ChemicalBook >> CAS DataBase List >>4-(N,N-Diphenylamino)benzaldehyde

4-(N,N-Diphenylamino)benzaldehyde

4-(N,N-Diphenylamino)benzaldehyde structure

CAS No.: 4181-05-9

Chemical Name:: 4-(N,N-Diphenylamino)benzaldehyde

Synonyms: 4-(DIPHENYLAMINO)BENZALDEHYDE;4-FORMYLTRIPHENYLAMINE;4-(N-phenylanilino)benzaldehyde;833249;4-DiphenyL;JACS-4181-5-9;4-(N,N-Diphenylamino;P-FORMYLTRIPHENYLAMINE;4-(diphenylamino)-benzaldehyd;4-Diphenylaminobenzaldehyde,98%

CBNumber:: CB6683056

Molecular Formula:: C19H15NO

Molecular Weight:: 273.33

MDL Number:: MFCD00145131

MOL File:: 4181-05-9.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-04-09 10:58:13

Product description	Number	Pack Size	Price
4-(Diphenylamino)benzaldehyde 97%	647209	5g	$199
4-(N,N-Diphenylamino)benzaldehyde >98.0%(GC)(N)	D2172	5g	$55
4-(N,N-Diphenylamino)benzaldehyde >98.0%(GC)(N)	D2172	25g	$194
4-(N,N-Diphenylamino)benzaldehyde	N497255	50mg	$45
4-(N,N-Diphenylamino)benzaldehyde 95+%	075564	1g	$47
More product size

Request For Quotation

4-(N,N-Diphenylamino)benzaldehyde Properties

Melting point	129-133 °C (lit.)
Boiling point	436.8±28.0 °C(Predicted)
Density	1.176±0.06 g/cm3(Predicted)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Soluble in methanol.
pka	-5.61±0.30(Predicted)
form	Solid
color	Pale yellow
Sensitive	Air Sensitive
BRN	2732795
InChI	InChI=1S/C19H15NO/c21-15-16-11-13-19(14-12-16)20(17-7-3-1-4-8-17)18-9-5-2-6-10-18/h1-15H
InChIKey	UESSERYYFWCTBU-UHFFFAOYSA-N
SMILES	C(=O)C1=CC=C(N(C2=CC=CC=C2)C2=CC=CC=C2)C=C1
CAS DataBase Reference	4181-05-9(CAS DataBase Reference)
EPA Substance Registry System	Benzaldehyde, 4-(diphenylamino)- (4181-05-9)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

target organs

Respiratory system

PPE

dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes

Xi,Xn

Risk Statements

36/37/38

Safety Statements

26-36

WGK Germany

TSCA

TSCA listed

HS Code

29223990

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

NFPA 704

	1
2		1

4-(N,N-Diphenylamino)benzaldehyde price More Price(28)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	647209	4-(Diphenylamino)benzaldehyde 97%	4181-05-9	5g	$199	2026-04-30	Buy
TCI Chemical	D2172	4-(N,N-Diphenylamino)benzaldehyde >98.0%(GC)(N)	4181-05-9	5g	$55	2026-04-30	Buy
TCI Chemical	D2172	4-(N,N-Diphenylamino)benzaldehyde >98.0%(GC)(N)	4181-05-9	25g	$194	2026-04-30	Buy
TRC	N497255	4-(N,N-Diphenylamino)benzaldehyde	4181-05-9	50mg	$45	2021-12-16	Buy
Matrix Scientific	075564	4-(N,N-Diphenylamino)benzaldehyde 95+%	4181-05-9	1g	$47	2021-12-16	Buy

Product number	Packaging	Price	Buy
647209	5g	$199	Buy
D2172	5g	$55	Buy
D2172	25g	$194	Buy
N497255	50mg	$45	Buy
075564	1g	$47	Buy

4-(N,N-Diphenylamino)benzaldehyde Chemical Properties,Uses,Production

Chemical Properties

Pale yellow powder

Chemical Properties

4-(N,N-Diphenylamino)benzaldehyde is stable in acidic solutions but unstable in basic solutions and it emits fluorescence when irradiated with UV light.

Uses

4-(N,N-Diphenylamino)benzaldehyde (DPAB) excited by visible-light could be reductively quenched by a RAFT reagent 4-cynao-4-(phenylcarbonothioylthio)pentanoic acid. Besides, DPAB as a photoredox catalyst was also successfully used in synthesis of α,ω-dithiol and α,ω-divinyl telechelic polythioether oligomers through thiol-ene click polymerization of 1,4-benzenedimethane (BDMT) and diethylene glycol divinyl ether (DEGVE)^[1].

Uses

It is used as pharmaceutical intermediate.

Synthesis

603-34-9

4181-05-9

Phosphoryl chloride (24 mL, 315 mmol) was slowly added dropwise to N,N-dimethylformamide (DMF, 30 mL) at 0 °C and the reaction mixture was stirred for 1 h keeping this temperature. Subsequently, triphenylamine (10 g, 40 mmol) was added and the reaction system was warmed to 100 °C with continuous stirring for 6 hours. After completion of the reaction, the mixture was cooled to room temperature, slowly poured into ice water and the pH was adjusted with 5% aqueous sodium hydroxide to 7. The aqueous phase was extracted with ethyl acetate and the combined organic phases were dried with anhydrous magnesium sulfate. The solvent was removed by concentration under reduced pressure to give the crude product. The crude product was purified by column chromatography using a mixed solvent of petroleum ether and dichloromethane (2:1, v/v/v) as eluent, and finally 4-diphenylaminobenzaldehyde was obtained as a white solid (5.76 g) in 52.74% yield.

References

[1] Inorganic Chemistry, 2017, vol. 56, # 5, p. 2409 - 2416
[2] Dyes and Pigments, 2014, vol. 100, # 1, p. 127 - 134
[3] Patent: US6603020, 2003, B1
[4] Patent: EP771809, 1997, A1
[5] Patent: EP1087006, 2001, A1

References

[1] Wang, Y., Liao, Q., Fan, Y., Chen, D., Ma, Y., Zhao, C., Yang, W. (2022). Surface engineering of Si wafers with tunable surface morphology and stiffness via visible light induced thiol-ene click polymerization with 4-(N,N-diphenylamino)benzaldehyde as an organocatalyst. Journal of Applied Polymer Science, 139 30. https://doi.org/10.1002/app.52677

4-(N,N-Diphenylamino)benzaldehyde synthesis

Synthesis of 4-(N,N-Diphenylamino)benzaldehyde from Dichloromethane and Triphenylamine and Acetone

4-(N,N-Diphenylamino)benzaldehyde Preparation Products And Raw materials

Raw materials

Acrylic acid Triphenylamine Dichloromethane Diphenylamine Diisobutylaluminium hydride

N,N-Dimethylformamide Triphenylphosphine Acetone

1of2

Preparation Products

N-BDAVBi , N-(4-((E)-2-(6-((E)-4-(diphenylaMino)styryl)naphtha 4-DIPHENYLAMINO-BENZONITRILE

4-(N,N-Diphenylamino)benzaldehyde Suppliers

Global( 239)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
JIAOZUO YAXIN CHEMICAL IMDUSTRY CO., LTD	+undefined13393895309	purchase@yaxinchemical.com	China	27	58
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	8736	58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	+86-13017695106 +86-13676922317	jiuyitime@fdachem.com	China	16513	58
Springchem New Material Technology Co.,Limited	+86-021-62885108 +8613917661608	info@spring-chem.com	China	2068	57
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21588	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
HaBo Hong Kong Co., Limited.	+86-25-18512596065	info@habotech.com	CHINA	933	58
Jinan Finer Chemical Co., Ltd	+86-531-88989536 +86-15508631887	sales@finerchem.com	China	2949	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569262 +86-15003564040	1056@dideu.com	China	3982	58

Supplier	Advantage
JIAOZUO YAXIN CHEMICAL IMDUSTRY CO., LTD	58
Shanghai UCHEM Inc.	58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	58
Springchem New Material Technology Co.,Limited	57
Henan Tianfu Chemical Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
HaBo Hong Kong Co., Limited.	58
Jinan Finer Chemical Co., Ltd	58
Alchem Pharmtech,Inc.	58
Shaanxi Dideu Medichem Co. Ltd	58

View Lastest Price from 4-(N,N-Diphenylamino)benzaldehyde manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-04-30	4-Formyltriphenylamine 4181-05-9	US $16.00-311.00 / g	25g	0.98	25kg	Shanghai UCHEM Inc.
2026-04-28	4-(N,N-Diphenylamino)benzaldehyde 4181-05-9	US $20.00 / g	1g	97%	200kgs	Zhengzhou Alfa Chemical Co.,Ltd
2026-04-17	4-(N,N-Diphenylamino)benzaldehyde 4181-05-9	US $2.20-8.80 / kg	1kg	99%min	100kg	ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

4-Formyltriphenylamine
4181-05-9
US $16.00-311.00 / g
0.98
Shanghai UCHEM Inc.

4-(N,N-Diphenylamino)benzaldehyde
4181-05-9
US $20.00 / g
97%
Zhengzhou Alfa Chemical Co.,Ltd

4-(N,N-Diphenylamino)benzaldehyde
4181-05-9
US $2.20-8.80 / kg
99%min
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

4-(N,N-Diphenylamino)benzaldehyde Spectrum

4-(N,N-Diphenylamino)benzaldehyde(4181-05-9)MS 4-(N,N-Diphenylamino)benzaldehyde(4181-05-9)¹HNMR 4-(N,N-Diphenylamino)benzaldehyde(4181-05-9)¹³CNMR 4-(N,N-Diphenylamino)benzaldehyde(4181-05-9)IR1 4-(N,N-Diphenylamino)benzaldehyde(4181-05-9)IR2

4181-05-9(4-(N,N-Diphenylamino)benzaldehyde)Related Search:

3,4-Dichloroaniline Phenothiazine 2,4-Difluoroaniline 2,4-Dimethoxyaniline 3,4-Dimethylbenzaldehyde

2,4-Dichloroaniline Benzaldehyde Sodium diphenylamine-4-sulfonate Diphenylamine 4-Aminoveratrole

3,4-Difluoroaniline 2,4-Dimethylbenzaldehyde DIPHENYLAMINE-4-SULFONIC ACID BARIUM SALT 2,4-Dinitroaniline TRIS(4-FORMYLPHENYL)AMINE

4-Di-p-tolylamino-benzaldehyde Triphenylamine Formaldehyde

1of4

4-(diphenylamino)-benzaldehyd 4-(N,N-DIPHENYLAMINO)BENZALDEHYDE P-N,N-DIPHENYLAMINO-BENZALDEHYDE P-FORMYLTRIPHENYLAMINE 4-(N,N-DIPHENYLAMINO)BENZALDEHYDE (P-) 98+% 4-Diphenylaminobenzaldehyde,98% 4-(N,N-Diphenylamino 4-DiphenylaMinobenzaldehyde, 98% 5GR 4-(N,N-Diphenylamino)benzaldehy de p-Formyltriphenylamine Benzaldehyde, 4-(diphenylamino)- JACS-4181-5-9 833249 4-(N,N-Diphenylamino)benzaldehyde> 4-DiphenyL 4-FORMYLTRIPHENYLAMINE 4-(N-phenylanilino)benzaldehyde 4-(N,N-Diphenylamino)benzaldehyde 95% 4-(DIPHENYLAMINO)BENZALDEHYDE 4181-05-9 4181-5-9 4181-01-3 4181-05-1 C19H15NO Organic Building Blocks Building Blocks Aldehydes C10 to C21 Carbonyl Compounds Pyrroles ,Pyrimidines Yellow crystalline powder White Powder Phenylamine Series Triphenylamine series Aromatic Aldehydes & Derivatives (substituted)