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Di-tert-butyl peroxide

Di-tert-butyl peroxide
Di-tert-butyl peroxide
CAS No.
110-05-4
Chemical Name:
Di-tert-butyl peroxide
Synonyms
DTBP;Cadox;cadoxtbp;Cadox tbp;perbutyld;trigonoxb;interoxdtb;kayabutyld;Trigonox b;(tert-C4H9O)2
CBNumber:
CB8852799
Molecular Formula:
C8H18O2
Formula Weight:
146.23
MOL File:
110-05-4.mol

Di-tert-butyl peroxide Properties

Melting point:
-30 °C
Boiling point:
109-110 °C(lit.)
Density 
0.796 g/mL at 25 °C(lit.)
vapor pressure 
40 mm Hg ( 20 °C)
refractive index 
n20/D 1.3891(lit.)
Flash point:
34 °F
storage temp. 
2-8°C
solubility 
0.063g/l
form 
Liquid
color 
Clear
Water Solubility 
immiscible
Merck 
14,3461
BRN 
1735581
Stability:
May decompose explosively if heated, subjected to shock, or treated with reducing agents. Highly flammable. Refrigerate.
CAS DataBase Reference
110-05-4(CAS DataBase Reference)
NIST Chemistry Reference
Di-tert-butyl peroxide(110-05-4)
EPA Substance Registry System
Peroxide, bis(1,1-dimethylethyl)(110-05-4)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  O,F,Xn
Risk Statements  7-11-68-52/53-2017/7/11
Safety Statements  14-16-3/7-36/37/39-14A-61-23
RIDADR  UN 3107 5.2
WGK Germany  1
RTECS  ER2450000
Autoignition Temperature 182 °C
HS Code  2909 60 00
HazardClass  5.2
PackingGroup  II
Hazardous Substances Data 110-05-4(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: > 25000 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H242 Heating may cause a fire Self-reactive substances and mixtures; and Organic peroxides Type C, D,Type E, F
Type G
Danger
Warning
P210, P220, P234, P280, P370+P378,P403+P235, P411, P420, P501
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P410 Protect from sunlight.
P411+P235 Store at temperatures not exceeding … oC/…oF. Keep cool.

Di-tert-butyl peroxide price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 168521 Luperox? DI, tert-Butyl peroxide 98% 110-05-4 5ml $33.6 2018-11-13 Buy
Sigma-Aldrich 168521 Luperox? DI, tert-Butyl peroxide 98% 110-05-4 1l $148 2018-11-13 Buy
TCI Chemical D3411 Di-tert-butyl Peroxide >98.0%(GC) 110-05-4 100mL $20 2018-11-22 Buy
Sigma-Aldrich 8.20248 Di-tert-butyl peroxide for synthesis. CAS 110-05-4, molar mass 146.23 g/mol., for synthesis 110-05-4 8202480250 $33 2018-11-23 Buy
Sigma-Aldrich 168521 Luperox? DI, tert-Butyl peroxide 98% 110-05-4 250ml $54.6 2018-11-13 Buy

Di-tert-butyl peroxide Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Uses

As polymerization catalyst.

General Description

Clear colorless liquid.

Reactivity Profile

The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. Di-tert-butyl peroxide is unlikely that this derivative would be particularly unstable compared to other peroxides in it's class, Bretherick 1979v.

Purification Methods

Wash the peroxide with aqueous AgNO3 to remove olefinic impurities, water and dry (MgSO4). Free it from tert-butyl hydroperoxide by passage through an alumina column [Jackson et al. J Am Chem Soc 107 208 1985], and if necessary two high vacuum distillations from room temperature to a liquid-air trap [Offenbach & Tobolsky J Am Chem Soc 79 278 1957]. [Beilstein 1 IV 1619.] The necessary protection from EXPLOSION should be used.

Di-tert-butyl peroxide Preparation Products And Raw materials

Raw materials

Preparation Products


Di-tert-butyl peroxide Suppliers

Global( 155)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22049 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20786 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32651 55
Hangzhou FandaChem Co.,Ltd.
0086 158 5814 5714 (Mobile; WhatsApp; Telegram)
+86-571-56059825 fandachem@gmail.com CHINA 2067 55
Chemson Industrial (Shanghai) Co., Ltd.
86-21-65208861-ext8007
86-21-65180813 sales1@chemson.com.cn CHINA 121 58
Tianjin Zhongxin Chemtech Co., Ltd.
022-89880739
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Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 marketing@haihangchem.com CHINA 4535 58
Yancheng Green Chemicals Co.,Ltd
86-515-87883661
86-515-87883652 sales@greenchem-china.com CHINA 350 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19990 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76

View Lastest Price from Di-tert-butyl peroxide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-21 Di-tert-butyl peroxide
110-05-4
US $1.00 / kg 1g 99% 100KG career henan chemical co

Di-tert-butyl peroxide Spectrum


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