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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)

TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) structure

CAS No.: 31011-57-1

Chemical Name:: TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)

Synonyms: Titanium(iv) chloride tet;Tetrachlorobis(THF)titanium;oxolane:tetrachlorotitanium;Titanium (IV) Chloride THF Complex;TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM;Bis(tetrahydrofuran)tetrachlorotitanium;TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV);Titanium tetrachloride bis(tetrahydrofuran);TITANIUM(IV) CHLORIDE-TETRAHYDOFURAN COMPLEX;Tetrachlorobis(tetrahydrofurane)titanium(IV)

CBNumber:: CB9359422

Molecular Formula:: C8H16Cl4O2Ti

Molecular Weight:: 333.89

MDL Number:: MFCD00077884

MOL File:: 31011-57-1.mol

MSDS File:: SDS

Last updated:2025-10-22 15:21:50

Product description	Number	Pack Size	Price
Titanium(IV) chloride tetrahydrofuran complex 97%	395404	5g	$90.1
Titanium(IV) chloride tetrahydrofuran complex 97%	395404	25g	$276.45
Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%	22-1080	5g	$63
Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%	22-1080	25g	$244
Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%	22-1080	100g	$732

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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Properties

Melting point	126-128 °C(lit.)
Flash point	1 °F
storage temp.	2-8°C
form	crystal
color	yellow
Water Solubility	Reacts with water
Sensitive	Moisture Sensitive
Hydrolytic Sensitivity	7: reacts slowly with moisture/water
InChI	InChI=1S/2C4H8O.4ClH.Ti/c21-2-4-5-3-1;;;;;/h21-4H2;4*1H;/q;;;;;;+4/p-4
InChIKey	LXWBMENBONGPSB-UHFFFAOYSA-J
SMILES	[Ti](Cl)(Cl)(Cl)Cl.C1COCC1.C1COCC1
CAS DataBase Reference	31011-57-1(CAS DataBase Reference)
UNSPSC Code	12352106
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS05

Signal word

Danger

Hazard statements

H228-H314

Precautionary statements

P210-P240-P260-P280-P303+P361+P353-P305+P351+P338

Hazard Codes

Risk Statements

14-34-37

Safety Statements

26-36/37/39-45

RIDADR

UN 2925 4.1/PG 2

WGK Germany

3-10

TSCA

HazardClass

PackingGroup

Limited Quantities

1.0 Kg (2.2 lbs)

Excepted Quantities

Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

NFPA 704

	2
3		0

TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) price More Price(7)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	395404	Titanium(IV) chloride tetrahydrofuran complex 97%	31011-57-1	5g	$90.1	2025-07-31	Buy
Sigma-Aldrich	395404	Titanium(IV) chloride tetrahydrofuran complex 97%	31011-57-1	25g	$276.45	2025-07-31	Buy
Strem Chemicals	22-1080	Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%	31011-57-1	5g	$63	2024-03-01	Buy
Strem Chemicals	22-1080	Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%	31011-57-1	25g	$244	2024-03-01	Buy
Strem Chemicals	22-1080	Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%	31011-57-1	100g	$732	2024-03-01	Buy

Product number	Packaging	Price	Buy
395404	5g	$90.1	Buy
395404	25g	$276.45	Buy
22-1080	5g	$63	Buy
22-1080	25g	$244	Buy
22-1080	100g	$732	Buy

TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Chemical Properties,Uses,Production

Chemical Properties

The reaction of tetrachlorodi(tetrahydrofuran)titanium(IV) and magnesium in tetrahydrofuran under argon protection gives [Ti(MgCl)2(THF)]2. It reacts with magnesium directly in a nitrogen atmosphere to give TiN(MgCl)2(THF), which can then be reacted with iodine, via the ITiN(MgCl)2 intermediate, to produce Ti=N(MgCl). Stannous chloride can also reduce it to produce TiCl3(THF)3 and green [TiCl2(THF)4][SnCl5(THF)]: 2 TiCl4(THF)2 + SnCl2 → [trans-TiCl2(THF)4][SnCl5(THF)] + TiCl3(THF)3

Uses

Titanium(IV) chloride tetrahydrofuran complex can be used as a catalyst in intermolecular hydroamination reactions.

reaction suitability

core: titanium
reagent type: Lewis acid
reagent type: catalyst

TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Preparation Products And Raw materials

Raw materials

Preparation Products

TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Suppliers

Global( 64)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49975	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58
Xi'an MC Biotech, Co., Ltd.	029-89275612 +8618991951683	mcbio_sales@163.com	China	2251	58
Shaanxi Dideu Medichem Co. Ltd	+86-029-89586680 +86-18192503167	1026@dideu.com	China	8026	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 +8617705817739	info@dycnchem.com	China	52846	58
PT CHEM GROUP LIMITED	+86-85511178;	peter68@ptchemgroup.com	China	35425	58
GIHI CHEMICALS CO.,LIMITED	+8618058761490	info@gihichemicals.com	China	49947	58
Shanghai Acmec Biochemical Technology Co., Ltd.	+86-18621343501; +undefined18621343501	product@acmec-e.com	China	33338	58
Aladdin Scientific		tp@aladdinsci.com	United States	57505	58
SHANGHAI KEAN TECHNOLOGY CO., LTD.	+8613817748580	cooperation@kean-chem.com	China	40066	58

Supplier	Advantage
CONIER CHEM AND PHARMA LIMITED	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Xi'an MC Biotech, Co., Ltd.	58
Shaanxi Dideu Medichem Co. Ltd	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
PT CHEM GROUP LIMITED	58
GIHI CHEMICALS CO.,LIMITED	58
Shanghai Acmec Biochemical Technology Co., Ltd.	58
Aladdin Scientific	58
SHANGHAI KEAN TECHNOLOGY CO., LTD.	58

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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) TRETRACHLOROBIS-(TETRAHYDROFURAN)-TITANIUM(IV) TITANIUM TETRACHLORIDE BIS(TETRAHYDROFURAN) COMPLEX TITANIUM TETRACHLORIDE TETRAHYDROFURAN COMPLEX TITANIUM(IV) CHLORIDE TETRAHYDROFURAN COMPLEX (1:2) TetrachlorobistetrahydrofurantitaniumIVminyellowxtl Titanium(IV) chloride tetrahydrofuran complex Tetrachlorobis(tetrahydrofurane)titanium(IV) TITANIUM(IV) CHLORIDE-TETRAHYDOFURAN COMPLEX Tetrachlorobis(tetrahydrofuran)titanium(IV),min.97% Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97% Titanium(iv) chloride tet Titanium(IV) chloride tetrahydrofuran complex 97% Tetrachlorobis(tetrahydrofuran)titanium (IV), 97+% Bis(tetrahydrofuran)tetrachlorotitanium Tetrachlorobis(THF)titanium Titanium tetrachloride bis(tetrahydrofuran) oxolane:tetrachlorotitanium TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) ISO 9001：2015 REACH Titanium (IV) Chloride THF Complex 31011-57-1 C8H16Cl4O2Ti TiCl42C4H8O TiCl42THF 2C4H8OCl4Ti TiCl4C4H8O2 Lewis Acids Synthetic Reagents Titanium metal halide