2-Chlor-2'-ethyl-N-(2-methoxy-1-methylethyl)-6'-methylacetanilid Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
GERUCHLOSE KLARE FLüSSIGKEIT.
ARBEITSPLATZGRENZWERTE
TLV nicht festgelegt (ACGIH 2005).
MAK nicht festgelegt (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den Körper durch Inhalation des Aerosols.
INHALATIONSGEFAHREN
Verdampfung bei 20°C vernachlässigbar; eine gesundheitsschädliche Partikelkonzentration in der Luft kann jedoch beim Versprühen schnell erreicht werden.
LECKAGE
NICHT in die Umwelt gelangen lassen. Ausgelaufene Flüssigkeit in abgedeckten Behältern sammeln. An sicheren Ort bringen. Persönliche Schutzausrüstung: Atemschutzgerät, P2-Filter für schädliche Partikel.
R-Sätze Betriebsanweisung:
R43:Sensibilisierung durch Hautkontakt möglich.
R36:Reizt die Augen.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
S-Sätze Betriebsanweisung:
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S16:Von Zündquellen fernhalten - Nicht rauchen.
Chemische Eigenschaften
Metolachlor is a colorless or tan to brown, oily
liquid. Slightly sweet odor.
Verwenden
A selective pre-emergence herbicide.
Allgemeine Beschreibung
Tan to brown oily liquid with a slightly sweet odor. Slightly soluble in water and denser than water. Hence sinks in water. Soluble in most organic solvents. Used as a selective herbicide.
Air & Water Reaktionen
Slightly soluble in water. Hydrolyzed by strong mineral acids and strong alkalis.
Reaktivität anzeigen
Metolachlor is a chlorinated acetamide. May react with azo and diazo compounds to generate toxic gases. May form flammable gases with strong reducing agents. Combustion generates mixed oxides of nitrogen (NOx).
Health Hazard
Can cause skin irritation and eye irritation. Headache and nausea may occur following prolong exposure.
Landwirtschaftliche Anwendung
Herbicide: Not approved for use in EU countries. Registered
for use in the U.S. Metolachlor is a selective herbicide that
is usually applied to crops before plants emerge from the
soil, and is used to control certain broadleaf and annual
grassy weeds in field corn, soybeans, peanuts, grain sorghum,
potatoes, pod crops, cotton, safflower, stone fruits,
nut trees, highway rights-of-way and woody ornamentals.
Prior to the RED of April, 1995, its primary use was on
corn, soybeans and sorghum. It inhibits protein synthesis;
thus, high-protein crops (e. g., soy) can be adversely
affected by excessive metolachlor application. Additives
may be included in product formulations to help protect
sensitive crops (i.e., sorghum) from injury.
Handelsname
BICEP®[C]; BROADSTRIKE®; CGA-
24705®; CINCH®; CODAL®; COTORAN® MULTI®;
CYCLE®[C] DREXEL ME-TOO-LACHLOR®; DUAL®;
DUAL MAGNUM®; DUET®[C]; INTER PLUS®;
MEDAL®[C]; MILOCEP®; ONTRACK 8E®[C];
PENNANT®[C]; PRELUDE®[C]; PRIMAGRAM®;
PRIMEXTRA®; TURBO®
mögliche Exposition
Metolachlor is a chlorinated acetamide
selective herbicide used for weed control in corn and for
controlling grasses in a variety of crops including cotton
and peanuts.
Stoffwechselwegen
A stable bacterial community absorbs and transforms
metolachlor from a liquid medium. From the medium
of the 7 day-old culture of the bacterial community, 2-
hydroxy-N-(2-methyl-6-vinylphenyl)-N-(2-methoxy-
methylethyl)acetamide and 4-(2-ethyl-6-methylphenyl)-
5-methyl-3-morpholinone are identified. The products
recovered from cells of J4-A include dechlorinated
metolachlor, a thiol compound, a more complicated
conjugate, and a non-sulfur-containing conjugate. By
sorghum microsomes, O-demethylation occurs in the
metolachlor degradation process.
Versand/Shipping
UN2902 Pesticides, liquid, toxic, n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name
Required. UN3082 Environmentally hazardous substances,
liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous
hazardous material, Technical Name Required.
Inkompatibilitäten
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions.
Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides, nitrates. Compounds of
the carboxyl group react with all bases, both inorganic and
organic (i.e., amines) releasing substantial heat, water and a
salt that may be harmful. Incompatible with arsenic compounds
(releases hydrogen cyanide gas), diazo compounds,
dithiocarbamates, isocyanates, mercaptans, nitrides, and
sulfides (releasing heat, toxic, and possibly flammable
gases), thiosulfates and dithionites (releasing hydrogen
sulfate and oxides of sulfur).
Waste disposal
In accordance with 40CFR
165 recommendations for the disposal of pesticides and
pesticide containers. Must be disposed properly by following
package label directions or by contacting your local or
federal environmental control agency, or by contacting
your regional EPA office.
2-Chlor-2'-ethyl-N-(2-methoxy-1-methylethyl)-6'-methylacetanilid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
