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(2R)-Bornane-10,2-sultam

(2R)-Bornane-10,2-sultam structure

CAS No.: 94594-90-8

Chemical Name:: (2R)-Bornane-10,2-sultam

Synonyms: D-SultaM;(1S,2R)-(-)-;(2R)-Bornane-10;L-(+)-CAMPHOR SULTAM;(2R)-Bornane-10,2-su;(-)-10,2-CAMPHORSULTAM;(1S)-(-)-Camphorsultam;(2R)-Borne-10,2-sultam;(-)-2,10-Camphorsultam;(1S)-2,10-CAMPHORSULTAM

CBNumber:: CB9468760

Molecular Formula:: C10H17NO2S

Molecular Weight:: 215.31

MDL Number:: MFCD00066271

MOL File:: 94594-90-8.mol

Last updated:2024-04-24 17:21:45

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(2R)-Bornane-10,2-sultam Properties

Melting point	183-185 °C
alpha	-33 º (c=4.9, CHCl3)
Boiling point	324.8±25.0 °C(Predicted)
Density	1.1469 (rough estimate)
refractive index	-31 ° (C=1, CHCl3)
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform, Ethanol, Methanol
form	Liquid
pka	11.05±0.40(Predicted)
color	Clear colorless
optical activity	[α]19/D 32°, c = 5 in chloroform
Water Solubility	Slightly soluble in water.
BRN	83811
CAS DataBase Reference	94594-90-8(CAS DataBase Reference)
NIST Chemistry Reference	(-)-10,2-Camphorsultam(94594-90-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-37/39-36

WGK Germany

HS Code

29349990

NFPA 704

	1
2		0

(2R)-Bornane-10,2-sultam price More Price(34)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	298352	(1S)-(?)-2,10-Camphorsultam 98%	94594-90-8	5g	$94.2	2024-03-01	Buy
TCI Chemical	C1325	(-)-10,2-Camphorsultam >98.0%(GC)	94594-90-8	1g	$25	2024-03-01	Buy
TCI Chemical	C1325	(-)-10,2-Camphorsultam >98.0%(GC)	94594-90-8	5g	$64	2024-03-01	Buy
Alfa Aesar	A15897	(1S,2R)-(-)-10,2-Camphorsultam, 99%	94594-90-8	5g	$196.65	2024-03-01	Buy
Alfa Aesar	A15897	(1S,2R)-(-)-10,2-Camphorsultam, 99%	94594-90-8	1g	$68.5	2021-12-16	Buy

Product number	Packaging	Price	Buy
298352	5g	$94.2	Buy
C1325	1g	$25	Buy
C1325	5g	$64	Buy
A15897	5g	$196.65	Buy
A15897	1g	$68.5	Buy

(2R)-Bornane-10,2-sultam Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

(1S)-(?)-2,10-Camphorsultam may be used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It may be used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones.

Uses

(1S,2R)-(-)-10,2-Camphorsultam is used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It is used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. It is also employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. Also used to prepare N-acryloyl derivatives which are employed as dienophiles in asymmetric Diels-Alder reactions. and for other asymmetric transformations.

Uses

(2R)-Bornane-10,2-sultam is a reagent used to make Camphorsultam conjugates.

General Description

(1S,2R,4R)-(?)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids.

Purification Methods

The (-)-enantiomer is recrystallised from 95% EtOH and dried in a vacuum desiccator. It dissolves in dilute aqueous NaOH and can be precipitated without hydrolysis by acidifying. It forms the N-Na salt in EtOH (by addition of Na to the EtOH solution), and the salt can be methylated with MeI to give the (-)-N-Me lactam with m 80o after recrystallisation from hot H2O and has []D -59.6o (c 5, CHCl3) [Shriner et al. J Am Chem Soc 60 2794 1938]. [Oppolzer et al. Helv Chim Acta 69 1142 1986, Weismiller et al. Org Synth 69 154 1955, Beilstein 27 III/IV 1007.]

(2R)-Bornane-10,2-sultam synthesis

Synthesis of (2R)-Bornane-10,2-sultam from Methanone, [(5R)-4,5-dihydro-3-methyl-5-isoxazolyl][(3aS,6R,7aR)-tetrahydro-8,8-dimethyl-2,2-dioxido-3H-3a,6-methano-2,1-benzisothiazol-1(4H)-yl]-

(2R)-Bornane-10,2-sultam Preparation Products And Raw materials

Raw materials

Preparation Products

(2R)-BORNANE-10,2-SULTAM GLYCINATE (N-CROTONYL)-(2R)-BORNANE-10,2-SULTAM

(2R)-Bornane-10,2-sultam Suppliers

Global( 264)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Jingbo New Material Technology Co., Ltd	+8619931165850	hbjbtech@163.com	China	1000	58
Hebei Saisier Technology Co., LTD	+86-18400010335 +86-18034520335	admin@hbsaisier.cn	China	938	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15957	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32686	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58
Hebei Guanlang Biotechnology Co., Ltd.	+86-19930503282	alice@crovellbio.com	China	8822	58
Xi'an Kono chem co., Ltd.,	029-86107037 13289246953	info@konochemical.com	China	2995	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58

Supplier	Advantage
Hebei Jingbo New Material Technology Co., Ltd	58
Hebei Saisier Technology Co., LTD	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Accela ChemBio Inc.	58
Hebei Guanlang Biotechnology Co., Ltd.	58
Xi'an Kono chem co., Ltd.,	58
Chongqing Chemdad Co., Ltd	58

View Lastest Price from (2R)-Bornane-10,2-sultam manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-24	(2R)-Bornane-10,2-sultam 94594-90-8	US $6.00 / KG	1KG	More than 99%	2000KG/MONTH	Hebei Saisier Technology Co., LTD
2023-12-27	(2R)-Bornane-10,2-sultam 94594-90-8	US $8.00 / kg	1kg	99%	200000	Hebei Jingbo New Material Technology Co., Ltd
2023-02-18	(1S)-(-)-2,10-Camphorsultam 94594-90-8	US $0.00-0.00 / kg	1kg	98%	kgs	Aromsyn Co., Ltd.

(2R)-Bornane-10,2-sultam
94594-90-8
US $6.00 / KG
More than 99%
Hebei Saisier Technology Co., LTD

(2R)-Bornane-10,2-sultam
94594-90-8
US $8.00 / kg
99%
Hebei Jingbo New Material Technology Co., Ltd

(1S)-(-)-2,10-Camphorsultam
94594-90-8
US $0.00-0.00 / kg
98%
Aromsyn Co., Ltd.

(2R)-Bornane-10,2-sultam Spectrum

(2R)-Bornane-10,2-sultam(94594-90-8)MS (2R)-Bornane-10,2-sultam(94594-90-8)¹HNMR (2R)-Bornane-10,2-sultam(94594-90-8)IR1 (2R)-Bornane-10,2-sultam(94594-90-8)IR2 (2R)-Bornane-10,2-sultam(94594-90-8)Raman

94594-90-8((2R)-Bornane-10,2-sultam)Related Search:

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Ethyl (S)-9,10-difluoro-3-methyl-7-oxo-2,3-dihydro-7H-pyrido[1,2,3-de]-1,4-benzoxazine-6-carboxylate 3-METHOXY-DL-TYROSINE L(-)-Carvone

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(-)-EXO-10,2-BORNANESULTAM (-)-D-2,10-CAMPHORSULTAM (-)-D-2,10-CAMPHOSULTAM D(-)-10,2-CAMPHORSULTAME (2R)-BORNANE-10,2-SULTAM (1S)-(-)-2,10-CAMPHORSULTAM (1S)-2,10-CAMPHORSULTAM (1S,2R)-(-)-2,10-CAMPHORSULTAM (1S,5R)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.0(1,5)]DECANE 3,3-DIOXIDE (-)-10,2-CAMPHORSULTAM [3AS-(3A-ALPHA,6-ALPHA,7A-BETA)]-HEXAHYDRO-8,8-DIMETHYL-2,2-DIOXIDE-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE [3as-(3aalpha,6alpha,7abeta)]-hexahydro-8,8-dimethyl-2,2-dioxide-3h-3a,6-methano-2,1-benzisothiazole [3AS-(3AALPHA,6ALPHA,7ABETA)]-HEXAHYDRO-8,8-DIMETHYL-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE-2,2-DIOXIDE (1S)-(-)-Camphorsultam (1S,2R)-(-)-10,2-Camphorsultam (1S,2R)-(-)-2,10-CAMPHORSULTAME 3H-3a,6-Methano-2,1-benzisothiazole, hexahydro-8,8-dimethyl-, 2,2-dioxide, (3aS,6R,7aR)- (-)-exo-10,2-Bornanesultam, (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide (-)-10,2-Camphorsultam, (-)-exo-10,2-Bornanesultam, [3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide, (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide (2R)-10,2-Camphorsultam (2R)-Bornane-10,2-sultam, 99+%, ee:>99% D-(+)-CAMPHOR SULTAM INFRA-ACIDAMIDE L-(+)-CAMPHOR SULTAM (IS)-(-)-2,10-Camphorsultam (2R)-Bornane-10,2-sultam ,98% [3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide (2R)-Bornane-10,2-sultam99+%(>99% ee) (3aR)-Hexahydro-8,8-dimethyl-3H-3aα,6α-methano-2,1-benzisothiazole 2,2-dioxide (3aS)-1,3,5,6,7,7aα-Hexahydro-4H-3aβ,6β-isopropylidene-2,1-benzisothiazole 2,2-dioxide (3aS)-1,4,5,6,7,7aα-Hexahydro-8,8-dimethyl-3H-3aβ,6β-methano-2,1-benzisothiazole 2,2-dioxide (3aS,7aα)-8,8-Dimethyl-3aβ,6β-methanooctahydro-2,1-benzisothiazole 2,2-dioxide (7aα)-8,8-Dimethyl-3aβ,6β-methanooctahydro-2,1-benzisothiazole 2,2-dioxide [3aS,7aα,(-)]-Hexahydro-8,8-dimethyl-3H-3aβ,6β-methano-2,1-benzisothiazole 2,2-dioxide (1S,2R)-(-)- (2R)-Bornane-10,2-su (2R)-Bornane-1,2-sultaM (1S)-(-)-10,2-CaMphorsultaM Hexahydro-8,8-diMethyl-3H-3a,6-Methano-2,1-benzisothiazole D-SultaM (2R)-Bornane-10,2-sultam (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0(1,5)]decane 3,3-Dioxide (2R)-Bornane-10,2-sultaM, 99+% (1S,2R)-(-)-2,10-CAMPHORSULTAME FOR SYNT (3aS,6S,7aS)-8,8-DiMethylhexahydro-1H-3a,6-Methanobenzo[c]isothiazole 2,2-dioxide (2R)-Bornane-10,2-sultam (1S)-(-)-2,10-Camphorsultam (1S)-(-)-2,10-Camphorsultam (2R)-Borne-10,2-sultam D-2,10-Camphorsultam,99%e.e. (2R)-Bornane-10, 2-sultam, ≥99% ee (-)-10,2-Camphorsultam > (1S)-(?)-2,10-CamphorsuL (-)-10,2-Camphorsultam? (1S)-(-)-2,11-Camphorsultam (2R)-Bornane-10,2-sultam ISO 9001：2015 REACH (-)-2,10-Camphorsultam (1S,2R)-(-)-10,2-Camphorsultam, 99%, (5R,7R)-10,10-dimethyl-3thia-4-azatricyclo[5.2.1.01?]decane 3,3-dioxide (3aS,6R,7aR)-8,8-Dimethylhexahydro-1H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide (2R)-Bornane-10