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6-Bromo-1-hexene

6-Bromo-1-hexene structure

CAS No.: 2695-47-8

Chemical Name:: 6-Bromo-1-hexene

Synonyms: 6-BROMOHEX-1-ENE;Bromohexene;6-Bromohexene;6-bromo-1-hexen;-BroMo-1-hexene;1-Bromohex-5-ene;1-Bromo-5-hexene;6-BROMO-1-HEXENE;1-Hexene,6-bromo-;Bromo-1-hexene,6-

CBNumber:: CB1229923

Molecular Formula:: C6H11Br

Molecular Weight:: 163.06

MDL Number:: MFCD00000269

MOL File:: 2695-47-8.mol

MSDS File:: SDS

Last updated:2026-01-13 11:13:45

Product description	Number	Pack Size	Price
6-Bromo-1-hexene 95%	247219	1g	$27.5
6-Bromo-1-hexene 95%	247219	5g	$126
6-Bromo-1-hexene >95.0%(GC)	B2106	5g	$54
6-Bromo-1-hexene >95.0%(GC)	B2106	25g	$185
6-Bromohexene	B681930	1g	$45
More product size

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6-Bromo-1-hexene Properties

Melting point	-102.35°C (estimate)
Boiling point	47-51 °C/16 mmHg (lit.)
Density	1.22 g/mL at 25 °C (lit.)
refractive index	n20/D 1.4652(lit.)
Flash point	126 °F
storage temp.	Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Liquid
Specific Gravity	1.217
color	Clear slightly yellow
Water Solubility	Not miscible in water.
BRN	506203
Stability	Stable. Incompatible with strong oxidizing agents, strong bases. Flammable.
InChI	1S/C6H11Br/c1-2-3-4-5-6-7/h2H,1,3-6H2
InChIKey	RIMXEJYJXDBLIE-UHFFFAOYSA-N
SMILES	BrCCCCC=C
CAS DataBase Reference	2695-47-8(CAS DataBase Reference)
NIST Chemistry Reference	1-Hexene, 6-bromo-(2695-47-8)
EPA Substance Registry System	1-Hexene, 6-bromo- (2695-47-8)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS07,GHS08

Signal word

Danger

Hazard statements

H226-H315-H319-H335-H360D

Precautionary statements

P202-P210-P233-P303+P361+P353-P305+P351+P338-P308+P313

target organs

Respiratory system

PPE

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Codes

Xi,F,T

Risk Statements

10-36/37/38-61

Safety Statements

26-36-37/39-16-45-53

RIDADR

UN 1993 3/PG 3

WGK Germany

Hazard Note

Flammable/Irritant

TSCA

TSCA listed

HazardClass

3.2

PackingGroup

III

HS Code

29039990

Storage Class

3 - Flammable liquids

Hazard Classifications

Eye Irrit. 2
Flam. Liq. 3
Repr. 1B
Skin Irrit. 2
STOT SE 3

Limited Quantities

5.0 L (1.3 gallons) (liquid)

Excepted Quantities

Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

NFPA 704

	2
2		0

6-Bromo-1-hexene price More Price(28)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	247219	6-Bromo-1-hexene 95%	2695-47-8	1g	$27.5	2026-04-30	Buy
Sigma-Aldrich	247219	6-Bromo-1-hexene 95%	2695-47-8	5g	$126	2026-04-30	Buy
TCI Chemical	B2106	6-Bromo-1-hexene >95.0%(GC)	2695-47-8	5g	$54	2026-04-30	Buy
TCI Chemical	B2106	6-Bromo-1-hexene >95.0%(GC)	2695-47-8	25g	$185	2026-04-30	Buy
TRC	B681930	6-Bromohexene	2695-47-8	1g	$45	2021-12-16	Buy

Product number	Packaging	Price	Buy
247219	1g	$27.5	Buy
247219	5g	$126	Buy
B2106	5g	$54	Buy
B2106	25g	$185	Buy
B681930	1g	$45	Buy

6-Bromo-1-hexene Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Uses

6-Bromo-1-hexene was used in the preparation of epoxide, 6-bromo-1,2-epoxyhexane. It was also used in a simple, direct preparation of 4-alkenylbenzonitriles via anionic reduced forms of terephthalonitrile in liquid ammonia.

Synthesis Reference(s)

Synthesis, p. 885, 1984 DOI: 10.1055/s-1984-31010

General Description

Reaction of 6-bromo-1-hexene with Mg to form Grignard compounds has been investigated. The thermal chemistry of 6-bromo-1-hexene on Ni (100) surface has been studied under ultrahigh vacuum conditions by X-ray photoelectron spectroscopy and temperature-programmed desorption.

Synthesis

629-03-8

2695-47-8

General method: To a stirred solution of 1,6-dibromohexane (1 eq.) in anhydrous tetrahydrofuran (THF, 0.1 M) was added potassium tert-butoxide (tert-BuOK, 1.15 eq.) in batches over a period of 30 min under argon protection. The reaction mixture was stirred under reflux conditions for 16 h before being cooled to room temperature and subsequently quenched with deionized water. The resulting mixture was diluted with diethyl ether and the organic and aqueous layers were separated. The aqueous layer was extracted several times with diethyl ether, all organic layers were combined, washed with saturated brine, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The crude product was purified by silica gel fast column chromatography with petroleum ether as eluent to obtain the target product 6-bromo-1-hexene. 2.3.1 Synthesis of 6-bromo-1-hexene 6-Bromo-1-hexene was synthesized from 1,6-dibromohexane (8.1 g, 33.6 mmol) according to the general method described above. Yield: 4.3 g (79% yield) as a colorless oil. Thin layer chromatography (TLC) Rf value: 0.71 (100% hexane unfolding, potassium permanganate solution color development). 1H NMR (CDCl3, 500MHz, ppm): δ5.79 (ddt, J = 17.0, 10.2, 6.7Hz, 1H), 5.02 (ddd, J = 17.1, 3.5, 1.6Hz, 1H), 4.97 (ddt, J = 10.2, 2.2, 1.2 Hz, 1H), 3.41 (t, J = 6.8 Hz , 2H), 2.13 - 2.05 (m, 2H), 1.92 - 1.83 (m, 2H), 1.54 (tt, J = 9.3, 6.6 Hz, 2H). 13C NMR (CDCl3, 126MHz, ppm): δ 138.27, 115.14, 33.87, 32.95, 32.29, 27.48.

References

[1] Bioorganic and Medicinal Chemistry, 2018, vol. 26, # 14, p. 4047 - 4057
[2] Synthetic Communications, 2001, vol. 31, # 9, p. 1367 - 1371
[3] Synthesis, 1984, # 10, p. 885
[4] Journal of the American Chemical Society, 1992, vol. 114, # 8, p. 3044 - 3051
[5] Chemistry - A European Journal, 2013, vol. 19, # 3, p. 1002 - 1012

6-Bromo-1-hexene synthesis

Synthesis of 6-Bromo-1-hexene from 1,6-Dibromohexane

6-Bromo-1-hexene Preparation Products And Raw materials

Raw materials

5-Hexen-1-ol 1,6-Dibromohexane Recombinant Human Telomerase Tetrahydrofuran Potassium

Preparation Products

7-METHYL-1,6-OCTADIENE 7-OCTENOIC ACID 6-Heptenoic acid Hex-5-enylmagnesium bromide 0.5M in THF N-Methyl-1-amino-hex-5-ene

6-Bromo-1-hexene Suppliers

Global( 349)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8738	58
Hebei Chuanghai Biotechnology Co., Ltd	+8615531151365	mina@chuanghaibio.com	China	18126	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29640	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29819	58
Zhejiang ZETian Fine Chemicals Co. LTD	+8618957127338	stella@zetchem.com	China	2994	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10404	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
SIMAGCHEM CORP	+86-5922680277 +86-13806087780	sale@simagchem.com	China	17346	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58
Alfa Chemistry		info@alfa-chemistry.com	United States	2344	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	58
Hebei Chuanghai Biotechnology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
career henan chemical co	58
Zhejiang ZETian Fine Chemicals Co. LTD	58
Shenzhen Nexconn Pharmatechs Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
SIMAGCHEM CORP	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Alfa Chemistry	58

View Lastest Price from 6-Bromo-1-hexene manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-03-20	6-Bromo-1-hexene 2695-47-8	US $0.00-0.00 / KG	1KG	99%	20 mt	Hebei Chuanghai Biotechnology Co., Ltd
2025-06-27	6-Bromo-1-hexene 2695-47-8	US $0.00 / KG	1KG	99%	500000kg	Hebei Chuanghai Biotechnology Co., Ltd
2021-08-12	6-Bromo-1-hexene 2695-47-8	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd

6-Bromo-1-hexene
2695-47-8
US $0.00-0.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

6-Bromo-1-hexene
2695-47-8
US $0.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

6-Bromo-1-hexene
2695-47-8
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

6-Bromo-1-hexene Spectrum

6-Bromo-1-hexene(2695-47-8)¹HNMR 6-Bromo-1-hexene(2695-47-8)¹³CNMR 6-Bromo-1-hexene(2695-47-8)IR 6-Bromo-1-hexene(2695-47-8)FT-IR 6-Bromo-1-hexene(2695-47-8)Raman

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