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Phosphorus trichloride

Chemical Properties Uses Preparation
Phosphorus trichloride
Phosphorus trichloride structure
CAS No.
7719-12-2
Chemical Name:
Phosphorus trichloride
Synonyms
PICl;PCl3;Fosfortrichloride;Phosphortrichlorid;trichloro-phosphin;Trichlorophosphine;trojchlorekfosforu;trichlorophosphane;phosphorouschloride;Trojchlorek fosforu
CBNumber:
CB6459046
Molecular Formula:
Cl3P
Formula Weight:
137.33
MOL File:
7719-12-2.mol

Phosphorus trichloride Properties

Melting point:
-112 °C
Boiling point:
74-78 °C(lit.)
Density 
1.574 g/mL at 25 °C
vapor density 
4.75 (vs air)
vapor pressure 
23.32 psi ( 55 °C)
refractive index 
n20/D 1.5148(lit.)
Flash point:
76°C
storage temp. 
Store at RT.
solubility 
Soluble in benzene, carbon sulfide, ether, chloroform, carbon tetrachloride.
form 
Liquid
color 
Yellow
Specific Gravity
approximate 1.6
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
Merck 
14,7358
BRN 
969177
Exposure limits
TLV-TWA 1.12 mg/m3 (0.2 ppm) (ACGIH), 2.8 mg/m3 (0.5 ppm) (OSHA).
Stability:
Stable, but light sensitive. Incompatible with water, many metals, fluorine, acids, variety of organic materials including acids, alcohols and reducing agents. Reaction with water is violent and yields toxic gas.
CAS DataBase Reference
7719-12-2(CAS DataBase Reference)
NIST Chemistry Reference
Phosphorus trichloride(7719-12-2)
EPA Substance Registry System
Phosphorous trichloride(7719-12-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  T+,C
Risk Statements  14-26/28-29-35-48/20-40-37
Safety Statements  26-36/37/39-45-7/8-43-28
RIDADR  UN 3390 6.1/PG 1
WGK Germany  2
RTECS  TH3675000
21
TSCA  Yes
HazardClass  6.1
PackingGroup  I
HS Code  28121043
Hazardous Substances Data 7719-12-2(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P320 Specific treatment is urgent (see … on this label).
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.

NFPA 704

Diamond Hazard Value Description
0
4 2
Health   4 Very short exposure could cause death or major residual injury (e.g. hydrogen cyanide, phosgene, methyl isocyanate, hydrofluoric acid)
Flammability   0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 820 °C (1,500 °F) for a period of 5 minutes.(e.g. Carbon tetrachloride)
Instability   2 Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water (e.g. white phosphorus, potassium, sodium)
Special  

(NFPA, 2010)

Phosphorus trichloride price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 157791 Phosphorus trichloride 99% 7719-12-2 50g $46.5 2018-11-20 Buy
Sigma-Aldrich 157791 Phosphorus trichloride 99% 7719-12-2 1kg $127 2018-11-20 Buy
Alfa Aesar 022988 Phosphorus(III) chloride, 99.997% (metals basis) 7719-12-2 25g $267 2018-11-16 Buy
Alfa Aesar 022988 Phosphorus(III) chloride, 99.997% (metals basis) 7719-12-2 100g $710 2018-11-16 Buy
Strem Chemicals 93-1588 Phosphorus(III) chloride (99.998%-P) PURATREM 7719-12-2 10g $70 2018-11-13 Buy

Phosphorus trichloride Chemical Properties,Uses,Production

Chemical Properties

A colorless or slightly yellow fuming liquid with a pungent and irritating odor resembling that of hydrochloric acid. Causes severe burns to skin, eyes and mucous membranes. Very toxic by inhalation, ingestion and skin absorption. Reacts with water to evolve hydrochloric acid, an irritating and corrosive gas apparent as white fumes.

Uses

Phosphorus trichloride is used to prepare phosphine and other phosphorus compounds; used during electrodeposition of metal on rubber and for making pesticides, surfactants, gasoline additives, plasticizers, dyestuffs, textile finishing agents, germicides, medicinal products, and other chemicals.

Preparation

Phosphorus trichloride is prepared by reacting white phosphorus with dry chlorine present in limited quantity. Excess chlorine will yield phosphorus pentachloride, PCl5.
P4 + 6Cl2 → 4PCl3
P4 + 10Cl2 → 4PCl5
The compound is prepared in a retort attached to inlet tubes for dry chlorine and dry carbon dioxide and a distillation flask. White phosphorus is placed on sand in the retort. All air, moisture, and any phosphorus oxide vapors present in the apparatus are expelled by passing dry carbon dioxide.
Dry chlorine is then introduced into the apparatus. If a flame appears on phosphorus it indicates presence of excess chlorine. In that event, the rate of chlorine introduction should be decreased. For obtaining phosphorus trichloride, flame should appear at the end of the chlorine-entry tube. The trichloride formed is collected by condensation in the distillation flask. A soda lime tube is attached to the apparatus to prevent moisture entering the flask.
Phosphorus trichloride also can be prepared by reducing phosphorus oxychloride vapors with carbon at red heat:
POCl3 + C → PCl3 + CO

Chemical Properties

Phosphorus trichloride is a colorless to yellow, fuming liquid. Odor like hydrochloric acid.

Uses

As of phosphorus oxychloride; manufacture of POCl3, PCl5; producing iridescent metallic deposits.

Uses

Phosphorus trichloride is used as a chlorinating agent; as an intermediate in making gasoline additives, dyes, surfactants, and pesticides; in the manufacture of phosphorus pentachloride and phosphorus oxychloride; and as a catalyst.

Reactivity Profile

Phosphorus trichloride is a strong reducing agent that may ignite combustible organic materials upon contact. May generate flammable and potentially explosive gaseous hydrogen upon contact with many common metals (except nickel and lead). Reactions with water are violent and produce heat and flashes of fire [AAR, 1999]. Gives intensely exothermic reactions with iodine monochloride [Mellor 2, Supp. 1:502. 1956]. Several laboratory explosions have been reported arising from mixtures with acetic acid, along with other acids, sulfuric acid and derivatives, carboxylic acids, etc. These have been ascribed to poor heat control allowing the formation of phosphine [J. Am. Chem. Soc. 60:488. 1938]. Ignites when mixed with hydroxylamine [Mellor 8:290. 1946-47]. Causes an explosion on contact with nitric acid [Comp. Rend. 28:86]. Phosphorus trichloride is incompatible with many common oxidants such as: sodium peroxide, fluorine, chromyl chloride, iodine chloride, to name a few. Isopropanol can react with PCl3, forming toxic HCl gas. (Logsdon, John E., Richard A. Loke., "Isopropyl Alcohol." Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. 1996.)

Health Hazard

Phosphorus trichloride is highly toxic; it may cause death or permanent injury. Contact is highly irritating to the skin, eyes, and mucous membranes, and the material is an irritant through oral and inhalation exposure.

Health Hazard

Phosphorus trichloride is a highly corrosive substance. Its vapors are an irritant to the upper and lower respiratory tracts. Chronic exposure to its vapors can produce coughing, bronchitis, and pneumonia.
LC50 value, inhalation (guinea pigs): 50 ppm (280 mg/m3)/4 h
The liquid is corrosive to the skin and can cause acid burns..

Fire Hazard

Phosphorus trichloride will react violently with water, producing heat and toxic and corrosive fumes. When heated to decomposition, Phosphorus trichloride emits highly toxic fumes of chlorides and phosphorus oxides. Phosphorus trichloride may ignite other combustible materials. Reacts violently with water. Reacts explosively with acetic acid, aluminum, chromyl chloride, diallylphosphite and allyl alcohol, dimethyl sulfoxide, fluorine, hydroxylamine, iodine monochloride, lead dioxide, nitric acid, nitrous acid, organic matter, potassium, and sodium. Avoid contact with water, steam, or acids. Hazardous polymerization may not occur.

Safety Profile

Poison by ingestion and inhalation. A corrosive irritant to skin, eyes (at 2 ppm), and mucous membranes. Potentially explosive reaction with chlorobenzene + sodtum, hethyl sulfoxide, molten sodmm, chromyl chloride, nitric acid, sodium peroxide, oxygen (above 100℃), tetravinyl lead. Reacts with carboxylic acids (e.g., acetic acid) to form violently unstable products. Violent reaction or ignition with Al, chromium pentafluoride, dtallyl phosphite + allyl alcohol, F2, hexa fluoroisoprop ylideneaminolithium, hydroxylamine, iodine chloride, PbO2, HNO2, organic matter, potassium, selenium dioxide, sulfur acids (e.g., sulfuric acid, fluorosulfuric acid, oleum). Violent reaction with water evolves hydrogen chloride and diphosphane gas, that then ignite. Incompatible with metals or oxidants. Wdl react with water, steam, or acids to produce heat and toxic and corrosive fumes; can react with oxidzing materials. To fight fire, use CO2, dry chemical. Used as a chlorinating agent, catalyst, and chemical intermedtate. Dangerous; when heated to decomposition it emits highly toxic fumes of Cland POx.

Potential Exposure

Phosphorus trichloride is used as an intermediate and as a chlorinating agent and catalyst; in the manufacture of agricultural chemicals; pharmaceuticals, chlorinated compounds; dyes, gasoline additives; acetyl cellulose; phosphorus oxychloride; plasticizers, saccharin, and surfactants.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 30 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water, or milk. Do not induce vomiting. Medical observation is recommended for 2448 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy

Shipping

UN1809 Phosphorous trichloride, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 8-Corrosive material, Inhalation Zone B.

Purification Methods

Heat it under reflux to expel dissolved HCl, then distil it. It has been further purified by vacuum fractionation several times through a -45o trap into a receiver at -78o. [Forbes Inorg Synth II 145 1946.] HARMFUL VAPOURS.

Incompatibilities

Phosphorus trichloride is a strong reducing Violent reaction with water, producing heat and hydrochloric and phosphorous acids. Violent reaction with hydrides, alcohols, phenols and bases; water, when in contact with combustible organics; chemically active metals: sodium, potassium, aluminum; strong sulfuric or nitric acid. Attacks most metals except nickel and lead; may generate flammable hydrogen gas on contact with metals. Attacks plastics, rubber, and coatings.

Waste Disposal

Decompose with water, forming phosphoric and hydrochloric acids. The acids may then be neutralized and diluted slowly to solution of soda ash and slaked lime with stirring, then flush to sewer with large volumes of water.

Phosphorus trichloride Preparation Products And Raw materials

Raw materials

Preparation Products


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