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Oxybenzone

Chemical properties Application and Synthesis Improvement of UV - 9 Production Process
Oxybenzone
Oxybenzone structure
CAS No.
131-57-7
Chemical Name:
Oxybenzone
Synonyms
MOD;uf3;HMB;Uf 3;Uv 9;BP-3;HMBP;Anuvex;uvinul9;LGB-BP3
CBNumber:
CB9276251
Molecular Formula:
C14H12O3
Formula Weight:
228.24
MOL File:
131-57-7.mol
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Oxybenzone Properties

Melting point:
62-64 °C(lit.)
Boiling point:
150-160 °C5 mm Hg(lit.)
Density 
1,3 g/cm3
refractive index 
1.5805 (estimate)
Flash point:
216°C
storage temp. 
2-8°C
solubility 
95% ethanol: soluble50mg/mL, clear, colorless
form 
Crystalline Powder
pka
7.56±0.35(Predicted)
color 
White to light yellow
Water Solubility 
<0.1 g/100 mL at 20 ºC
Merck 
14,6954
BRN 
1913145
InChIKey
DXGLGDHPHMLXJC-UHFFFAOYSA-N
CAS DataBase Reference
131-57-7(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances
OXYBENZONE
FDA 21 CFR
177.1010; 201.327
EWG's Food Scores
6-8
FDA UNII
95OOS7VE0Y
NIST Chemistry Reference
Oxybenzone(131-57-7)
EPA Substance Registry System
2-Hydroxy-4-methoxybenzophenone (131-57-7)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P280a-P304+P340-P405-P501a-P305+P351+P338-P261
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37
RIDADR  UN 3077 9/PG III
WGK Germany  2
RTECS  DJ1575000
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29145000
Toxicity LD50 orally in rats: >12.8 g/kg (Lewerenz)

Oxybenzone price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 01479 2-Hydroxy-4-methoxybenzophenone certified reference material, TraceCERT 131-57-7 50mg $102 2020-08-18 Buy
Sigma-Aldrich 1485001 Oxybenzone United States Pharmacopeia (USP) Reference Standard 131-57-7 150mg $366 2020-08-18 Buy
TCI Chemical H0266 2-Hydroxy-4-methoxybenzophenone >99.0%(GC) 131-57-7 25g $20 2021-03-22 Buy
TCI Chemical H0266 2-Hydroxy-4-methoxybenzophenone >99.0%(GC) 131-57-7 500g $98 2021-03-22 Buy
Alfa Aesar A17662 2-Hydroxy-4-methoxybenzophenone, 98+% 131-57-7 50g $19.4 2020-06-24 Buy

Oxybenzone Chemical Properties,Uses,Production

Chemical properties

light yellow crystalline powder, soluble in ethanol, acetone and other organic solvents, insoluble in water.

Application and Synthesis

UV-9 is a light yellow or white crystalline powder, also known as sunscreen 2, BP-3, suitable for polyvinyl chloride, polyvinylidene chloride, polymethyl methacrylate , unsaturated polyester, ABS resin and cellulose resin and other plastics, the maximum absorption wavelength range of 280-340 nm, the general amount of 0.1-1.5%, good thermal stability, does not decompose at 200 ℃. This product hardly absorb visible light, it applies to light-colored transparent products. This product can also be used for paints and synthetic rubber. For the broad-spectrum UV absorbers, with high absorption rate, non-toxic, non-teratogenic effect, light, thermal stability. UV-9 can absorb UV-A and UV-B together, is the US FDA approved Class I sunscreen and being used with a higher frequency in the US and European countries. UV-9 is widely used in sunscreen cream, cream, honey, lotion, oil and other sunscreen cosmetics, but also as a product from the photosensitive and discoloration of the anti-discoloration agent. In addition, it is usually used for PVC and unsaturated polyester and many other fields, because UV-9 has good compatibility with many kinds of plastics and resins.

Improvement of UV - 9 Production Process

Using mixed acid as catalyst, trichloromethylbenzene and resorcinol were condensed into intermediate 2,4-dihydroxydiphenyl ketone in aqueous phase, and then the catalyst was treated with phase transfer catalyst, etherification of the target product UV-9.

Chemical Properties

white to light yellow crystalline powder

Uses

ultraviolet screen

Uses

Oxybenzone is an organic compound used in sunscreens. Oxybenzone is used as an ingredient in sunscreen and other cosmetics because it absorbs UVB and short-wave UVA (ultraviolet) rays. Oxybenzone was one of the first compounds incorporated into sunscreen formulations to offer enhanced UVA protection because its absorption spectrum extends to less than 350 nm.

Uses

Sunscreen. UV stabilizer

Uses

Ultraviolet light absorber and stabilizer, especially in plastics and paints.

Uses

oxybenzone (benzophenone-3) is the drug name for an FDAapproved uV filter and absorber.

Uses

benzophenone-3 (oxybenzone) is an oil-soluble uV absorber and filter with absorption rates within the uVA and uVB peak ranges. It has an approved usage level of up to 6 percent in the united States and 10 percent in the european union. Benzophenone-3 enhances SPF and is popular among sunscreen formulators given a concern over potential safety problems associated with more traditional sunscreen chemicals. However, some reports associate it with causing photocontact allergy. It is considered a non-comedogenic raw material.

Preparation

Preparation by partial methylation of 2,4- dihydroxy-benzophenone,
? with methyl iodide in the presence of sodium hydroxide;
? with a methyl halide;
? with dimethyl sulfate in the presence of sodium hydroxide or alkaline solution.

Definition

ChEBI: A hydroxybenzophenone that is benzophenone which is substituted at the 2- and 4-positions of one of the benzene rings by hydroxy and methoxy groups respectively.

brand name

Uvinul M40 (BASF).

Synthesis Reference(s)

Tetrahedron, 42, p. 885, 1986 DOI: 10.1016/S0040-4020(01)87495-0

General Description

White to off-white or light yellow powder.

Air & Water Reactions

Insoluble in water.

Fire Hazard

Flash point data for Oxybenzone are not available; however, Oxybenzone is probably combustible.

Contact allergens

BZP-3 is used as a direct sunscreen agent and in antiaging creams. Allergic reactions have been reported. Cross-reactivity is expected in an average of one in four patients photoallergic to ketoprofen.

Safety Profile

Poison by intraperitoneal route. Mddly toxic by ingestion. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.

Oxybenzone Preparation Products And Raw materials

Raw materials

Benzoyl chloride Dimethyl sulfate 2,4-Dimethoxybenzophenone 3-FORMYL-7-METHOXYCHROMONE Benzenemethanol, 2-hydroxy-4-methoxy-α-phenyl- 3-METHOXYPHENYLBENZOATE 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid Benzoylformic acid Phenylboronic acid 3-Methoxyphenol 2-Hydroxy-4-methoxybenzaldehyde 2,4-Dihydroxybenzophenone Dimethoxybenzene

Preparation Products

photosensitive polyimide/SiO2 hybrid mate materials

Oxybenzone Suppliers

Global( 516)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671
 0551-65418697 sales@tnjchem.com CHINA 37441 58
HANGZHOU CLAP TECHNOLOGY CO.,LTD
13588875226 86-571-88216897、88216896
 86-571-88216895 sales@hzclap.com CHINA 6469 58
Yantai Suny Chem Int'l Co.,Ltd
+8613606382686 +86-0535-6622355
 laureenwang@sunychem.com;andy@sunychem.com CHINA 79 58
Henan DaKen Chemical CO.,LTD. 		+86-371-66670886
 info@dakenchem.com China 21022 58
Dalian Richfortune Chemicals Co., Ltd 		0411-84820922
 86-411-84821380 sales@richfortunechem.com China 300 57
Shanghai Bojing Chemical Co.,Ltd. 		+86-21-37122233
 +86-21-37127788 Candy@bj-chem.com CHINA 497 55
Henan Tianfu Chemical Co.,Ltd. 		0371-55170693
 0371-55170693 info@tianfuchem.com CHINA 22607 55
Hangzhou FandaChem Co.,Ltd. 		008615858145714
 +86-571-56059825 fandachem@gmail.com CHINA 8882 55
ATK CHEMICAL COMPANY LIMITED 		+86 21 5161 9050/ 5187 7795
 +86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 26734 60
Anhui Royal Chemical Co., Ltd. 		+86-025-86655873
 marketing@royal-chem.com CHINA 536 55

View Lastest Price from Oxybenzone manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-10-14 LGB-BP3
131-57-7 		US $0.00 / drums 25drums 99% 20 TONS Hebei Dongdu Import and Export Co. LTD
2021-10-14 Benzophenone-3
131-57-7 		US $20.00 / Kg/Drum 25KG 99% 20 tons/month Hebei Dongdu Import and Export Co. LTD
2021-10-11 2-Hydroxy-4-methoxybenzophenone
131-57-7 		US $0.00 / Kg/Bag 1KG 99% 20ton Hebei Mojin Biotechnology Co., Ltd

Oxybenzone Spectrum

Oxybenzone(131-57-7) 13C NMROxybenzone(131-57-7) 1H NMROxybenzone(131-57-7) IR1Oxybenzone(131-57-7) Raman

131-57-7(Oxybenzone)Related Search:

2-[4-[2-HYDROXY-3-TRIDECYL OXYPROPYL]OXY]-2-HYDROXYPHENYL]-4,6-BIS(2,4-DIMETHYLPHENYL)-1,3,5-TRIAZINE AND 2-[4-[2-HYDROXY-3-DODECYL OXYPROPYL]OXY]-2-HYDROXYPHENYL]-4,6-BIS(2,4-DIMETHYLPHENYL)-1,3,5-TRIAZINE 2-(2H-Benzotriazol-2-yl)-6-(1-methyl-1-phenylethyl)-4-(1,1,3,3-tetramethylbutyl)phenol 2,2'-(1,4-PHENYLENE)BIS-4H-3,1-BENZOXAZIN-4-ONE Ultraviolet Absorbent UV-1164 2-(4,6-Diphenyl-1,3,5-triazin-2-yl)-5-[(hexyl)oxy]-phenol Benazol P 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid Octabenzone 2,2',4,4'-Tetrahydroxybenzophenone 2,2'-Dihydroxy-4-methoxybenzophenone 2,2'-Dihydroxy-4,4'-dimethoxybenzophenone 2-Phenylbenzimidazole-5-sulfonic acid Tinuvin-1130 2,2'-Thiobis(4-tert-octylphenolato)-n-butylamine nickel(II) 2-(2'-Hydroxy-4'-benzoyloxyphenyl)-5-chlorobenzotriazole Poly[N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexanediamine-co-2,4-dichloro-6-morpholino-1,3,5-triazine] N-(2-Ethoxyphenyl)-N'-(4-ethylphenyl)-ethlyene diamide 2-Hydroxy-4-methoxybenzophenone-5-sodium sulfonate
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