ChemicalBook >> CAS DataBase List >>Titanium tetraisopropanolate
Titanium tetraisopropanolate
- CAS No.
- 546-68-9
- Chemical Name:
- Titanium tetraisopropanolate
- Synonyms
- TITANIUM ISOPROPOXIDE;TITANIUM(IV) ISOPROPOXIDE;TITANIUM TETRAISOPROPOXIDE;TTIP;tetraisopropoxytitanium;TETRAISOPROPYL TITANATE;ISOPROPYL TITANATE;Titanium(Ⅳ) isopropoxide;TETRAISOPROPYL ORTHOTITANATE;TITANIUM(IV) TETRAISOPROPOXIDE
- CBNumber:
- CB3363214
- Molecular Formula:
- C12H28O4Ti
- Molecular Weight:
- 284.22
- MDL Number:
- MFCD00008871
- MOL File:
- 546-68-9.mol
- MSDS File:
- SDS
Last updated:2023-12-22 17:53:22
| Melting point | 14-17 °C(lit.) |
|---|---|
| Boiling point | 232 °C(lit.) |
| Density | 0.96 g/mL at 20 °C(lit.) |
| vapor pressure | 60.2hPa at 25℃ |
| refractive index |
n |
| Flash point | 72 °F |
| storage temp. | Flammables area |
| solubility | Soluble in anhydrous ethanol, ether, benzene and chloroform. |
| form | Liquid |
| Specific Gravity | 0.955 |
| color | Colorless to pale yellow |
| Water Solubility | HYDROLYSIS |
| FreezingPoint | 14.8℃ |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| Merck | 14,9480 |
| BRN | 3679474 |
| Stability | Stable, but decomposes in the presence of moisture. Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable. |
| InChIKey | VXUYXOFXAQZZMF-UHFFFAOYSA-N |
| LogP | 0.05 |
| Indirect Additives used in Food Contact Substances | TITANIUM TETRAISOPROPYLATE |
| FDA 21 CFR | 175.105 |
| CAS DataBase Reference | 546-68-9(CAS DataBase Reference) |
| FDA UNII | 76NX7K235Y |
| EPA Substance Registry System | 2-Propanol, titanium(4+) salt (546-68-9) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226-H319-H336 | |||||||||
| Precautionary statements | P210-P233-P240-P241-P242-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,F | |||||||||
| Risk Statements | 10-36-36/37/38-11-67 | |||||||||
| Safety Statements | 16-26-36/37/39-7/9 | |||||||||
| RIDADR | UN 2413 3/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | NT8060000 | |||||||||
| F | 21 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29051900 | |||||||||
| NFPA 704 |
|
Titanium tetraisopropanolate price More Price(51)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 205273 | Titanium(IV) isopropoxide 97% | 546-68-9 | 1l | $145 | 2024-03-01 | Buy |
| Sigma-Aldrich | 205273 | Titanium(IV) isopropoxide 97% | 546-68-9 | 2l | $263 | 2024-03-01 | Buy |
| TCI Chemical | T0133 | Tetraisopropyl Orthotitanate | 546-68-9 | 25g | $17 | 2024-03-01 | Buy |
| TCI Chemical | T0133 | Tetraisopropyl Orthotitanate | 546-68-9 | 500g | $49 | 2024-03-01 | Buy |
| Alfa Aesar | 077115 | Titanium(IV) isopropoxide, 97+% | 546-68-9 | 10g | $31.65 | 2024-03-01 | Buy |
Titanium tetraisopropanolate Chemical Properties,Uses,Production
Reactions
- Catalyst for the synthesis of acyclic epoxy alcohols and allylic epoxy alcohols.
- Useful for diastereoselective reduction of alpha-fluoroketones.
- Catalyzes the asymmetric allylation of ketones.
- Reagent for the synthesis of cyclopropylamines from aryl and alkenyl nitriles.
- Useful for racemic and/or enantioselective addition of nucleophiles to aldehydes, ketones and imines.
- Catalytic intramolecular formal [3+2] cycloaddition.
- Catalyst for the synthesis of cyclopropanols from esters and organomagnesium reagents
Chemical Properties
colourless to light yellow liquid
Uses
Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.
Uses
Titanium(IV) isopropoxide is used as a precursor for the preparation of titanium and barium-strontium-titanate thin films. It is useful to make porous titanosilicates and potential ion-exchange materials for cleanup of radioactive wastes. It is an active component of Sharpless epoxidation as well as involved in the synthesis of chiral epoxides. In Kulinkovich reaction, it is involved as a catalyst in the preparation of cyclopropanes.
Definition
ChEBI: Titanium(IV) isopropoxide is a titanium coordination entity consisting of a titanium(IV) cation with four propan-2-olate anions as counterions.
General Description
Tetraisopropyl titanate appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water. Vapors heavier than air.
Air & Water Reactions
Highly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol.
Reactivity Profile
Metal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.
Health Hazard
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Flammability and Explosibility
Flammable
Purification Methods
Dissolve it in dry *C6H6 , filter if a solid separates, evaporate and fractionate. It is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o. [Bradley et al. J Chem Soc 2027, 1952, Bradley et al. J Chem Soc 469 1957, Beilstein 1 II 328, 1 IV 1469S.]
Titanium tetraisopropanolate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of2
Global( 409)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Zouping mingyuan import & export trading co., ltd | +86-0543-2240078 +8618364991597 | myzhao793@163.com | China | 994 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
| Anhui Ruihan Technology Co., Ltd | +8617756083858 | daisy@anhuiruihan.com | China | 994 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7845 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Dalian Richfortune Chemicals Co., Ltd | 0411-84820922 8613904096939 | sales@richfortunechem.com | China | 303 | 57 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
| Anhui Royal Chemical Co., Ltd. | +86-25-86655873 +8613962173137 | marketing@royal-chem.com | China | 142 | 55 |
View Lastest Price from Titanium tetraisopropanolate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-26 | Titanium tetraisopropanolate
546-68-9
|
US $5.00 / kg | 1kg | ≥99% | 100mt/year | Jinan Finer Chemical Co., Ltd | |
 |
2024-04-15 | Titanium(4+) tetrapropan-2-olate
546-68-9
|
US $1.00-100.00 / mg | 100mg | 98.0% | 5ton/month | ANHUI SHENGZHIKAI BIOTECHNOLOGY CO.,LTD | |
 |
2024-04-09 | Titanium(IV) isopropoxide
546-68-9
|
US $3200.00 / T | 1T | 99% | 600T | Shandong Luning Pharmaceutical Co., Ltd. |
-
- Titanium tetraisopropanolate
546-68-9
- US $5.00 / kg
- ≥99%
- Jinan Finer Chemical Co., Ltd
-
- Titanium(4+) tetrapropan-2-olate
546-68-9
- US $1.00-100.00 / mg
- 98.0%
- ANHUI SHENGZHIKAI BIOTECHNOLOGY CO.,LTD
-
- Titanium(IV) isopropoxide
546-68-9
- US $3200.00 / T
- 99%
- Shandong Luning Pharmaceutical Co., Ltd.
546-68-9(Titanium tetraisopropanolate)Related Search:
TITANIUM ISO-PROPYLATE
TITANIUM (IV) I-PROPOXIDE
TITANIUM (IV) TETRA-I-PROPOXIDE
Titanium tetraisopropanolate
TITANIUM TETRAISOPROPYLATE
TITANIUM(+4)ISOPROPOXIDE
TITANIC ACID TETRAISOPROPYL ESTER
ORTHOTITANIC ACID TETRAISOPROPYL ESTER
TYZOR(R) ORGANIC TITANATE
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tetrakis(isopropoxy)titanium
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Titanium(IV) isopropoxide, 99.999% metals basis
TITANIUM(IV) ISOPROPOXIDE, FOR CAMBRIDG&
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Titanium(IV)isopropoxide,95%
Titanium(IV)isopropoxide,99.995%(metalsbasis)
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titanium(iv) isopropoxide, vertec
TETRA-ISO-PROPYL-O-TITANATE
Titantetraisopropanolat
2-Propanol, titanium salt
Titanium(IV) isopropoxide, VERTEC(R) TIPT, 97+%
Isopropyl titanate(IV): (Titanium(IV) isopropoxide)
Titanium (IV) isopropoxide, 97% min
Titanium(IV) isopropoxide, VERTEC TIPT, 97+%
Iso-propy titanate
Tetraisopropoxytitanium(IV)
Titanium(IV) i-propoxide, min. 98%
Titanium(IV) isopropoxide, 99.995% trace metals basis
Tetraisopropyl Titanate(monomer) 〔Titanium(Ⅳ) Isopropoxide〕
Titanium(IV) isopropoxide, 97+%
titanicacidisopropylester
titanium(4+)salt
titaniumisopropoxide(ti(oc3h7)4)
Titaniumispropoxide
TYZOR organic titanate
Titanium(IV) isopropoxide/ 99.99%
Titanium(IV) isopropoxide,Tetraisopropyl orthotitanate
Titanium(IV) isoprop
Titanium(IV) i-propoxide, min. 98%, 93-2216, contained in 50 ml Swagelok cylinder for CVD/ALD
Tetra Isopropyl Titanate (TIPT)
Titanium(IV) Isopropoxide 99.999%
TitaniuM(IV) isopropoxide, 98+% 250ML
Tetra-isopropyl Titanate,Tetra-isopropoxytitaniuM
Isopropyl Titanate
Tetraisopropyl Titanate
Titanium(IV) Isopropoxide
Titanium(IV) Tetraisopropoxide
TIPT TETRAISOPROPYL TITANATE
EsoMeprazo interMediate E
TitaniuM(IV) isopropoxide >=97.0%
TitaniuM(IV) isopropoxide 97%
TitaniuM(IV) isopropoxide 99.999% trace Metals basis
2-Propanol,titanium(4+)salt
2-propanol,titanium(4++)salt
isopropylalcohol,titanium(4+)salt