ジクロロペルスルフィド

ジクロロペルスルフィド 化学構造式
10025-67-9
CAS番号.
10025-67-9
化学名:
ジクロロペルスルフィド
别名:
塩化硫黄;二塩化二硫黄;ジクロロペルスルフィド;一化硫黄;一塩化いおう
英語名:
Disulfur dichloride
英語别名:
S2Cl2;SULFUR MONOCHLORIDE;SULFUR CHLORIDE;SULPHUR MONOCHLORIDE;ClSSCl;U.N. 1828;Chlorschwefel;Chlorosulfane;siarkichlorek;Sulfor choride
CBNumber:
CB2776712
化学式:
Cl2S2
分子量:
135.04
MOL File:
10025-67-9.mol
MSDS File:
SDS

ジクロロペルスルフィド 物理性質

融点 :
−80 °C(lit.)
沸点 :
138 °C(lit.)
比重(密度) :
1.688 g/mL at 25 °C(lit.)
蒸気密度:
4.7 (vs air)
蒸気圧:
6.8 mm Hg ( 20 °C)
屈折率 :
n20/D 1.658(lit.)
闪点 :
>130℃
貯蔵温度 :
Store below +30°C.
溶解性:
soluble in No data available
外見 :
黄赤色油状液体
色:
yellow-red oily liquid
爆発限界(explosive limit):
4.2-32.5%(V)
水溶解度 :
反応する
Merck :
13,9060
Dielectric constant:
4.8(15℃)
CAS データベース:
10025-67-9(CAS DataBase Reference)
NISTの化学物質情報:
Disulfur dichloride(10025-67-9)
EPAの化学物質情報:
Sulfur monochloride (10025-67-9)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T,C,N
Rフレーズ  14-20-25-29-35-50-67-40-37-22
Sフレーズ  26-36/37/39-45-61
RIDADR  UN 3390 6.1/PG 1
WGK Germany  3
RTECS 番号 WS4300000
自然発火温度 451 °F
国連危険物分類  8
容器等級  I
HSコード  28121091
有毒物質データの 10025-67-9(Hazardous Substances Data)
毒性 LD50 orally in Rabbit: 132 mg/kg
IDLA 5 ppm
絵表示(GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
注意喚起語 危険
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H314 重篤な皮膚の薬傷?眼の損傷 皮膚腐食性/刺激性 1A, B, C 危険 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H400 水生生物に強い毒性 水生環境有害性、急性毒性 1 警告 GHS hazard pictograms P273, P391, P501
注意書き
P261 粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P303+P361+P353 皮膚(または髪)に付着した場合:直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。
P305+P351+P338 眼に入った場合:水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

ジクロロペルスルフィド 価格 もっと(7)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
Sigma-Aldrich Japan 157759 一塩化硫黄 98%
Sulfur monochloride 98%
10025-67-9 50g ¥6300 2024-03-01 購入
Sigma-Aldrich Japan 157759 一塩化硫黄 98%
Sulfur monochloride 98%
10025-67-9 250g ¥7540 2024-03-01 購入
Sigma-Aldrich Japan 157759 一塩化硫黄 98%
Sulfur monochloride 98%
10025-67-9 1kg ¥12600 2024-03-01 購入
Sigma-Aldrich Japan 293113 一塩化硫黄 溶液 1.0?M in methylene chloride
1.0?M in methylene chloride
10025-67-9 100ML ¥7790 2023-06-01 購入
純正化学株式会社 15375-1530 98.0%+
Disulfur dichloride Sulfur monochloride 98.0%+
10025-67-9 500ml ¥4100 2024-03-01 購入

ジクロロペルスルフィド MSDS


Sulfur chloride

ジクロロペルスルフィド 化学特性,用途語,生産方法

外観

無色~黄褐色, 澄明の液体

溶解性

水に分解, アルコール, ベンゼン, エーテル, 二硫化炭素, 酢酸アミルに可溶。エタノール及びアセトンに溶け、水により分解し、硫黄、硫化水素、亜硫酸塩及びチオ硫酸塩を生成する。

用途

硫黄の溶剤、塩化チオニル、四塩化炭素、二硫化炭素などの製造、織物仕上げ、糖汁精製、殺虫剤、金?銀の抽出などに使用

使用上の注意

アルゴン封入

化学的特性

Disulfur dichloride is a fuming, oily liquid with a yellowish-red to amber color and a suffocating odor. Soluble in alcohol, ether, benzene, carbon disulfide, and amyl acetate; decomposes on contact withwater. Combustible. It has an added hazard since it oxidizes and hydrolyzes to sulfur dioxide and hydrogen chloride.

使用

Disulfur dichloride is used as Intermediate and chlorinating agent in the manufacture of organic chemicals, sulfur dyes, insecticides, synthetic rubbers; in cold vulcanization of rubber; as polymerization catalyst for vegetable oils; for hardening soft woods. The chemical fiber industry is used as a finishing agent for the manufacture of fabrics. The metallurgical industry is used as an extraction agent for precious and rare metals such as gold and silver.

定義

Disulfur dichloride is a red fuming liquid with a strong smell. It is prepared by passing chlorine over molten sulfur and is used to harden rubber.

一般的な説明

Sulfur monochloride appears as a yellow-red, oily, fuming liquid with a sharp odor. Contact or ingestion causes irritation or chemical burns to skin, eyes, and mucous membranes. Also poisonous by inhalation of vapors.

健康ハザード

Sulfur monochloride is an irritant of the eyes, mucous membranes, and skin. On contact with water, it decomposes to form hydrogen chloride and sulfur dioxide; because this occurs rapidly, it acts primarily as an upper respiratory irritant and does not ordinarily reach the lungs. However, exposure to high concentrations may cause pulmonary edema.

安全性プロファイル

Poison by ingestion and inhalation. A fuming, corrosive liquid very irritating to shin, eyes, and mucous membranes. It decomposes on contact with water to form the highly irritating hydrogen chloride, thiosulfuric acid, and sulfur. Its toxic effects are irritating to the upper respiratory tract, although the results of intoxication are usually transitory in nature. However, if hydrolysis is not complete in the upper respiratory tract, injury to the broncholes and alveoli can result. A fire hazard when in contact with organic matter, P203, Na2O2, water, Cr(OCl)2. Combustible when exposed to heat or flame. Will react with water or steam to produce heat and toxic and corrosive fumes. Can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits highly toxic fumes of Cland SOX.

職業ばく露

Sulfur chloride finds use as a chlorinating agent, catalyst, and as an intermediate in the manufacture of organic chemicals; carbon tetrachloride; sulfur dyes; insecticides, synthetic rubber; and pharmaceuticals. Exposure may also occur during the extraction of gold, purification of sugar juice; finishing and dyeing textiles; processing vegetable oils; hardening wood; and vulcanization of rubber. Has been used as a military poison.

輸送方法

UN1828 Sulfur chlorides, Hazard class: 8; Labels: 8-Corrosive material, Potential Inhalation Hazard (Special Provision 5)

純化方法

It isa pungent, irritating golden yellow liquid. When impure its colour is orange to red due to SCl2 formed. It fumes in moist air and liberates HCl, SO2 and H2S in the presence of H2O. Distil it and collect the fraction boiling above 137o at atmospheric pressure. Fractionate this fraction over sulfur at ca 12mm using a ground glass apparatus (b 29-30o). Alternatively purify it by distillation below 60o from a mixture containing sulfur (2%) and activated charcoal (1%), under reduced pressure (e.g. 50mm). It is soluble in EtOH, *C6H6, Et2O, CS2 and CCl4. Store it in a closed container in the dark in a refrigerator. [Fehér in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 371 1963.] HARMFUL VAPOURS.

不和合性

Decomposes violently in water, forming hydrochloric acid, sulfur dioxide; sulfur, sulfite, thiosulfate, and hydrogen sulfide. Reacts with oxidizers, strong bases; peroxides, phosphorus oxides; organics, antimony, antimony sulfide; arsenic sulfide; mercury oxide; tin, alkenes, terpenes, unsaturated glycerides; chromyl chloride; methyl sulfoxide; dimethylformamide, acetone, and other compounds; causing fire and explosion hazard. Corrosive to many metals in presence of water. Attacks some plastics, rubber and coatings.

廃棄物の処理

Wearing protective equipment, spray carefully onto sodium ash/slaked lime mixture. Then spray with water, dilute, neutralize and flush to drain.

予防処置

Sulfur monochloride is minimally corrosive to carbon steel and iron when dry. When wet, it behaves like hydrochloric acid and attacks steel, cast iron, aluminum, stainless steels, copper and copper alloys, and many nickel-based materials.

ジクロロペルスルフィド 上流と下流の製品情報

原材料

準備製品


ジクロロペルスルフィド 生産企業

Global( 105)Suppliers
名前 電話番号 電子メール 国籍 製品カタログ 優位度
ARCTIC EXPORTS INC
+1-3026880818 +1-3026880818
ARCTICEXPORTSINC@GMAIL.COM Canada 68 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21691 55
career henan chemical co
+86-0371-86658258
sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22968 58
Shandong chuangyingchemical Co., Ltd.
18853181302
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Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873
sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
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Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671
sales@tnjchem.com China 34572 58
Shaanxi Didu New Materials Co. Ltd
+86-89586680 +86-13289823923
1026@dideu.com China 9116 58

10025-67-9(ジクロロペルスルフィド)キーワード:


  • 10025-67-9
  • DISULFUR DICHLORIDE
  • Sulfor choride
  • SulfureChloride
  • SULPHURCHLORIDE
  • U.N. 1828
  • SULFUR (I) CHLORIDE
  • SULPHURE CHLORIDE
  • Chlorosulfane
  • Chlorschwefel
  • cloruredesoufre
  • ClSSCl
  • dichlorodisulfane
  • Dischwefeldichlorid
  • disulphurdichloride
  • Schwefelmonochlorid
  • Siarki chlorek
  • siarkichlorek
  • siarkichlorek(polish)
  • Sulfur chloride (S2Cl2)
  • Sulfur chloride(di)
  • Sulfur subchloride
  • sulfurchloride(di)
  • sulfurchloride(s2cl2)
  • sulfurchlorides
  • sulfursubchloride
  • sulphursubchloride
  • Thiosulfurous dichloride
  • thiosulfurousdichloride
  • thiosulphurousdichloride
  • disulphur dichloride sulfur monochloride
  • 塩化硫黄
  • 二塩化二硫黄
  • ジクロロペルスルフィド
  • 一化硫黄
  • 一塩化いおう
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