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Titanium tetraisopropanolate

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Titanium tetraisopropanolate
Titanium tetraisopropanolate structure
CAS No.
546-68-9
Chemical Name:
Titanium tetraisopropanolate
Synonyms
TTIP;A-1(TPT);TYZOR TP;tyzortpt;tiisopropylate;VERTEC(TM) TIPT;titanium(4+)salt;Iso-propy titanate;ISOPROPYL TITANATE;Titaniumispropoxide
CBNumber:
CB3363214
Molecular Formula:
C12H28O4Ti
Formula Weight:
284.22
MOL File:
546-68-9.mol

Titanium tetraisopropanolate Properties

Melting point:
14-17 °C(lit.)
Boiling point:
232 °C(lit.)
Density 
0.96 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.464(lit.)
Flash point:
72 °F
storage temp. 
Flammables area
solubility 
Soluble in anhydrous ethanol, ether, benzene and chloroform.
form 
Liquid
color 
Colorless to pale yellow
Specific Gravity
0.955
Water Solubility 
HYDROLYSIS
FreezingPoint 
14.8℃
Sensitive 
Moisture Sensitive
Merck 
14,9480
BRN 
3679474
Stability:
Stable, but decomposes in the presence of moisture. Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable.
InChIKey
VXUYXOFXAQZZMF-UHFFFAOYSA-N
CAS DataBase Reference
546-68-9(CAS DataBase Reference)
EPA Substance Registry System
2-Propanol, titanium(4+) salt(546-68-9)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi,F
Risk Statements  10-36-36/37/38-11-67
Safety Statements  16-26-36/37/39-7/9
RIDADR  UN 2413 3/PG 3
WGK Germany  2
RTECS  NT8060000
21
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29051900
Hazardous Substances Data 546-68-9(Hazardous Substances Data)
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240 Ground/bond container and receiving equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.

Titanium tetraisopropanolate price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 205273 Titanium(IV) isopropoxide 97% 546-68-9 1l $107 2018-11-13 Buy
Sigma-Aldrich 205273 Titanium(IV) isopropoxide 97% 546-68-9 2l $192 2018-11-13 Buy
TCI Chemical T0133 Tetraisopropyl Orthotitanate 546-68-9 25g $14 2018-11-22 Buy
TCI Chemical T0133 Tetraisopropyl Orthotitanate 546-68-9 500g $47 2018-11-22 Buy
Alfa Aesar 077115 Titanium(IV) isopropoxide, 97+% 546-68-9 10g $24.9 2018-11-16 Buy

Titanium tetraisopropanolate Chemical Properties,Uses,Production

Reactions

Chemical Properties

colourless to light yellow liquid

Uses

Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.

General Description

A water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water and . Flash point 66°F. Vapors heavier than air.

Air & Water Reactions

Highly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol.

Reactivity Profile

Metal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Purification Methods

Dissolve it in dry *C6H6 , filter if a solid separates, evaporate and fractionate. It is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o. [Bradley et al. J Chem Soc 2027, 1952, Bradley et al. J Chem Soc 469 1957, Beilstein 1 II 328, 1 IV 1469S.]

Titanium tetraisopropanolate Preparation Products And Raw materials

Raw materials

Preparation Products


Titanium tetraisopropanolate Suppliers

Global( 249)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Shenzhen Sendi Biotechnology Co.Ltd.
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Dalian Richfortune Chemicals Co., Ltd
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Shanghai Time Chemicals CO., Ltd.
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View Lastest Price from Titanium tetraisopropanolate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-16 Titanium tetraisopropanolate
546-68-9
US $1.00 / g 20kg 98% 1000KG career henan chemical co
2019-03-08 Titanium tetraisopropanolate
546-68-9
US $0.00 / kg 200kg 96% 1000MT Hefei TNJ Chemical Industry Co.,Ltd.

Titanium tetraisopropanolate Spectrum


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