지넵 C화학적 특성, 용도, 생산
개요
Zineb is a light-coloured powder/crystal and insoluble in water. Zineb is one of the nonsystemic
(surface-acting) fungicides of the group ethylenebisdithiocarbamates (EBDCs).
Zineb is a polymer of ethylene (bis)thiocarbamate units linked with zinc and used for the
control and prevention of crop damage in the field and also to protect harvested crops from
deterioration during storage or transport. Zineb was used to protect fruit and vegetable
crops from a wide range of foliar and other diseases. It was available in the United States
as wettable powder and dust formulations. Zineb can be formed by combining nabam and
zinc sulphate in the spray tank.
화학적 성질
Pure product is white crystal, industrial product is white to light yellow powder. Soluble in carbon disulfide and pyridine, insoluble in most organic solvents, insoluble in water (10mg/L). It is unstable to light, heat and humidity, and decomposes easily when it meets alkaline substances or copper. The decomposition products of zineb include ethylene thiourea, which is more toxic.
용도
Zineb is a contact fungicide that provides protection against a
wide variety of fungal diseases (including leaf spots, blights, rust, downy
mildew, scab, etc.) in field crops, fruits, vines, vegetables, ornamentals,
citrus and bananas.
정의
ChEBI: Zineb is a polymeric complex of zinc with the ethylene bis(dithiocarbamate) anionic ligand. Formerly used as an agricultural fungicide for the control of downy mildews and rusts, its use is no longer permitted in the US or the EU. It has a role as an antifungal agrochemical. It is a macromolecule, a zinc coordination entity and a dithiocarbamate salt. It contains an ethylenebis(dithiocarbamate).
일반 설명
An off-white powder. Used as a fungicide.
공기와 물의 반응
Decomposes gradually, accelerated by exposure to air, moisture, and heat. Insoluble in water. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.
반응 프로필
Zineb is a zinc salt of a dithiocarbamic acid. May generate flammable gases with aldehydes, nitrides, and hydrides. Incompatible with acids, peroxides, and acid halides.
위험도
Toxic by inhalation and ingestion; irritant
to eyes and mucous membranes. Questionable carcinogen.
화재위험
Flash point data for Zineb are not available, but Zineb is probably combustible.
색상 색인 번호
Zineb is a pesticide of the dithiocarbamate group.
Sensitization can occur in gardeners and florists.
신진 대사 경로
Zineb and other alkylenebis( dithiocarbamate) fungicides are degraded
and metabolised via a common pathway. The primary degradation
reaction of zineb in water, soil, plants and animals involves the initial
dissociation of the metal complex and decomposition to numerous degradation
products including ethylenethiourea (ETU) and ethyleneurea (EU)
as major products (Scheme 1).
Purification Methods
Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. It is a skin irritant. [Beilstein 4 III 149, 4 IV 234.]
Toxicity evaluation
Zineb has a low mammalian toxicity however, it may cause adverse reproduction/developement effects if ingested. It is moderately toxic to most fauna and flora.
지넵 준비 용품 및 원자재
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