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Bis(2-ethylhexyl) phthalate

Bis(2-ethylhexyl) phthalate
Bis(2-ethylhexyl) phthalate structure
CAS No.
117-81-7
Chemical Name:
Bis(2-ethylhexyl) phthalate
Synonyms
DOP;Behp;DEHP;daf68;DAF 68;di-sec;NLA-20;Octoil;mollano;Fleximel
CBNumber:
CB8708555
Molecular Formula:
C24H38O4
Formula Weight:
390.56
MOL File:
117-81-7.mol

Bis(2-ethylhexyl) phthalate Properties

Melting point:
-50 °C
Boiling point:
386 °C(lit.)
Density 
0.985 g/mL at 25 °C(lit.)
vapor density 
>16 (vs air)
vapor pressure 
1.2 mm Hg ( 93 °C)
refractive index 
n20/D 1.488
Flash point:
405 °F
storage temp. 
2-8°C
form 
Liquid
color 
APHA: ≤10
Odor
Very slight, characteristic.
Water Solubility 
Negligible
FreezingPoint 
<-60℃
Merck 
14,2864
BRN 
1890696
CAS DataBase Reference
117-81-7(CAS DataBase Reference)
NIST Chemistry Reference
Bis(2-ethylhexyl)phthalate(117-81-7)
EPA Substance Registry System
1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester(117-81-7)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,F
Risk Statements  60-61-39/23/24/25-23/24/25-11
Safety Statements  53-45-36/37-16
RIDADR  UN 1230 3/PG 2
WGK Germany  1
RTECS  TI0350000
Autoignition Temperature 734 °F
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29173400
Hazardous Substances Data 117-81-7(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H360 May damage fertility or the unborn child Reproductive toxicity Category 1A, 1B Danger
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P311 Call a POISON CENTER or doctor/physician.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.

Bis(2-ethylhexyl) phthalate price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 36735 Bis(2-ethylhexyl) phthalate PESTANAL , analytical standard 117-81-7 1g $34.5 2018-11-13 Buy
Sigma-Aldrich 1545056 Plastic additive 14 United States Pharmacopeia (USP) Reference Standard 117-81-7 100mg $348 2018-11-13 Buy
TCI Chemical P0297 Bis(2-ethylhexyl) Phthalate >98.0%(GC) 117-81-7 25g $14 2018-11-22 Buy
TCI Chemical P0297 Bis(2-ethylhexyl) Phthalate >98.0%(GC) 117-81-7 500g $19 2018-11-22 Buy
Alfa Aesar A10415 Bis(2-ethylhexyl) phthalate 98+% 117-81-7 500g $24.2 2018-11-20 Buy

Bis(2-ethylhexyl) phthalate Chemical Properties,Uses,Production

Chemical Properties

CLEAR LIQUID

Uses

Dialkyl phthalate ester plasticizer used to import softness and flexibility to PVC products.

Definition

ChEBI: A phthalate ester that is the bis(2-ethylhexyl) ester of benzene-1,2-dicarboxylic acid.

Uses

As plasticizer in PVC applications and flexible vinyls.

General Description

Colorless to pale yellow oily liquid. Nearly odorless.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Bis(2-ethylhexyl) phthalate reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides. Incompatible with nitrates .

Health Hazard

Inhalation can cause nausea and irritation of nose and throat. Contact of liquid with eyes or skin causes irritation. Ingestion can cause abdominal cramps, nausea and diarrhea.

Health Hazard

The acute oral toxicity is of extremelylow order. The oral LD50 value in miceis in the range 30,000 mg/kg. Ingestion ofabout 10 mL of the liquid may produce gas trointestinal pain, hypermotility, and diar rhea in humans. Chronic administration byoral route did not produce any adverseeffect in animals. A dose of 100 mg/kg/dayproduced increased liver and kidney weight,as well as retardation of growth in dogs.Mice given diets containing 12,000 ppm ofdiethylhexyl phthalate for 40 weeks devel oped renal hyperplasia (Ward et al. 1988).There was no evidence of renal carcino genicity. Oral administration, however, pro duced tumors in livers in the laboratoryanimals. It is a suspected cancer-causingagent, and there is sufficient evidence of itscarcinogenicity in animals. Such evidence inhumans, however, is lacking
Rock and co-workers (1988) reported theinteraction of diethylhexyl phthalate withblood during storage in PVC plastic containers. The plasticizer is leached into theplasma and converted to mono(2-ethylhexyl)phthalate by a plasma enzyme. At a levelof >125 mg/mL in the blood mono(2-ethyl hexyl) phthalate produced a 50% decrease inheart rate and blood pressure in rats.

Fire Hazard

Flash Point (°F): 425 ℃; Flammable Limits in Air (%): Not pertinent; Fire Extinguishing Agents: Dry powder, carbon dioxide, foam; Fire Extinguishing Agents Not To Be Used: Water or foam may cause frothing; Special Hazards of Combustion Products: None; Behavior in Fire: Not pertinent; Ignition Temperature: Data not available; Electrical Hazard: Not pertinent; Burning Rate: Not pertinent.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Experimental teratogenic data. Other experimental reproductive effects. Poison by intravenous route. Human systemic effects by ingestion: gastrointestinal tract effects. A mild skin and eye irritant. When heated to decomposition it emits acrid smoke.

Purification Methods

Wash the ester with Na2CO3 solution, then shake it with water. After the resulting emulsion has been broken by adding ether, the ethereal solution is washed twice with water, dried (CaCl2), and evaporated. The residual liquid is distilled several times under reduced pressure, then stored in a vacuum desiccator over P2O5 [French & Singer J Chem Soc 1424 1956]. [Beilstein 9 IV 3184.]

Bis(2-ethylhexyl) phthalate Preparation Products And Raw materials

Raw materials

Preparation Products


Bis(2-ethylhexyl) phthalate Suppliers

Global( 248)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
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info@dakenchem.com CHINA 22043 58
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Mainchem Co., Ltd.
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Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
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Shanghai BaiShun Biological Technology Co., Ltd 021-37581181
021-57456066 sales@chem-mall.com China 10382 58

View Lastest Price from Bis(2-ethylhexyl) phthalate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-06 Bis(2-ethylhexyl) phthalate
117-81-7
US $1.00 / KG 1KG 98% 1 career henan chemical co
2018-08-06 Bis(2-ethylhexyl) phthalate
117-81-7
US $280.00-280.00 / KG 200KG 99.5% 20T career henan chemical co

Bis(2-ethylhexyl) phthalate Spectrum


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