ChemicalBook >> CAS DataBase List >>BENZYL 2,2,2-TRICHLOROACETIMIDATE
BENZYL 2,2,2-TRICHLOROACETIMIDATE
- CAS No.
- 81927-55-1
- Chemical Name:
- BENZYL 2,2,2-TRICHLOROACETIMIDATE
- Synonyms
- Benzyl trichloroacetimidate;oroacetimidate;BENZYLPHOSPONIC ACID;LABOTEST-BB LT00455324;Benzyl 2,2,2-trichloroacetimide;BENZYL 2,2,2-TRICHLOROACETIMIDATE;benzyl 2,2,2-trichloroethaniMidate;Benzyl 2,2,2-trichloroethanimidoate;O-Benzyl 2,2,2-trichloroacetiMidate;TRICHLOROACETIMIDIC ACID BENZYL ESTER
- CBNumber:
- CB8409616
- Molecular Formula:
- C9H8Cl3NO
- Molecular Weight:
- 252.52
- MDL Number:
- MFCD00000805
- MOL File:
- 81927-55-1.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| Melting point | 3 °C |
|---|---|
| Boiling point | 106-114 °C0.5 mm Hg(lit.) |
| Density | 1.359 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | Miscible with cyclohexane/dichloromethane. |
| form | Liquid |
| pka | 2.23±0.70(Predicted) |
| color | Clear colorless to yellow |
| Sensitive | Moisture Sensitive |
| BRN | 2525375 |
| Stability | Moisture Sensitive |
| CAS DataBase Reference | 81927-55-1(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319-H335 | |||||||||
| Precautionary statements | P301+P312+P330-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22-36/37/38 | |||||||||
| Safety Statements | 26 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 8-10-21 | |||||||||
| HS Code | 29252900 | |||||||||
| NFPA 704 |
|
BENZYL 2,2,2-TRICHLOROACETIMIDATE price More Price(25)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 140333 | Benzyl 2,2,2-trichloroacetimidate 99% | 81927-55-1 | 5g | $41.8 | 2024-03-01 | Buy |
| Sigma-Aldrich | 140333 | Benzyl 2,2,2-trichloroacetimidate 99% | 81927-55-1 | 25g | $138 | 2024-03-01 | Buy |
| TCI Chemical | B1483 | Benzyl 2,2,2-Trichloroacetimidate >97.0%(GC) | 81927-55-1 | 25g | $94 | 2024-03-01 | Buy |
| Alfa Aesar | A12387 | Benzyl 2,2,2-trichloroacetimidate, 98% | 81927-55-1 | 5g | $32.65 | 2024-03-01 | Buy |
| Alfa Aesar | A12387 | Benzyl 2,2,2-trichloroacetimidate, 98% | 81927-55-1 | 25g | $90.65 | 2024-03-01 | Buy |
BENZYL 2,2,2-TRICHLOROACETIMIDATE Chemical Properties,Uses,Production
Chemical Properties
clear colorless to yellow liquid
Uses
Benzyl 2,2,2-trichloroacetimidate was used as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It was used in the acid-catalyzed benzylation of hydroxy groups.
Uses
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.
Uses
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups.
Purification Methods
Purify the imidate by distillation to remove up to 1% of PhCH2OH as stabiliser. A solution in hexane can be stored for up to 2 months without decomposition. It is hygroscopic and has to be stored dry. [Wessel et al. J Chem Soc, Perkin Trans 1 2247 1985, Beilstein 6 IV 2265.]
BENZYL 2,2,2-TRICHLOROACETIMIDATE Preparation Products And Raw materials
Global( 165)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10248 | 58 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 6992 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
View Lastest Price from BENZYL 2,2,2-TRICHLOROACETIMIDATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2022-09-27 | BENZYL 2,2,2-TRICHLOROACETIMIDATE
81927-55-1
|
US $0.00-0.00 / KG | 1KG | 98% | 1ton | Henan Aochuang Chemical Co.,Ltd. | |
 |
2022-08-26 | BENZYL 2,2,2-TRICHLOROACETIMIDATE
81927-55-1
|
US $1.10 / g | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited | |
 |
2021-07-20 | BENZYL 2,2,2-TRICHLOROACETIMIDATE
81927-55-1
|
US $0.00-0.00 / KG | 1g | 99% HPLC | 2000tons | Shaanxi Dideu Medichem Co. Ltd |
-
- BENZYL 2,2,2-TRICHLOROACETIMIDATE
81927-55-1
- US $0.00-0.00 / KG
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- BENZYL 2,2,2-TRICHLOROACETIMIDATE
81927-55-1
- US $1.10 / g
- 99.00%
- Dideu Industries Group Limited
-
- BENZYL 2,2,2-TRICHLOROACETIMIDATE
81927-55-1
- US $0.00-0.00 / KG
- 99% HPLC
- Shaanxi Dideu Medichem Co. Ltd
81927-55-1(BENZYL 2,2,2-TRICHLOROACETIMIDATE)Related Search:
2,2,2-TRICHLOROACETIMIDIC ACID BENZYL ESTER
Benzyl 2,2,2-trichloroacetimidate, 98+%
Ethanimidic acid, 2,2,2-trichloro-, phenylmethyl ester
Benzyl 2,2,2-trichloroacetimidate, GC 99%
BENZYLPHOSPONIC ACID
Benzyl 2,2,2-trichloroethanimidoate
TRICHLOROACETIMIDIC ACID BENZYL ESTER
LABOTEST-BB LT00455324
BENZYL 2,2,2-TRICHLOROACETIMIDATE
Benzyl 2,2,2-trichloroacetimidate, 99 %
AcetiMidic acid, 2,2,2-trichloro-, benzyl ester (6CI)
O-Benzyl 2,2,2-trichloroacetiMidate
Benzyl 2,2,2-trichloroacetimide
Benzyl 2,2,2-trichloroacetimidate 99%
Benzyl 2,2,2-trichloroacetiMidate, 99% 25GR
benzyl 2,2,2-trichloroethaniMidate
(2,2,2-trichloro-1-phenylmethoxyethylidene)azanide
Benzyl 2,2,2-Trichloroacetimidate >
oroacetimidate
BENZYL 2,2,2-TRICHLOROACETIMIDATE ISO 9001：2015 REACH
Benzyl trichloroacetimidate
Phenylmethyl 2,2,2-trichloroethanimidate
81927-55-1
CCl3CNHOCH2C6H5
C9H8Cl3NO
Amidates/Imidates
Building Blocks
Nitrogen Compounds
Organic Building Blocks
Protection & Derivatization Reagents (for Synthesis)
Protection & Derivatization Reagents (for Synthesis)
Synthetic Organic Chemistry
Amidates/Imidates
Building Blocks
Chemical Synthesis
Nitrogen Compounds
Organic Building Blocks
Benzene series