2-METHOXYTETRAHYDROPYRAN

2-METHOXYTETRAHYDROPYRAN 구조식 이미지
카스 번호:
6581-66-4
상품명:
2-METHOXYTETRAHYDROPYRAN
동의어(영문):
2-methoxyoxane;2-METHOXYTETRAHYDROPYRAN;2-methoxy-tetrahydro-pyra;2-Methoxytetrahydropyrane;Pyran,tetrahydro-2-methoxy-;2-Methoxytetrahydro-2H-pyran;tetrahydro-2-methoxy-2h-pyra;tetrahydro-2-methoxy-2h-pyran;2H-Pyran,tetrahydro-2-methoxy-;(R,S)-2-Methoxy-tetrahydro-pyran
CBNumber:
CB6194233
분자식:
C6H12O2
포뮬러 무게:
116.16
MOL 파일:
6581-66-4.mol
MSDS 파일:
SDS

2-METHOXYTETRAHYDROPYRAN 속성

끓는 점
128-129 °C (lit.)
밀도
0.963 g/mL at 25 °C (lit.)
굴절률
n20/D 1.425(lit.)
인화점
77 °F
Specific Gravity
0.963
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F
위험 카페고리 넘버 10
안전지침서 16-29-33
유엔번호(UN No.) UN 1993 3/PG 3
WGK 독일 2
RTECS 번호 UQ0300000
위험 등급 3.2
포장분류 III
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P403+P235 환기가 잘 되는 곳에 보관하고 저온으로 유지하시오.

2-METHOXYTETRAHYDROPYRAN C화학적 특성, 용도, 생산

제조 방법

To a flask equipped with a stirrer and containing 84.0 gm (1.0 mole) of 2,3-dihydropyran in the presence of 1 ml of cone, hydrochloric acid is added 32.0 gm (1.0 mole) of methanol. The reaction is exothermic and is stirred for 3 hr. Then a few pellets of sodium hydroxide are added to make the reaction basic. The mixture is directly distilled to afford 98.6 gm (85%), b.p. 125°C (760 mm Hg).

Preparation of 2-Methoxytetrahydropyran

일반 설명

2-Methoxytetrahydropyran is methoxy-substituted tetrahydropyran. α- and β-glycosidic C1-O1 bonds of the axial and equatorial forms of 2-methoxytetrahydropyran has been investigated by ab initio conformational study. Stereochemical properties of the glycosidic linkage of 2-methoxytetrahydropyran have been studied by the quantum-chemical PCILO method. It undergoes elimination reaction in the gas phase to yield 3, 4-dihydro-2H-pyran and methanol. Proton resonance spectra of 2-methoxytetrahydropyran has been analyzed.

2-METHOXYTETRAHYDROPYRAN 준비 용품 및 원자재

원자재

준비 용품


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