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Allyl glycidyl ether

Description Preparation Uses
Allyl glycidyl ether
Allyl glycidyl ether structure
CAS No.
106-92-3
Chemical Name:
Allyl glycidyl ether
Synonyms
AGE;M 560;allyl;NCI-C56666;Ageflex AGE;Sipomer AGE;Allylglycidaether;Allylglycide ether;ALLYLGLYCIDOLETHER;Ally glycidyl ether
CBNumber:
CB3852688
Molecular Formula:
C6H10O2
Formula Weight:
114.14
MOL File:
106-92-3.mol

Allyl glycidyl ether Properties

Melting point:
-100 °C
Boiling point:
154 °C(lit.)
Density 
0.962 g/mL at 25 °C(lit.)
vapor density 
3.9 (vs air)
vapor pressure 
4.7 mm Hg ( 25 °C)
refractive index 
n20/D 1.433(lit.)
Flash point:
135 °F
storage temp. 
Refrigerator (+4°C)
solubility 
50 g/L (20°C)
form 
Liquid
color 
Clear colorless
Water Solubility 
50 g/L (20 ºC)
BRN 
105871
Henry's Law Constant
(x 10-6 atm?m3/mol): 3.83 at 20 °C (approximate - calculated from water solubility and vapor pressure)
Exposure limits
NIOSH REL: TWA 5 ppm (22 mg/m3), STEL 10 ppm (44 mg/m3), IDLH 50 ppm; OSHA PEL: ceiling 10 ppm; ACGIH TLV: TWA 5 ppm, STEL 10 ppm.
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, acids, bases. May form peroxides in storage if in contact with air.
InChIKey
LSWYGACWGAICNM-UHFFFAOYSA-N
CAS DataBase Reference
106-92-3(CAS DataBase Reference)
NIST Chemistry Reference
Oxirane, [(2-propenyloxy)methyl]-(106-92-3)
EPA Substance Registry System
Oxirane, [(2-propenyloxy)methyl]-(106-92-3)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS05,GHS07,GHS08,GHS06
Signal word  Danger
Hazard statements  H331-H361-H370-H372-H313-H402-H226-H302-H315-H317-H318-H332-H335-H341-H351-H361f-H412
Precautionary statements  P261-P273-P280-P305+P351+P338-P303+P361+P353-P405-P501a-P201-P202-P210-P233-P240-P241+P242+P243-P260-P264-P270-P271-P272-P301+P312+P330-P302+P352+P333+P313+P363-P304+P340+P311-P305+P351+P338+P310-P307+P311-P403+P233
Hazard Codes  Xn
Risk Statements  10-20/22-37/38-40-41-43-52/53-62-68
Safety Statements  24/25-26-36/37/39-61
RIDADR  UN 2219 3/PG 3
WGK Germany  3
RTECS  RR0875000
Autoignition Temperature 264 °C
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29109000
Toxicity LD50 orally in Rabbit: 922 mg/kg LD50 dermal Rabbit 2550 mg/kg

Allyl glycidyl ether price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich A32608 Allyl glycidyl ether ≥99% 106-92-3 100ml $45.6 2018-11-13 Buy
Sigma-Aldrich A32608 Allyl glycidyl ether ≥99% 106-92-3 500ml $89.1 2018-11-13 Buy
TCI Chemical A0221 Allyl Glycidyl Ether >99.0%(GC) 106-92-3 25mL $21 2018-11-22 Buy
TCI Chemical A0221 Allyl Glycidyl Ether >99.0%(GC) 106-92-3 500mL $42 2018-11-22 Buy
Alfa Aesar L11634 Allyl glycidyl ether, 97% 106-92-3 500g $77.6 2018-11-13 Buy

Allyl glycidyl ether Chemical Properties,Uses,Production

Description

Allyl glycidyl ether is a colorless liquid clycidyl ether with a pleasant odor. The compound is insoluble in water and less dense than water, therefore can easily float on water. When ingested or inhaled, allyl glycidyl ether is mildly toxic. It is not classified as a human carcinogen.

Preparation

In a condensation reaction, epichlorohydrin and allyl alcohol are used in the synthesis of allyl glycidyl ether.

Uses

Allyl glycidyl ether is utilized in sealants and adhesives. It is also used in the production of polyvinylcaprolactam.

Chemical Properties

colourless liquid

Chemical Properties

Allyl glycidyl ether is a stable, colorless, flammable liquid with a pleasant odor. It is incompatible with strong oxidizers agents, acids, and bases. It may form peroxides in storage if in contact with air.

Chemical Properties

Allyl glycidyl ether is a colorless liquid with a strong, sweet odor

Physical properties

Clear, colorless, watery, combustible liquid with a strong, pleasant odor. An odor threshold value of 47 mg/m3 was reported (quoted, Verschueren, 1983).

Uses

Resin intermediate, stabilizer of chlorinated compounds, vinyl resins, and rubber.

General Description

A colorless liquid with a pleasant odor. Flash point 135°F. Slightly less dense than water and insoluble in water. Hence floats on water. Poisonous by ingestion and mildly toxic by inhalation and skin contact. Very irritating to skin and eyes. Used to make other chemicals.

Air & Water Reactions

Flammable. Insoluble in water.

Reactivity Profile

Allyl glycidyl ether reacts violently with oxidizing agents. Can form peroxides. Polymerizes readily [Handling Chemicals Safely 1980. p.128].

Hazard

Skin, eye, and upper respiratory tract irri- tant, and dermatitis. Questionable carcinogen.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Health Hazard

Occupational workers exposed to allyl glycidyl ether develop severe symptoms of poisoning that include, but are not limited to, irritation of the eyes, redness, pain, blurred vision, deep skin burns, respiratory system; causes damage of the mucous membranes, dermatitis, burning sensation, shortness of breath, headache, drowsiness, dullness, nausea, vomiting, pulmonary edema, narcosis, possible hematopoietic and reproductive effects. Acute exposure may cause CNS depression. The major target organs include the eyes, skin, respiratory system, blood, and the reproductive system.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Contact allergens

Allyl glycidyl ether is a monoglycidyl derivative, used as a reactive epoxy diluent for epoxy resins. As an impurity, it was considered to be the sensitizing agent in a plastic industry worker allergic to 3-glycidyloxypropyl trimethoxysilane, an epoxy silane compound used as a fixing additive in silicone and polyurethane

Safety Profile

Confirmed animal carcinogen. Poison by ingestion. Moderately toxic by inhalation and skin contact. Mutation data reported. A severe skin and eye irritant. Can cause central nervous system depression and pulmonary edema. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical.When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS

Potential Exposure

Used as a solvent and emulsifier; making epoxy resins, chlorinated compounds; and rubber.

Environmental Fate

Biological. Bridié et al. (1979) reported BOD and COD values of 0.06 and 1.99 g/g using filtered effluent from a biological sanitary waste treatment plant. These values were determined using a standard dilution method at 20 °C for a period of 5 d. The ThOD for allyl glycidyl ether is 2.11 g/g.
Chemical/Physical. Hydrolysis of the epoxide ring is likely forming 1-allyloxy-2,3- dihydroxypropane (Perez and Osterman-Golkar, 2000).

storage

Allyl glycidyl ether should be kept stored in a cool, dark, fi reproof area separated from strong oxidants, strong bases, and strong acids.

Shipping

UN2219 Allyl glycidal ether, Hazard Class: 3; Labels: 3-Flammable liquid

Incompatibilities

May form explosive mixture with air. Contact with acids or bases may cause explosive polymerization. Contact with oxidizers or amines may cause fire and explosions.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Precautions

During use and/or handling of allyl glycidyl ether, occupational workers should not be near open flames, sparks, or smoking areas. For temperatures above 48°C, use a closedsystem ventilation and explosion-proof electrical equipment. Workers should use protective gloves, protective clothing, and avoid all contact.

Allyl glycidyl ether Preparation Products And Raw materials

Raw materials

Preparation Products


Allyl glycidyl ether Suppliers

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Allyl glycidyl ether Spectrum


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