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Titanium ethoxide

CAS No.
3087-36-3
Chemical Name:
Titanium ethoxide
Synonyms
TITANIUM(IV) ETHOXIDE;TITANIUM TETRAETHOXIDE;Tetraethoxy titanium;TETRAETHYL TITANATE;ETHYL ORTHOTITANATE;TETRAETHYL ORTHOTITANATE;TitaniuM tetraethanolate;VERTEC(TM) ET;ETHYL TITANATE;TITANIUM ETHOXIDE
CBNumber:
CB5152902
Molecular Formula:
C8H20O4Ti
Molecular Weight:
228.11
MDL Number:
MFCD00009071
MOL File:
3087-36-3.mol
MSDS File:
SDS
Last updated:2023-09-15 15:02:29

Titanium ethoxide Properties

Melting point 54°C
Boiling point 150-152 °C10 mm Hg(lit.)
Density 1.088 g/mL at 25 °C(lit.)
vapor pressure 57.26hPa at 19.6℃
refractive index n20/D 1.505(lit.)
Flash point 84 °F
storage temp. 2-8°C
solubility Soluble in organic solvents.
form Liquid
color Pale yellow
Specific Gravity 1.107 (20℃)
Water Solubility reacts
Sensitive Moisture Sensitive
BRN 3678992
Exposure limits ACGIH: TWA 200 ppm; STEL 400 ppm
OSHA: TWA 400 ppm(980 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3)
Stability Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture.
InChIKey JMXKSZRRTHPKDL-UHFFFAOYSA-N
LogP -0.3 at 25℃
CAS DataBase Reference 3087-36-3(CAS DataBase Reference)
FDA UNII 98L0R4158B
NIST Chemistry Reference Ti(OEt)4(3087-36-3)
EPA Substance Registry System Ethanol, titanium(4+) salt (3087-36-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H319
Precautionary statements  P210-P305+P351+P338
Hazard Codes  Xi
Risk Statements  10-36/37/38-67
Safety Statements  26-37/39-16
RIDADR  UN 1993 3/PG 3
WGK Germany  3
3-10-21
TSCA  Yes
HazardClass  4.1
PackingGroup  III
HS Code  29051900
NFPA 704
2
2 0

Titanium ethoxide price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.21083 Tetraethyl orthotitanate for synthesis 3087-36-3 250ML $111 2024-03-01 Buy
Sigma-Aldrich 8.21083 Tetraethyl orthotitanate for synthesis 3087-36-3 1L $237 2024-03-01 Buy
Sigma-Aldrich 244759 Titanium(IV) ethoxide technical grade 3087-36-3 50g $92.3 2024-03-01 Buy
Sigma-Aldrich 244759 Titanium(IV) ethoxide technical grade 3087-36-3 250g $329 2024-03-01 Buy
TCI Chemical T0967 Tetraethyl Orthotitanate 3087-36-3 25mL $21 2024-03-01 Buy
Product number Packaging Price Buy
8.21083 250ML $111 Buy
8.21083 1L $237 Buy
244759 50g $92.3 Buy
244759 250g $329 Buy
T0967 25mL $21 Buy

Titanium ethoxide Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Uses

Titanium(IV) ethoxide can be used:

  • As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
  • As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
  • As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Uses

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :

  • in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
  • spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
  • by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

Uses

Titanium(IV) ethoxide is used in organic synthesis and material science. It is involved in the synthesis of anti-perspirants and antifungal agents. Furthermore, it is used to prepare carbon films in association with silicon dioxide. It is also used as a precursor for the synthesis of Ti4+ ions titanium nanoparticles by various methods.

Application

Titanium(IV) ethoxide can be used:
As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Flammability and Explosibility

Flammable

Materials Uses

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

Global( 244)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12453 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5993 58
Dalian Richfortune Chemicals Co., Ltd
0411-84820922 8613904096939 sales@richfortunechem.com China 303 57
Henan Tianfu Chemical Co.,Ltd.
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Shanghai Time Chemicals CO., Ltd.
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86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Shandong chuangyingchemical Co., Ltd.
18853181302 sale@chuangyingchem.com CHINA 5909 58

View Lastest Price from Titanium ethoxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Titanium(IV) ethoxide,TiO2 33.2% pictures 2024-04-19 Titanium(IV) ethoxide,TiO2 33.2%
3087-36-3
US $20.00 / KG 1KG 99% 300 Tons/ year Speranza Chemical Co., Ltd.
Titanium(IV) ethoxide  pictures 2024-04-09 Titanium(IV) ethoxide
3087-36-3
US $15.00 / KG 1KG 99% 6000KG Shandong Luning Pharmaceutical Co., Ltd.
Titanium ethoxide pictures 2023-09-15 Titanium ethoxide
3087-36-3
US $30.00-1.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
TITANIUM(IV) ETHOXIDE, TECH. Titanium ethoxide, contains 10-15% Titaniumisopropoxide Titanium(IV) ethoxide, 33-35% TiO2 Titanium(IV) ethoxide, tech., contains 5-15% isopropanol, 85% TITANIUM TETRAETHOXIDE TECHNICAL Titanium (IV) ethoxide (tetraethyl orthotitanate) Titanium(IV)ethoxide(99.99%-Ti)PURATREM Titanium(IV)ethoxide(contains5-15%isopropanol) titanium(iv) ethoxide, vertec ethanol, titanium salt Ethanol,titaniumsalt TITANIUM(IV) ETHOXIDE: 99.99%, PURATREM Titanium(IV) ethoxide, VERTEC(R) ET, 99+% TITANIUM ETHOXIDE (99%) Titanium (IV) ethoxide, TiO2 33% min Titanium(IV) ethoxide, VERTEC ET, 99+% ETHYL TITANATE ETHYL TITANATE(IV) ORTHOTITANIC ACID TETRAETHYL ESTER VERTEC(TM) ET TITANIUM TETRAETHYLATE TITANIC ACID TETRAETHYL ESTER TITANIUM ETHOXIDE TITANIUM ETHYLATE TITANIUM (IV) TETRAETHOXIDE titanium(4+) ethanolate Ethanol, titanium(4+) salt Ethanol,titanium(4+)salt ethanol,titanium(4++)salt TITANIUM(IV) ETHOXIDE APPROX. 80% Tetraethyl orthotitanate, Tetraethyl titanate Tetraethyl orthotitanate for synthesis Titanium (IV) ethoxide, VERTEC? ET Titanium(iv) ethoxide, 85%, contains 5-15% isopropanol, tech. Titanium(IV)tetraethanolate Titanium(IV) ethoxide,85%,tech., contains 5-15% isopropanol Titanium(IV) ethoxide, TiO2 33% min Titanium(IV) ethoxide ,98% Titanium(iv) ethoxide, 33-35% TiO2 ,95% TitaniuM(IV) ethoxide, 33-35% TiO2 250GR TitaniuM(IV) ethoxide, 33-35% TiO2 50GR TitaniuM(IV) ethoxide, tech., contains 5-15% isopropanol, 85% 50GR Titanium(Ⅳ) ethoxide TET TETRA ETHYL TITANATE TitaniuM(Ⅳ) ethoxide, 33 - 35% TiO2 TitaniuM (IV) Ethoxide (~80%, contain 20% Isopropoxide) Ethanol, titaniuM(4+)salt (4:1) TitaniuM(IV) ethoxide technical grade Titanate acidethyl ester four Tetra Ethyl Titanate (TET) Titanium(IV) ethanolate Titanium(IV) ethoxide,TiO2 Titanium(IV) ethoxide,TiO2 33.2% Tetraethyl Titanate Titanium(IV) Ethoxide Tetraethyl Orthotitanate (contains 35% Tetraisopropyl Orthotitanate at maximum) TITANIUM TETRAETHOXIDE, TECHNICALTITANIUM TETRAETHOXIDE, TECHNICAL TITANIUM ETHOXIDE, tech-95 Ethanolate, titanium salt (4:1)