ChemicalBook
Chinese english Germany Japanese Korea

Tetrachlorvinphos Produkt Beschreibung

Tetrachlorvinphos Struktur
22248-79-9
CAS-Nr.
22248-79-9
Bezeichnung:
Tetrachlorvinphos
Englisch Name:
Tetrachlorvinphos
Synonyma:
ROL;CVMP;ipo8;Rabon;Ravap;Appex;Rabond;Vinfos;Gardon;Dust M
CBNumber:
CB1673649
Summenformel:
C10H9Cl4O4P
Molgewicht:
365.96
MOL-Datei:
22248-79-9.mol

Tetrachlorvinphos Eigenschaften

Schmelzpunkt:
97-98 °C(lit.)
Siedepunkt:
399.5±42.0 °C(Predicted)
Dichte
1.520±0.06 g/cm3(Predicted)
Dampfdruck
6.0×10-6 Pa (20 °C)
storage temp. 
0-6°C
Wasserlöslichkeit
11mg l-1(20°C)
Aggregatzustand
solid
Merck 
13,9267
CAS Datenbank
22248-79-9(CAS DataBase Reference)
NIST chemische Informationen
Tetrachlorvinphos(22248-79-9)
IARC
2B (Vol. 30, Sup 7, 112) 2017
EPA chemische Informationen
Tetrachlorvinphos (22248-79-9)

Sicherheit

Kennzeichnung gefährlicher Xn,N,F
R-Sätze: 21/22-50/53-36-20/21/22-11-22
S-Sätze: 36-60-61-36/37-16
RIDADR  UN 3077 9/PG 3
RTECS-Nr. TB9100000
HS Code  29199000
Giftige Stoffe Daten 22248-79-9(Hazardous Substances Data)
Toxizität LD50 in male, female rats (mg/kg): 1100, 1125 orally (Gaines)

Tetrachlorvinphos Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R21/22:Gesundheitsschädlich bei Berührung mit der Haut und beim Verschlucken.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R36:Reizt die Augen.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.

S-Sätze Betriebsanweisung:

S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S16:Von Zündquellen fernhalten - Nicht rauchen.

Beschreibung

Tetrachlorvinphos was initially registered for use in the United States in 1966 for use on various food crops, livestock, and pet animals, and in around buildings. Its use on food crops were voluntarily canceled in the United States in 1987; however, it is used on food crops in developing countries. Tetrachlorvinphos is sold under the trade names Rabon and Gardona.

Chemische Eigenschaften

Powder.Partially soluble in chloroform; slightly soluble in water.

Chemische Eigenschaften

Technical tetrachlorvinphos is a tan-to-brown crystalline solid. Tetrachlorvinphos is stable at ,100 C and slowly hydrolyzed at 50°C. Aromatic odor.
Soluble in water at 24°C 15 ppm; limited solubility in most aromatic hydrocarbons.

Verwenden

Tetrachlorvinphos is used to control lepidopterous and dipterous larvae in fruit and lepidopterous larvae in cotton, maize, rice, tobacco and vegetables. It is also used against nuisance flies in animal houses, animal ectoparasites and stored product pests.

Verwenden

Insecticide.

Verwenden

Tetrachlorvinphos is commonly used as a feed additive to control flies in livestock and as dusts, sprays, dips, and collar ingredient to control ticks and fleas on domestic pets. It is extensively used in poultry. In horses, its formulations are commonly used as a feed additive (feed-through tetrachlorvinphos) larvicide. In addition, tetrachlorvinphos is also used in the control of public health pests, manure flies associated with livestock, and poultry as a feed additive.

Hazard

Cholinesterase inhibitor. Questionable carcinogen.

Carcinogenicity

When rats were given diets with 0, 4250, or 8500 ppm tetrachlorvinphos for 80 weeks, both males and females had a high incidence of thyroid C-cell hyperplasia, and females had increased incidences of adrenal cortical adenomas and thyroid C-cell adenomas .

Environmental Fate

Tetrachlorvinphos is nonpersistent in the environment. The primary route of dissipation is through biotic degradation. Based on its use pattern, risks of contamination of groundwater or surface water by tetrachlorvinphos are minimal.

Stoffwechselwegen

The chemical structure of tetrachlorvinphos is very close to that of chlorfenvinphos and the routes of metabolic breakdown have been shown to be very similar. Technical tetrachlorvinphos is usually >95% Z-isomer, unlike chlorfenvinphos which is an E/Z mixture. As with chlorfenvinphos, the major routes of detoxification are by dealkylation and hydrolysis to yield desmethyltetrachlorvinphos and 2,2’,4’,5’- tetrachloroacetophenone plus dimethyl phosphate, respectively. Further metabolism of the chloroacetophenone moiety then leads, via reduction or hydrolysis and glutathione-dependent displacement of the side chain chlorine substituent, to the formation of 1-(2,4,5-trichlophenyl) ethane-l,Z-diol and 1-(2,4,5-trichlorophenyl)ethan-l-owl hich are conjugated with glucose or glucuronic acid to afford the ultimate metabolites. Oxidation of the β carbon atom to give 2,4,5-trichloromandelic acid followed by decarboxylation leads to the formation of 2,4,5-trichlorobenzoic acid which is conjugated with glycine in some mammals as the final metabolite. The metabolic routes were summarised by Beynon et al. (1973).

Degradation

Tetrachlorvinphos is hydrolysed slowly in neutral, acidic and slightly alkaline aqueous solutions but hydrolysed rapidly in strongly alkaline solutions to metabolites 3 and 5 (PM). Dureja et al. (1987) reported the photochemical degradation of tetrachlorvinphos in water, ethanol, ether and hexane irradiated with a xenon lamp. In polar solvents, the main product was desmethyltetrachlorvinphos (2), whereas in non-polar solvents such as hexane the reaction yielded dimethyl phosphate (3), 2,4,5-trichloroacet ophenone (4) and 2,2’,4’,5’-tetrachloroacetophenone (5). Interconversion of the Z- and Ε-isomers has been observed on leaves (Beynon and Wright, 1969). These pathways are shown in Scheme 1.

Toxicity evaluation

Acute oral LD50 for rats: 4,000-5,000 mg/kg

Tetrachlorvinphos Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Tetrachlorvinphos Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 78)Lieferanten
Firmenname Telefon Fax E-Mail Land Produktkatalog Edge Rate
Capot Chemical Co.,Ltd.
+86(0)13336195806 +86-571-85586718
+86-571-85864795 sales@capotchem.com China 20012 60
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58
CONIER CHEM AND PHARMA LIMITED
86-18523575427
sales@conier.com CHINA 47498 58
Career Henan Chemica Co
13203830695 0371-86658258
0371-86658258 Laboratory@coreychem.com CHINA 30290 58
Dayang Chem (Hangzhou) Co.,Ltd.
17705817739 +86-571-88938639
+86-571-88938652,+86-571- 88492614 info@dycnchem.com CHINA 52932 58
Henan Alfa Chemical Co., Ltd
+8619139973225
adam@alfa-chemical.com;sales4@alfachem.cn China 11904 58
Mainchem Co., Ltd. +86-0592-6210733
+86-0592-6210733 sale@mainchem.com CHINA 32439 55
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18
0086-571-85864795 sales@capotchem.com China 18227 66

22248-79-9(Tetrachlorvinphos)Verwandte Suche:


  • ncic00168
  • o,o-dimethyl-o-2-chlor-1-(2,4,5-trichlorphenyl)-vinyl-phosphat
  • Phosphoric acid, 2-chloro-1-(2,4,5-trichlorophenyl)ethenyl dimethyl ester, (Z)-
  • phosphoricacid,2-chloro-1-(2,4,5-trichlorophenyl)ethenyldimethylester
  • phosphoricacid,2-chloro-1-(2,4,5-trichlorophenyl)vinyldimethylester
  • Rabon
  • Rabond
  • ROL
  • SD 8447
  • Stirofo
  • Tetrachlorvinphos, (Z)
  • Vinfos
  • RABON(R)
  • STIRIFOS
  • STIROFOS
  • STIROPHOS
  • Ravap
  • REVAP(R)
  • TETRACHLORVINPHOS, 1GM, NEAT
  • TETRACHLORVINPHOS PESTANAL, 250 MG
  • Phosphoric acid, (1Z)-2-chloro-1-(2,4,5-trichlorophenyl)ethenyl dimethyl ester
  • stirofos (esa)
  • stirofox
  • tetrachlorvinphos (bsi,iso)
  • TETRACHLOVINPOS
  • TETRACHLOROVINPHOS
  • SHELLSD-8447
  • (Z)-O,O-dimethyl-O-[1-(2,4,5-trichlorophenyl)-2 -chlorovinyl] phosphate
  • Gardon
  • O,O-dimethyl-O-[1-(2,4,5-trichlorophenyl)-2-chloro]vinylphosphate
  • GARDONA
  • GARDONA(R)
  • DIMETHYL-1-[2,4,5-TRICHLOROPHENYL]-2-CHLOROVINYL PHOSPHATE
  • DEBANTIC
  • CVMP
  • (z)-2-chloro-1-(2,4,5-trichlorophenyl)ethenylphosphoric acid dimethyl ester
  • (Z)-2-Chloro-1-(2,4,5-trichlorophenyl)ethenyl dimethyl phosphate
  • (Z)-2-Chloro-1-(2,4,5-trichlorophenyl)vinyl dimethyl phosphate
  • 2,4,5-trichloro-alpha-(chloromethylene)-benzylalcohodimethylphosphate
  • 2,4,5-trichloro-alpha-(chloromethylene)benzylphosphate
  • Appex
  • cis-Gardona
  • Dietreen
  • Dust M
  • ENT 25,841
  • Gardcide
  • Gordona
  • ipo8
  • Rabona
  • Dimethyl 2,4,5-trichloro-alpha-(chloromethylene)benzyl phosphate
  • Phosphoric acid, 2-chloro-1-(2,4,5-trichlorophenyl)vinyl dimethyl ester, (Z)
  • 2,4,5-Trichloro-alpha-(chloromethylene)benzyl phosphate ester
  • 2-Chloro-1-(2,4,5-trichlorophenyl)vinyl Dimethylphosphate, (Z)-
  • C14513
  • Tetrachlorvinphos
  • Tetrachlorvinphos Solution, 100ppm
  • Tetrachlorvinphos Standard
  • Tetrachlorvinphos
Copyright 2019 © ChemicalBook. All rights reserved