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1-Bromotetradecane

CAS No.
112-71-0
Chemical Name:
1-Bromotetradecane
Synonyms
MYRISTYL BROMIDE;NSC 83468;BROMOTETRADECANE;1-Bromtetradecan;Tetradecylbromid;TETRADECYL BROMIDE;1-BROMOTETRADECANE;1-bromo-tetradecan;1-tetradecylbromide;1-Tetradecyl bromide
CBNumber:
CB8212243
Molecular Formula:
C14H29Br
Molecular Weight:
277.28
MDL Number:
MFCD00000228
MOL File:
112-71-0.mol
MSDS File:
SDS
Last updated:2025-12-07 19:09:50
Product description Number Pack Size Price
1-Bromotetradecane 97% 195332 5ml $17.82
1-Bromotetradecane 97% 195332 500ml $104.86
1-Bromotetradecane for synthesis 8.18896 5ml $34.3
1-Bromotetradecane for synthesis 8.18896 250ML $60.7
1-Bromotetradecane >97.0%(GC) B0233 25mL $22
More product size

1-Bromotetradecane Properties

Melting point 5-6 °C(lit.)
Boiling point 175-178 °C20 mm Hg(lit.)
Density 0.932 g/mL at 25 °C(lit.)
refractive index n20/D 1.460(lit.)
Flash point >230 °F
storage temp. Store below +30°C.
solubility Chloroform
form Liquid
color Clear yellow
Water Solubility insoluble
BRN 1742640
Dielectric constant 3.8399999999999999
Stability Stable. Incompatible with strong bases, strong oxidizing agents.
CAS DataBase Reference 112-71-0(CAS DataBase Reference)
FDA UNII GX615908HN
NIST Chemistry Reference Tetradecane, 1-bromo-(112-71-0)
EPA Substance Registry System Tetradecane, 1-bromo- (112-71-0)
UNSPSC Code 12352101
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38-22
Safety Statements  26-36-24/25
WGK Germany  3
TSCA  Yes
HS Code  29033036
NFPA 704
0
0 0

1-Bromotetradecane price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 195332 1-Bromotetradecane 97% 112-71-0 5ml $17.82 2025-07-31 Buy
Sigma-Aldrich 195332 1-Bromotetradecane 97% 112-71-0 500ml $104.86 2025-07-31 Buy
Sigma-Aldrich 8.18896 1-Bromotetradecane for synthesis 112-71-0 5ml $34.3 2022-05-15 Buy
Sigma-Aldrich 8.18896 1-Bromotetradecane for synthesis 112-71-0 250ML $60.7 2022-05-15 Buy
TCI Chemical B0233 1-Bromotetradecane >97.0%(GC) 112-71-0 25mL $22 2025-07-31 Buy
Product number Packaging Price Buy
195332 5ml $17.82 Buy
195332 500ml $104.86 Buy
8.18896 5ml $34.3 Buy
8.18896 250ML $60.7 Buy
B0233 25mL $22 Buy

1-Bromotetradecane Chemical Properties,Uses,Production

Chemical Properties

colorless or pale yellow liquid. soluble in acetone, benzene and chloroform. intermediates for organic synthesis.

Uses

1-Bromotetradecane was used in the synthesis of tetradecylferrocene, cationic and zwitterionic gemini surfactants, and 9-tetradecylcarbazole. Also used for synthesis of metallomesogenic polymers based on bis[η1(N)-3,4-dialkyloxybenzylidene-4?-dodecyloxyaniline]dichloropalladium(II) with octyl, decyl, dodecyl, tetradecyl and hexadecyl alkyl groups.

Preparation

1-Bromotetradecane is synthesized from 1-tetradecanol by bromination. The 1-tetradecanol was added to the reaction pot, and the sulfuric acid was added dropwise with stirring, and the stirring was continued for half an hour after the addition. Then add hydrobromic acid, heat to 99-101°C, and react for 8h. Cool to 30°C, stop stirring, stand for 12 hours, and separate the upper layer of oil, and adjust the pH to 8 with 10% sodium carbonate solution. The water layer was separated, the oily substance was washed twice with an equal volume of 50% ethanol, the washed oily substance was added with sodium carbonate, stirred intermittently, and dried for 24h. Filtration to obtain 1-bromotetradecane.

Synthesis

1-TETRADECENE

1120-36-1

1-Bromotetradecane

112-71-0

General procedure for the synthesis of bromotetradecane from 1-tetradecene: 1-tetradecene (393 mg, 2 mmol) was dissolved in hexane (2 mL) at room temperature, followed by the addition of 1c (17 wt%, 1.3 g, 2.7 mmol). The reaction mixture was stirred for 1 h at room temperature. Upon completion of the reaction, the reaction was quenched with deionized water (10 mL) and extracted with ether (10 mL × 3). The organic phases were combined, washed with saturated saline (15 mL × 2), dried over anhydrous sodium sulfate (5 g), and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography using hexane as eluent to afford bromotetradecane (543 mg, 98% yield) as a colorless liquid. The structure of the product was confirmed by 1H-NMR (500 MHz, CDCl3) and 13C NMR (126 MHz, CDCl3): 1H-NMR δ 0.89 (t, J = 6.9 Hz, 3H), 1.26-1.31 (m, 18H), 1.84 (dd, J = 7.7 Hz, J = 6.7 Hz, 2H), 3.41 (t, J = 6.9 Hz, 2H); 13C NMR δ 14.21, 22.85, 28.38, 28.97, 29.55, 29.64, 29.74, 29.85 (4C), 32.11, 33.03, 33.59.

References

[1] Tetrahedron Letters, 2017, vol. 58, # 12, p. 1190 - 1193
[2] Synlett, 2010, # 13, p. 2014 - 2018

1120-36-1
112-71-0
Synthesis of 1-Bromotetradecane from 1-TETRADECENE
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View Lastest Price from 1-Bromotetradecane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Bromotetradecane pictures 2025-12-23 1-Bromotetradecane
112-71-0
US $0.00 / KG 1KG ≥98% 40 Tons/Month Yancheng Longshen Chemical Co.,Ltd.
1-Bromotetradecane pictures 2025-12-23 1-Bromotetradecane
112-71-0
US $0.00 / KG 25KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
1-Bromotetradecane pictures 2025-12-11 1-Bromotetradecane
112-71-0
US $10.00 / KG 1KG 99% 100 mt Hebei Chuanghai Biotechnology Co., Ltd
1-Bromtetradecan 1-Tetradecyl bromide 1-tetradecylbromide 1-BROMOTETRADECANE BROMOTETRADECANE TETRADECYL BROMIDE N-TETRADECYL BROMIDE 1-BROMOTETRADECANE (MYSTRYL BROMIDE) 1-BROMOTETRADECANE pure Myristyl bromide, Tetradecyl bromide 1-Bromotetradecane,98% 1-BroMotetradecane, 98% 100GR NSC 83468 1-bromo-tetradecan n-Tetradecyl-1-bromide tetradecane,1-bromo- Tetradecylbromid 1-BROMOTETRADECANE 99+% 1-Bromotetradecane > 1-Bromotetradecane ISO 9001:2015 REACH MYRISTYL BROMIDE 112-71-0 112-71-1 C14H29Br 112710 CH3CH213Br Halogenated Hydrocarbons Organic Building Blocks Building Blocks Alkyl Monofunctional & 伪,蠅-Bifunctional Alkanes Alkyl Bromides Monofunctional Alkanes Alkyl Bromides Monofunctional & alpha,omega-Bifunctional Alkanes Monofunctional Alkanes