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Triphenyl phosphate

Triphenyl phosphate
Triphenyl phosphate
CAS No.
115-86-6
Chemical Name:
Triphenyl phosphate
Synonyms
TPP;TPPA;Altal;Dymel;Wako TPP;NSC 57868;Plastifier;Reofos TPP;phosflextpp;Kronitex TPP
CBNumber:
CB9233809
Molecular Formula:
C18H15O4P
Formula Weight:
326.28
MOL File:
115-86-6.mol

Triphenyl phosphate Properties

Melting point:
48-50 °C(lit.)
Boiling point:
370 °C
Density 
1.2055
vapor pressure 
1.3 mm Hg ( 200 °C)
refractive index 
1.563
Flash point:
435 °F
storage temp. 
2-8°C
solubility 
H2O: soluble0.0019g/L at 20°C
form 
Crystalline Flakes
color 
White
Water Solubility 
insoluble
Merck 
14,9742
BRN 
1888236
Stability:
Stable.
InChIKey
XZZNDPSIHUTMOC-UHFFFAOYSA-N
CAS DataBase Reference
115-86-6(CAS DataBase Reference)
NIST Chemistry Reference
Triphenylphosphate(115-86-6)
EPA Substance Registry System
Phosphoric acid, triphenyl ester(115-86-6)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn,N,F,Xi
Risk Statements  22-38-40-48/20/22-50/53-52/53-36/37/38-67-66-36-11-51/53
Safety Statements  36/37-61-60-24/25-22-36-26-16-24-9
RIDADR  UN 3077 9/PG 3
WGK Germany  2
RTECS  TC8400000
Autoignition Temperature >500 °C
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29190010
Hazardous Substances Data 115-86-6(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 3500 mg/kg LD50 dermal Rabbit > 7900 mg/kg
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P273 Avoid release to the environment.
P501 Dispose of contents/container to..…

Triphenyl phosphate price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 241288 Triphenyl phosphate ≥99% 115-86-6 50g $29.1 2018-11-13 Buy
Sigma-Aldrich 05498 Triphenyl phosphate TraceCERT , 31P-qNMR Standard 115-86-6 1g $133 2018-11-13 Buy
TCI Chemical P0272 Triphenyl Phosphate >99.0%(GC) 115-86-6 25g $14 2018-11-22 Buy
TCI Chemical P0272 Triphenyl Phosphate >99.0%(GC) 115-86-6 500g $27 2018-11-22 Buy
Alfa Aesar L08130 Triphenyl phosphate, 98% 115-86-6 250g $24.8 2018-11-13 Buy

Triphenyl phosphate Chemical Properties,Uses,Production

Chemical Properties

Colorless, crystalline powder; odorless. Soluble in most lacquers, solvents, thinners, oils; insoluble in water. Combustible.

Chemical Properties

Triphenyl phosphate is a colorless crystalline powder with a faint, phenol-like odor.

Uses

Triphenyl Phosphate is used in the insecticidal composition. Also acts as a flame retardant.

Definition

ChEBI: An aryl phosphate resulting from the formal condensation of phosphoric acid with 3 mol eq. of phenol.

Uses

Noncombustible substitute for camphor in celluloid; rendering acetylcellulose, nitrocellulose, airplane "dope", etc., stable and fireproof; impregnating roofing paper; plasticizer in lacquers and varnishes.

Reactivity Profile

Organophosphates, such as Triphenyl phosphate, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Hazard

Toxic by inhalation. Cholinesterase inhibitor. Questionable carcinogen.

Safety Profile

Poison by subcutaneous route. Moderately toxic by ingestion. Absorbed slowly, particularly by skin contact. Not a potent cholinesterase inhibitor. Combustible when exposed to heat or flame. To fight fire, use CO2, dry chemical. When heated to decomposition it emits toxic fumes of POx. See also TRITOLYL PHOSPHATE.

Potential Exposure

Triphenyl phosphate is used to impregnate roofing paper and as a fire-resistant plasticizer in plastics; for cellulose esters in lacquers and varnishes. Used in making adhesives, gasoline additives; flotation agents; insecticides, surfactants, antioxidants, and stabilizers. A substitute for camphor.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, rinse mouth and get medical attention.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Purification Methods

Crystallise the phosphate from EtOH or pet ether (b 60-80o)/EtOH. [Cox & Westheimer J Am Chem Soc 80 5441 1958, Krishnakumar & Sharma Synthesis 558 1983, Cherbuliez in Organo Phosphorus Compounds (Kosolapoff & Maier eds) Wiley Vol 6 pp 211-577 1973, Beilstein 6 III 658, 6 IV 720.]

Incompatibilities

Incompatible with strong oxidizers; strong acids; nitrates may cause fire or explosions. Phosphates are incompatible with antimony pentachloride, magnesium, silver nitrate, zinc acetate.

Waste Disposal

Incinerate in furnace equipped with alkaline scrubber.

Triphenyl phosphate Preparation Products And Raw materials

Raw materials

Preparation Products


Triphenyl phosphate Suppliers

Global( 320)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Tianjin Zhongxin Chemtech Co., Ltd.
022-89880739
022-66880086 sales@tjzxchem.com CHINA 560 58
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22059 58
Dalian Richfortune Chemicals Co., Ltd
86-411-84820922, 84821539
86-411-84821380 sales@richfortunechem.com China 362 57
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20795 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com CHINA 1374 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32764 55
Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 1582 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20001 58
Zhejiang ZETian Fine Chemicals Co. LTD
+86-18957127338
sales@zetchem.com CHINA 1260 58
Shanghai Zheyan Biotech Co., Ltd.
18017610038
zheyansh@163.com CHINA 3624 58

View Lastest Price from Triphenyl phosphate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-18 Triphenyl phosphate
115-86-6
US $1.00 / kg 1kg 99% 2000kg career henan chemical co

Triphenyl phosphate Spectrum


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