppliers
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Hebei Yanxi Chemical Co., Ltd.
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View Lastest Price from Methyl trifluoroacetate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
methyl trifluoroacetate pictures 2024-04-08 methyl trifluoroacetate
431-47-0
US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
Methyl trifluoroacetate pictures 2023-09-04 Methyl trifluoroacetate
431-47-0
US $30.00 / KG 1KG 0.99 25MT/MON Hebei Yanxi Chemical Co., Ltd.
Methyl trifluoroacetate pictures 2023-07-31 Methyl trifluoroacetate
431-47-0
US $10.00 / kg 10kg 99% 20tons Hebei Linwo New Material Technology Co., LTD
Methyl trifluoroacet Methyl trifluoroacetate, 99% 25ML METHYL TRIFLUOROACETATE FOR SYNTHESIS Trifluoroacetic acid methyl ester, Methyl 2,2,2-trifluoroethanoate Methyl trifluoroacetate (TFAM) Methyletrifluoroacetate METHYL TRIFLUOROACETATE Acetic acid, trifluoro-, methyl ester trifluoro-aceticacimethylester TFAME Methyl trifluoroacetate 99% 2,2,2-TRIFLOUROMETHYLACETATE(TFAMT) Methyltrifluoroacetate99% Methyltrifluoracetat Mthyl trifluoroacetate Methyl trifluoroacetate, 98+% Methyl perfluoroacetate Methyltrifluoroacetate,97% Trifluoroacetic Acid Methyl Ether TRIFLUOROACETIC ACID METHYL ESTER Methyl Trifluoroacetate > Acetic acid, 2,2,2-trifluoro-, methyl ester TIANFU CHEM---Methyl trifluoroacetate Methyl 2,2,2-trifluoroacetate 431-47-0 CF3CO2CH3 C3H3F3O2 CF3COOCH3 Reagents for Oligosaccharide Synthesis Building Blocks Carbonyl Compounds C2 to C5 Organic Building Blocks Esters Biochemistry Reagents for Oligosaccharide Synthesis C2 to C5 Carbonyl Compounds Esters PHARMACEUTICAL INTERMEDIATES john's